Tropospheric NO2 and HCHO derived from dual-scan MAX-DOAS measurements in Uccle (Belgium) and application to S5P/TROPOMI validation

Ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of aerosols, tropospheric nitrogen dioxide (NO₂) and formaldehyde (HCHO) have been carried out in Uccle, Brussels, during two years (March 2018 – March 2020). The MAX-DOAS instrument has been operating in both UV and visible (Vis) wavelength ranges in a dual-scan configuration consisting of two sub-modes: (1) an elevation scan in a fixed viewing azimuthal direction (the so-called main azimuthal direction) pointing and (2) an azimuthal scan in a fixed low elevation angle (2^o). By applying a vertical profile inversion algorithm in the main azimuthal direction and an adapted version of the parameterization technique proposed by Sinreich et al. (2013) in the other azimuthal directions, near-surface  concentrations (VMRs) and vertical column densities (VCDs) are retrieved in ten different azimuthal directions.

The present work focuses on the seasonal horizontal variation of NO₂ and HCHO around the measurement site. The observations show a clear seasonal cycle of these trace gases. An important application of the dual-scan MAX-DOAS measurements is the validation of satellite missions with high spatial resolution, such as TROPOMI/S5P. Measuring the tropospheric  VCDs in different azimuthal directions is shown to improve the spatial colocation with satellite measurements leading to a better agreement between both datasets. By using  vertical profile information derived from the MAX-DOAS measurements, we show that a persistent systematic underestimation of the TROPOMI  data can be explained by uncertainties in the a-priori NO₂ profile shape in the satellite retrieval. A similar validation study for TROPOMI HCHO is currently under progress and preliminary results will be presented.

References:

Sinreich, R., Merten, A., Molina, L., and Volkamer, R.: Parameterizing radiative transfer to convert MAX-DOAS dSCDs into near-surface box-averaged mixing ratios, Atmos. Meas. Tech., 6, 1521–1532, https://doi.org/10.5194/amt-6-1521-2013, 2013.