Characterizing the spatiotemporal dynamics of soil water stable isotopes on a karst hillslope in southwestern China

Soil water stable isotope compositions (SWSI; i.e., δD and δ¹⁸O) and soil moisture content (SMC) are widely used to illuminate water exchange processes across the atmosphere-land interface. Thus, the knowledge of spatiotemporal dynamics of these two variables is critical to help our understanding of relevant ecohydrological processes. However, in comparison to the efforts for elucidating the spatiotemporal variability in SMC, much less attention was paid to understand the spatiotemporal variability in SWSI, which also raises the question as to whether SWSI and SMC share similar spatiotemporal features. To this end, the spatiotemporal dynamics of SWSI and SMC were jointly investigated on a karst hillslope with eight sampling campaigns among two years. The method of temporal stability analysis (TSA) was adopted to evaluate the spatiotemporal patterns of SWSI and SMC in this study. Generally, both δD and δ¹⁸O exhibited considerable temporal and spatial variations; meanwhile, the variations in δD and δ¹⁸O values were relatively smaller than that of SMC. In addition, in comparison with the spatial pattern of SMC, there were no clear relationships between the standard deviation (SD) and the spatial mean of δD or δ¹⁸O. However, the SD of line-conditioned excess (lc-excess) and its mean values displayed a strong negative correlation, indicating that the spatial variations in lc-excess increased with soil evaporation. Moreover, SWSI displayed weaker temporal stability than SMC and no clear controlling factors were identified, suggesting that the spatiotemporal dynamics of SWSI might be more complex than that of SMC. This study provided comprehensive field evidence that there existed profound spatiotemporal variability in SWSI and its spatiotemporal features were different from SMC, highlighting that the spatiotemporal variability in SWSI needs to be considered in isotope-based estimations and it should be investigated separately from the spatiotemporal characteristics of SMC in future studies.