EGU21-10338
https://doi.org/10.5194/egusphere-egu21-10338
EGU General Assembly 2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.

The information content of skylight polarisation in MAX-DOAS trace gas- and aerosol profiling applications 

Jan-Lukas Tirpitz1, Udo Frieß1, and Ulrich Platt1,2
Jan-Lukas Tirpitz et al.
  • 1Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
  • 2Max Planck Institute for Chemistry, Mainz, Germany

Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) is a well-established measurement technique for the detection of atmospheric aerosol and trace gases: ultra-violet and visible radiation spectra of skylight are analyzed to obtain information on different atmospheric parameters. An appropriate set of spectra recorded under different viewing geometries ("Multi-Axis") allows retrieval of aerosol and trace gas vertical distributions as well as aerosol properties by applying numerical inversion methods. Currently one of the method’s major limitations in ground-based applications is the limited information contained in the measurements that reduces the sensitivity, particularly at higher altitudes.

It is well known but not yet used in MAX-DOAS profile retrievals that measuring skylight of different polarisation directions provides additional information: The degree of polarisation for instance strongly depends on the atmospheric aerosol content and the aerosol properties and – since the light path differs for the light of different polarisation -  the set of geometries available for the inversion is extended. We present a novel polarization-sensitive MAX-DOAS instrument (PMAX-DOAS) and a corresponding inversion algorithm, capable of using polarimetric information to significantly extend the information content of the measurements. The improvement over conventional “unpolarised” MAX-DOAS approaches will be discussed, based on both, synthetic data and real measurements.

How to cite: Tirpitz, J.-L., Frieß, U., and Platt, U.: The information content of skylight polarisation in MAX-DOAS trace gas- and aerosol profiling applications , EGU General Assembly 2021, online, 19–30 Apr 2021, EGU21-10338, https://doi.org/10.5194/egusphere-egu21-10338, 2021.

Display materials

Display file

Comments on the display material

to access the discussion