Large-eddy Simulation of Plume Dispersion over Hypothetical Urban Areas

More than 80% of people living in urban areas that exposed to air quality levels that exceed WHO guideline limits both indoors and outdoors. Road transport has been found to be one of major anthropogenic sources of aerosol particles and many gaseous pollutants in urban areas. Dispersion of pollutants emitted from vehicles over urban areas largely affects pedestrian-level air quality. A good understanding of pollutant transport, mixing process and removal mechanism is crucial to effectuate air quality management. In this study, turbulent dispersion of reactive pollutants in the atmospheric boundary layer (ABL) over hypothetical urban area in the form of an array of idealised street canyons is investigated using large-eddy simulation (LES). The irreversible ozone O3 titration oxidizes nitric oxide NO to nitrogen dioxide NO2, representing the typical anthropogenic air pollution chemistry. Nitric oxide (NO) is emitted from the ground level of the first street canyon into the urban ABL doped with ozone (O3). From the LES results, negative vertical NO flux is found at the roof level of the street canyons.  By looking into the different plume behavior and vertical flux between the inert pollutant and chemically reactive pollutant, a fundamental understanding of exchange processes of anthropogenic chemicals between an urban surface and the atmosphere is developed.