Limited subduction of water to mid-upper mantle depths predicted by the phase assemblages in hydrated peridotites with natural chemical composition at high-PT conditions

The water exchange between the Earth’s surface and the deep interior is a prime process for the geochemical evolution of our planet and its dynamics. The degassing of water from the mantle takes place through volcanism whereas mantle regassing occurs through the subduction of H₂O chemically bound to hydrous minerals. The (im)balance between degassing and regassing controls the budget of surficial liquid water over geological timescales, i.e, the long-term global sea level. Continental freeboard constraints show that the mean-sea level has remained relatively constant in the last 540 Ma (changes less than about 100 m), thus suggesting a limited imbalance. However, thermopetrological models of water fluxes at present-day subduction zones predict that regassing exceeds degassing by about 50% which, if extrapolated to the past, would have induced a drop inconsistent with the estimations of the long-term sea-level. We have made the case that these inconsistencies arise from thermodynamic predictions for the hydrated lithospheric mantle mineralogy that are poorly constrained at a high pressure (P) and temperature (T). In our study, we thus have revised the global-water flux calculations in subduction zones using petrological constraints on post-antigorite assemblages from recent laboratory experimental data on natural peridotites under high-PT conditions [e.g. Maurice et al, 2018].

We model the thermal state of all present-day mature subduction zones along with petrological modeling using the thermodynamic code Perple_X and the most updated version of the thermodynamic database of Holland and Powell [2011]. For the modeling of peridotite, we build a hybrid phase diagram that combines thermodynamic calculations at moderate PT and experimental data at high PT (> 6 GPa- 600˚C). Our updated thermopetrological model reveals that the hydrated mantle efficiently dehydrates upon the breakdown of the hydrous aluminous-phase E before reaching 250 km in all but the coldest subduction zones. Further subducting slab dehydration is expected between 300-350 km depths, regardless of its thermal state, as a result of lawsonite breakdown in the gabbroic crust. Overall, we predict that present-day global water retention in subducting plates beyond a depth of 350 km barely exceeds the estimations of mantle degassing for average thicknesses of subducting serpentinized mantle subducting at the trenches of up to 6 km. Finally, our models quantitatively support the steady-state sea level scenario over geological times.

 

Maurice, J., Bolfan-Casanova, N., Padrón-Navarta, J. A., Manthilake, G., Hammouda, T., Hénot, J. M., & Andrault, D. (2018). The stability of hydrous phases beyond antigorite breakdown for a magnetite-bearing natural serpentinite between 6.5 and 11 GPa. Contributions to Mineralogy and Petrology, 173(10), 86.

Holland, T. J. B., & Powell, R. (2011). An improved and extended internally consistent thermodynamic dataset for phases of petrological interest, involving a new equation of state for solids. Journal of Metamorphic Geology, 29(3), 333-383.