Denitrification potential and occurrence of reactive minerals in the fractured carbonate aquifer of the Upper Muschelkalk, SW-Germany

Fractured or karstified carbonate rocks constitute major drinking water resources all over the world. Nitrate is one of the major threads for drinking water suppliers in regions with intensive agrucultural use. Field scale observations in the Upper Muschelkalk aquifer in the area “Oberes Gäu”, SW-Germany, suggest that denitrification due to oxidation of Fe^(II) or sulfide-bearing minerals might be a relevant attentuation process at least in cases of extended mean residence times (> 5-40 years).

To identify reactive minerals within the rock matrix rock samples have been taken from major facies types within the Upper Muschelkalk from outcrops, drillings and carbonate quarries. Samples have been analysed in polished thin sections using transmitted & reflected light microscopy as well as electron microscopy including energy-dispersive elemental analysis.

Reactive Fe^(II) and sulfide-bearing minearls are pyrite and marcasite as well as saddle dolomites (Fe-bearing dolomites). Concentrations of these minerals depend on facies types and amount to several weight percent iron. Porosities range from very low values (<1 %) up to 25 %.

In combination with a hydrogeological characterization, these investigations allowed to delineate reactive zones within the fractured aquifer. Denitrification within these reactive zones depends on the amount and dissolution of these minerals as well as effective diffusion in the pore space.