EGU2020-11563
https://doi.org/10.5194/egusphere-egu2020-11563
EGU General Assembly 2020
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.

Paratethys pacing of the Messinian Salinity Crisis: low salinity waters contributing to gypsum precipitation?

Wout Krijgsman1, Arjen Grothe1, Federico Andreetto1, Gert-Jan Reichart1, Mariette Wolthers1, Christiaan van Baak1, Iuliana Vasiliev2, Marius Stoica3, Francesca Sangiorgi1, Jack Middelburg1, and Gareth Davies4
Wout Krijgsman et al.
  • 1Department of Earth Sciences, Utrecht University, Princetonlaan 8A, 3584 CB, Utrecht, Netherlands (w.krijgsman@uu.nl)
  • 2Senckenberg Biodiversity and Climate Research Centre, Senckenberganlage 25, 60325, Frankfurt am Main, Germany
  • 3Department of Geology, University of Bucharest, Bălcescu Bd. 1, Bucharest, 010041, Romania.
  • 4Geology & Geochemistry, VU University, De Boelelaan 1085, 1081 HV, Amsterdam, The Netherlands

During the so-called Messinian Salinity Crisis (MSC: 5.97-5.33 Myr ago), reduced exchange with the Atlantic Ocean caused the Mediterranean to develop into a “saline giant” wherein ~1 million km3 of evaporites (gypsum and halite) were deposited. Despite decades of research it is still poorly understood exactly how and where in the water column these evaporites formed. Gypsum formation commonly requires enhanced dry conditions (evaporation exceeding precipitation), but recent studies also suggested major freshwater inputs into the Mediterranean during MSC-gypsum formation. Here we use strontium isotope ratios of ostracods to show that low-saline water from the Paratethys Seas actually contributed to the precipitation of Mediterranean evaporites. This apparent paradox urges for an alternative mechanism underlying gypsum precipitation. We propose that Paratethys inflow would enhance stratification in the Mediterranean and result in a low-salinity surface-water layer with high Ca/Cl and SO4/Cl ratios. We show that evaporation of this surface water can become saturated in gypsum at a salinity of ~40, in line with salinities reported from fluid inclusions in MSC evaporites.

How to cite: Krijgsman, W., Grothe, A., Andreetto, F., Reichart, G.-J., Wolthers, M., van Baak, C., Vasiliev, I., Stoica, M., Sangiorgi, F., Middelburg, J., and Davies, G.: Paratethys pacing of the Messinian Salinity Crisis: low salinity waters contributing to gypsum precipitation?, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-11563, https://doi.org/10.5194/egusphere-egu2020-11563, 2020.

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