Environmental change across the onset of the Messinian salinity crisis in the northern Mediterranean (Piedmont Basin, NW Italy)

In the late Miocene, the Mediterranean Basin became a restricted basin because of its progressive tectonic isolation from the Global Ocean. The almost complete halt of the Atlantic-Mediterranean water exchange about 6 Ma ago triggered the deposition of the Mediterranean Salt Giant during the Messinian salinity crisis (MSC; 5.97-5.33 Ma). The environmental conditions, which developed at the onset and during the MSC, are still debated since the evaporites buried beneath the modern Mediterranean seafloor are mostly inaccessible and the marginal successions contain scarce or no body fossils. Aiming to improve our knowledge on the environmental conditions at the onset of the MSC, we investigated the sedimentary record of intermediate palaeobathymetric settings (200-1000 m) from the Piedmont Basin (NW Italy) through a multidisciplinary approach (petrography, organic geochemistry). Shale/marl couplets deposited after the MSC onset are lateral time equivalents of shallow water (<200 m) shale/gypsum couplets deposited during the first phase of the crisis (5.97-5.60 Ma). Our results suggest that the MSC onset coincided with an intensification of water column stratification, most likely favoured by enhanced freshwater input due to moister climate conditions. No evidence of hypersaline conditions was found at the onset of the crisis, but rather normal marine conditions seem to have persisted at least in the upper water column, influenced by freshwater discharge. A stable chemocline apparently separated an upper water layer from a stagnant deeper-water body typified by reducing conditions. These physicochemical changes in the water column governed the sedimentary facies distribution during the first phase of the MSC.