Processes affecting the behaviour of persistent, mobile, and toxic substances in a riverbank filtration system

Riverbank filtration (RBF) consists in forcing surface water to infiltrate and flow through an aquifer by means of a pumping well located near a surface water body. RBF aims to take advantage of the filtration capacity of aquifers to improve the water quality by removing a wide range of pollutants, including contaminants of emerging concern, by combining of physical, chemical and biological processes. However, the efficacy of RBF for eliminating substances that are considered persistent, mobile, and toxic (PMT), or very persistent and very mobile (vPvM), is expected to be low due to the high mobility of these substances. PMT and vPvM compounds, which are accumulated in the water cycle, are harmful to humans and the environment. For this reason, the processes affecting PMT and vPvM substances during RBF processes deserve to be deeply investigated.

This study aims at investigating the processes affecting PMT and vPvM substances in a site that behaves similarly to a RBF system. The study site is located in Sant Adriá del Besòs (Barcelona, Spain), where a constant pumping to drain an underground parking lot forces the water from the Besòs river to infiltrate and travel up to 230 m through the aquifer. Groundwater samples were collected from the river, and a set of piezometers aligned along the groundwater flow line between the Besòs river, and the underground parking lot allowed monitoring of the water at different stages after its infiltration. The samples were analysed by liquid chromatography coupled to high resolution mass spectrometry (LC-HRMS) and PMT and vPvM were determined by a suspected screening approach.

This investigation provides new insights into the processes affecting PMT and vPvM substances and will have tremendous implications for determining groundwater quality in managed aquifer recharge contexts.