The Weakest Link – Revealing the microphysical deformation mechanisms of talc under P-T conditions associated with fault creep and slow slip events

Talc is an important product of several hydration and dehydration reactions in deep faults and subduction zones. The unique weakness of talc along its basal planes makes it an essential component in understanding various fault slip behaviors (e.g., episodic vs continuous slip, seismic vs aseismic) or realistic geodynamic models. A recent experimental study by Boneh et al. (2023) on talc mechanical behavior at high P-T conditions highlighted: (i) talc’s low friction coefficient under all conditions (<0.14), with thermal weakening down to µ~0.01 at 700 °C. (ii) Grain-scale microstructures demonstrate a component of fracturing and microcracking under all conditions tested. And (iii) pressure-dependence of talc strength decreases at higher temperatures, where there is also a greater tendency for localization. A vital part of depicting mineral rheology is the understanding of their underlying mechanisms of deformation associated with the observed bulk mechanical and microstructural behavior. To reveal the underlying deformation mechanism/s we analyzed the deformed samples through high-resolution transmission electron microscopy (TEM) at Utrecht university of samples prepared using a focus ion beam (FIB). Five talc samples were examined – an undeformed sample, and samples deformed at 400, 600, and 700°C under 1 GPa, and at 400 °C under 1.5 GPa.

Seven FIB lamellae sampled areas adjacent to the main fracture (if exists) or high damage zones. The starting material shows talc flakes with a thickness of ~100-400 nm without a sample-scale preferred alignment. The sample deformed under 400°C and 1.5 GPa exhibits distributed deformation with opening cracks along talc basal planes and pervasive kinking normal to the basal planes. The sample deformed at 400°C and lower pressure (1.0 GPa) exhibits thin lamination (~50 nm) well oriented with the orientation of the main fracture plane. The sample deformed at 600°C exhibits crystal delamination along the basal cleavage (forming grain fragments <10 nm in width) along the main fracture. The sample deformed at 700°C exhibits more areas of high damage, possibly due to the similar basal-cleavage delamination. A key incentive is to relate the observed nano-scale crystal defects with the bulk mechanical behavior and with processes that might promote the localization of deformation. Pressure-dependent strength can be accounted for by kinking and kinking-induced porosity while thermal weakening can be related to temperature-dependent mobility of crystal defects leading to delamination along the basal cleavage. We will discuss possible physical mechanisms of talc deformation and the prospect of extrapolating the mechanical behavior of talc achieved at the lab to the range of conditions expected in natural settings.