Does the polymorphic transition in quartz trigger lower crustal earthquakes?

Earthquakes are generated through the brittle failure of rocks at depth. While earthquakes are generally caused by far–field tectonic stresses, the atomic–scale mechanisms that actually trigger brittle failure in dry ductile crustal rocks are still uncertain. Quartz, a widespread mineral in the lower crust, undergoes an instantaneous polymorphic transformation from the α to β phase at pressure and temperature conditions compatible with the estimates of several lower–crustal paleo–earthquakes recorded as pseudotachylytes. The α–β quartz transition is displacive, reversible and, as α–quartz approaches the transition temperature at constant pressure, its volume increases non–linearly but without sudden jumps. In contrast, near the phase–transition temperature, the bulk modulus of quartz drops from ~30 GPa to almost zero and then abruptly rises to more than 70 GPa within a temperature range of only 10 K (Lakshtanov et al., 2007).

Due to the confined space, near the α–β transition, a quartz inclusion in a garnet host is expected to develop strong differential strains and consequently will impose strong differential stresses on the surrounding host crystal. To check this hypothesis, we have applied in situ high–temperature Raman spectroscopy to quartz inclusions in garnet to monitor the development of structural deformation via the atomic dynamics at temperatures across the phase transition temperature T_c = 847 K for a free quartz crystal at atmospheric pressure. The temperature behaviour of the phonon wavenumbers ω of a quartz inclusion, in particular the hardening and disappearance of a minimum in ω(T) for the A modes near 208 and 464 cm^-1 (involved in the α-β phase transition) as well as the persistence of Raman activity of the modes at ~128 cm^-1 and ~355 cm^-1 above T_c, reveals the accumulation of abnormally high strain in the confined quartz grains in the vicinity of the expected phase transition. Consequently, the corresponding stored elastic energy in the inclusion is released through the inclusion-host boundary into the host matrix while crossing the α–β transition, causing the garnet around the quartz inclusion to fracture or even, in some cases, shatter due to the large differential stresses developing in the inclusion at its transition.  Inclusions of apatite and zircon in the same garnets remain unchanged at the same conditions, excluding the fracturing being caused by the host garnet itself.

We propose that this process can create sufficient fracturing in lower–crustal garnets, which can in turn accumulate into planar fractures along garnet-rich layers and thus trigger brittle failure and seismicity.

References

Lakshtanov, D.L., Sinogeikin, S.V., Bass, J.D., 2007. High-temperature phase transitions and elasticity of silica polymorphs. Physics and Chemistry of Minerals 34, 11-22.