EGU22-6525
https://doi.org/10.5194/egusphere-egu22-6525
EGU General Assembly 2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.

Passive CO2 mineralisation in slag: evidence from a slag heap in Lanarkshire, Scotland.

Faisal W. K. Khudhur1, Alice Macente1,2, John MacDonald1, and Luke Daly1,3,4
Faisal W. K. Khudhur et al.
  • 1School of Geographical and Earth Sciences, University of Glasgow, Glasgow, United Kingdom
  • 2Department of Civil and Environmental Engineering, University of Strathclyde, Glasgow, United Kingdom
  • 3Centre for Microscopy and Microanalysis, University of Sydney, Sydney, Australia
  • 4Department of Materials, University of Oxford, Oxford, United Kingdom

CO2 mineralization is a natural process that occurs during weathering of silicate materials that are calcium/magnesium-rich and aluminum-poor (Kelemen et al., 2020). During this process, silicates convert to carbonates, making silicate-rich materials such as ultramafic rocks and alkaline wastes suitable for CO2 removal from air.  Using slag to sequester CO2 is particularly attractive as it is a by-product of a key industry, and it can utilize CO2 from the emission source, therefore reducing the need for CO2 and slag transportation, or draw down of CO2 already in the atmosphere. It is estimated that steel slag has the potential to capture ~150-250 Mt CO2 yr-1 now, and ~320-870 Mt CO2 yr-1 by 2100 (Renforth, 2019).

Although the chemical composition of alkaline wastes shows that CO2 capture can significantly offset emissions from corresponding industries, recent observations reveal that the CO2 uptake in alkaline wastes in underutilized (Pullin et al., 2019). Here, we use image-based analysis to understand the microstructures of CO2 mineralization in slag. We use X-ray Computed Tomography (XCT) to visualize slag internal structures and to calculate reactive surface area and pore connectivity. We then use scanning electron microscopy (SEM), coupled with energy dispersive spectroscopy (EDS) to study the distribution of elements within the studied sample.

In our study, we use a slag sample collected from the former Ravenscraig Steelworks in Lanarkshire, Scotland, where steelmaking took place from 1950s until 1992 (Stewart, 2008), leaving behind a slag heap that has been weathering since then. Our analysis demonstrates that calcium carbonate precipitates as pore-lining. Surface passivation and low surface-connected porosity were identified as processes that can cause reduction in CO2 uptake.

 

References

 

Kelemen, P.B., McQueen, N., Wilcox, J., Renforth, P., Dipple, G., Vankeuren, A.P., 2020. Engineered carbon mineralization in ultramafic rocks for CO2 removal from air: Review and new insights. Chem. Geol. 550, 119628. https://doi.org/10.1016/j.chemgeo.2020.119628

Pullin, H., Bray, A.W., Burke, I.T., Muir, D.D., Sapsford, D.J., Mayes, W.M., Renforth, P., 2019. Atmospheric Carbon Capture Performance of Legacy Iron and Steel Waste. Environ. Sci. Technol. 53, 9502–9511. https://doi.org/10.1021/acs.est.9b01265

Renforth, P., 2019. The negative emission potential of alkaline materials. Nat. Commun. 10, 1401. https://doi.org/10.1038/s41467-019-09475-5

Stewart, D., 2008. Fighting for Survival: The 1980s Campaign to Save Ravenscraig Steelworks. J. Scottish Hist. Stud. 25, 40–57. https://doi.org/10.3366/JSHS.2005.25.1.40

How to cite: Khudhur, F. W. K., Macente, A., MacDonald, J., and Daly, L.: Passive CO2 mineralisation in slag: evidence from a slag heap in Lanarkshire, Scotland., EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-6525, https://doi.org/10.5194/egusphere-egu22-6525, 2022.