Uncertainties in the stability field of UHP hydrous phases (10-A phase and phase E) and deep-slab dehydration: potential implications for fluid migration and water fluxes at subduction zones

The subduction of water via lithospheric-mantle hydrous phases have major implications for the generation of arc and back-arc volcanism, as well as for the global water cycle. Most of the current numerical models use Perple_X [Connolly et al., 2009] to quantify water release from the slab and subsequent fluid migration in the mantle wedge. At UHP conditions, the phase diagrams generated with this thermodynamic code suggest that the breakdown of serpentine and chlorite leads to the near complete dehydration of the lithospheric mantle before reaching a 200-km depth. Laboratory experiments, however, have observed the stability of the 10-Å phase and the phase E in natural bulk compositions, which may hold moderate amounts of water, beyond the stability field of serpentine and chlorite [Fumagalli and Poli, 2005; Maurice et al., 2018]. Here, using 2D thermo-mechanical models, we explore to what extent the presence of these hydrous phases may favor a deeper subduction of water than those predicted by Perple_X.

We perform end-member models in terms of slab temperature and thickness of hydrated lithospheric mantle entering at trench. The computed geotherms within the uppermost subducted mantle show that the stability field of mantle hydrous phases around 600-800°C and 6-8 GPa is crucial for predictions of water fluxes. We point out that the lack of systematic experiments at these P-T conditions, as well as the absence of 10-Å and E phases in current thermodynamic databases, prevent accurate estimates of deep water transfers. We nonetheless build a phase diagram based on current experimental constraints that includes approximations of their stability field and qualitatively discuss the potential implications for fluid migration in the back-arc mantle wedge and water fluxes.