Evidence of abiotic graphite formation in Proterozoic marbles of the Lewisian Complex: mechanisms and consequences for the deep carbon cycle

The role of subduction zones has been considered critical to understand carbon fluxes among the Earth’s reservoirs. At plate margins, most of the carbon is stored in carbonate sediments. Nevertheless, the past decade saw an increasing focus also on reduced carbon - kerogen and graphite – to understand its role in the deep carbon cycle. Most of reduced carbon derive from seafloor organic-rich sediments, even if, a little portion can form by decarbonation during metamorphism.

In the Palaeoproterozoic supracrustal rocks of the Lewisian Complex, graphitic marbles were found in a mixed succession of metasediments at Gott Bay, Island of Tiree (Scotland). Such marbles show bedding-parallel slip surfaces associated with chlorite that are absent in other marbles on the island that are devoid of graphite. Marbles and schists-hosted graphite were analysed showing marked differences in carbon isotopic composition and structural ordering measured by means of Raman spectroscopy.

Petrographic and chemical evidence support the hypothesis of an abiotic origin of the marble-hosted graphite and the mechanisms that led to its formation could explain the heavy isotopic composition of many Proterozoic marbles in the world.