Brine Vs Marine Water as Sources of Halogen-rich Hydrothermal Fluids at La Soufrière de Guadeloupe

Abstract

The hydrothermal system of the andesitic volcano La Soufrière in the Basse-Terre island of Guadeloupe, is an ever evolving and highly dynamic system that is characterized by a variety of surface manifestations such as thermal springs, fumaroles and the Tarissan acid boiling pond (TAS) (Villemant et al.,2014). These produce halogen-rich surface emissions that makes it difficult to interpret subtle perturbations in the magmatic reservoirs using traditional geochemical and geophysical monitoring techniques (Moretti et al., 2020). A challenging situation for monitoring a volcano that has in recent history experienced six phreatic eruptions, the latest being the 1976-1977 eruptive crisis followed by a renewal of unrest in 1992 with the latest accelerated unrest episode occurring in 2018 (Komorowski et al., 2005, Moretti et al.,2020). Concurrently, TAS exhibited reduced Cl/Br ratios from ~1000 to ~300 from 18 January 2018 to 23 November 2020, suggesting marine water as a possible salinity source into the hydrothermal system. Hence, there is a critical need to fully conceptualize and appreciate the sources, full evolution and dynamic response of the hydrothermal system at La Soufrière. The research begins with investigating the potential input of ocean water into the hydrothermal system to aid in developing an exploitable geochemical database for prospective geochemical modelling analysis, leading to possible inferences on the influence of salinity on; 1) the gas-water-rock interactions in the shallow hydrothermal reservoir 2) scrubbing effects and 3) forcing conditions responsible for the measured surface gas emissions. We investigate this by numerically modelling flow transport of NaCl brines (wt.% 5, 25 and 35) using TOUGH2 software. Brines were modelled to represent volcanic- or marine- sourced brines at high temperature and pressure conditions (300°C - 350°C and 195Pa respectively). Steady state solutions of varying mass injections of orders of 1.0E^-4 kg/s/m² and 1.0E^-5 kg/s/m² resulted with the brines concentrating at heights of ~1100m a.s.l. at the summit and exiting the system, depending on the adopted permeability values. Thus implying that strong permeability contrasts due to sealing effects promoted by argillic alterations influences the trapping of brines in the upper edifice.