EGU2020-3611
https://doi.org/10.5194/egusphere-egu2020-3611
EGU General Assembly 2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Iron in Soils and Road Dust is Modulated by Coal-Fired Power Plant Sulfur Making Toxic PM2.5

Rodney J. Weber1, Jenny Wong1,2, Yuan Wang1, Ting Fang3, James Mulholland4, Armistead (Ted) Russell4, Stefanie Sarnat5, and Athanasios (Thanos) Nenes6,7
Rodney J. Weber et al.
  • 1Georgia Institute of Technology, Earth and Atmospheric Sciences, Atlanta, United States of America (rweber@eas.gatech.edu)
  • 2Department of Chemistry and Biochemistry, Mount Allison University, Sackville, E4L 1G8, Canada
  • 3Department of Chemistry, University of California Irvine, Irvine, 92697, USA
  • 4School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, 30331, USA
  • 5Department of Environmental Health, Rollins School of Public Health, Emory University, Atlanta, 30322, USA
  • 6Laboratory of Atmospheric Processes and their Impacts, School of Architecture, Civil & Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, 1015, Switzerland
  • 7Institute of Chemical Engineering Science, Foundation for Research and Technology, Patras, GR-26504, Greece

Transition metal ions, such as water-soluble iron (WS-Fe), are toxic components of fine particulate matter (PM2.5). In Atlanta, GA, from 1998 to 2013, WS-Fe was the PM2.5 species most associated with adverse cardiovascular outcomes in a previous study. We examined this data set to investigate the sources of WS-Fe and effects of air quality regulations on ambient levels of WS-Fe. Insoluble forms of iron in mineral and traffic dust combined with sulfate from coal-fired electrical generating units (EGU) were converted to soluble forms by sulfate-driven acid-dissolution. Sulfate produced both the highly acidic aerosol (summer pH 1.5-2) and liquid water required for the aqueous phase acid-dissolution, but variability in WS-Fe was mainly driven by particle liquid water. These processes were more pronounced in summer when particles were most acidic, whereas in winter the relative importance of WS-Fe from combustion emissions increased. Although WS-Fe represents a minute mass fraction (0.15%) of PM2.5, the observed high correlation between WS-Fe and PM2.5 mass (r=0.67) may result from these formation routes and account for some association between mass and adverse health seen in past studies. Similar processes are expected in many regions, implying these unexpected benefits from coal-burning reduction may be widespread.

How to cite: Weber, R. J., Wong, J., Wang, Y., Fang, T., Mulholland, J., Russell, A. (., Sarnat, S., and Nenes, A. (.: Iron in Soils and Road Dust is Modulated by Coal-Fired Power Plant Sulfur Making Toxic PM2.5, EGU General Assembly 2020, Online, 4–8 May 2020, EGU2020-3611, https://doi.org/10.5194/egusphere-egu2020-3611, 2020

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