Investigating the Relation of Arctic Tropospheric Bro Derived by Satellite Remote Sensing to Sea Ice Age and Meteorological Driving Mechanisms Under the Impact of Arctic Amplification

Arctic Amplification, the rapid increase of air temperature in higher latitudes over the last decades, is expected to have drastic impacts on all the sub-systems of the Arctic ecosystem. Bromine Oxides play a key role in the atmospheric composition of the Arctic. During polar spring, bromine molecules are released from young sea ice covered regions.  A rapid chemical chain reaction starts, the -so called 'bromine explosion', which depletes ozone, alters the production of OH, and thereby eventually changes the oxidizing capacity of the troposphere. Halogens oxidize elemental to gaseous mercury, which may then be deposited and harm the ecosystem. Based on current literature, there is considerable uncertainty on the impact of Arctic Amplification on halogen evolution. On one hand, the melting of multi-year sea ice should result in formation of more young sea ice, which favors bromine release. On the other hand, BrO explosion events are triggered by low temperatures, an effect expected to be reduced due to Arctic Amplification. Moreover, changes of other meteorological drivers, such as cyclone frequency and wind speed may impact on BrO amounts in the Arctic troposphere.

In this study, a long-term time-series of tropospheric BrO derived from 4 UV-VIS instruments (GOME, SCIAMACHY, GOME-2A, GOME-2B) is used as a basis, in order to investigate the impact of Arctic Amplification on BrO amounts in the Arctic. The long-term BrO data is being compared to sea ice age (NSIDC) and meteorological (air temperature, mean sea level pressure, wind speed and boundary layer height from ERA-5 & ASR-2) data. Our results focus on determining the relation between tropospheric BrO and its drivers, and especially on how the drivers impact on the formation of BrO plumes. Different cases studies throughout the 22 years of the BrO dataset were performed and evaluated. The changes in the tropospheric BrO abundances come in general agreement with changes in the drivers of BrO explosion events.

 

We gratefully acknowledge the funding by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) – Projektnummer 268020496 – TRR 172, within the Transregional Collaborative Research Center “ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms (AC)³”.