CCS Reservoir Characterisation using Carbon Quantum Dots

Efficient use of new CCS resources depends critically on their characterisation. This is as true for CCS reservoirs that are deep aquifers or reservoirs that have previously been exploited as oil or gas reservoirs. Conventional pre-existing or newly commissioned reservoir characterization methodologies, such as well logs, 3D and 4D seismic reflection and cross-well electromagnetic imaging are limited in their scope and resolution. For CCS, the  crucial characterisation is that of the connectivity of the pore network. Carbon quantum dots (CQDs) are inert carbon nano-particles less than 10 nm in diameter. They can be made easily from environmentally-friendly stock materials and remain stable in aqueous solution no matter the pH or salinity, unlike conventional nanoparticles. In fluorescence spectroscopy CQDs demonstrate a strong absorption in the UV region with peaks at 228 nm and 278 nm. Their fluorescence spectra occupy the visible spectrum and are related to the stimulating frequency. These optical properties allow the number of particles to be ascertained easily and their small size allows them to be pervasive in the porous medium. Consequently, CQDs are ideal for use as a conservative tracer. Core and bead–pack tests have shown that almost 100% of the injected CQDs can be recovered from the porous medium indicating that there would be no damage to the CCS resource by their use. Breakthrough curves (BTCs) can be used to calculate the porosity and connectivity of water saturated rocks and the water saturation and connectivity of rocks from previously exploited hydrocarbon reservoirs at temperatures up to 80^oC. Indeed it is possible that CQDs could be used to monitor quantitatively the emplacement of CO₂ along the injection path. Although these CQDs have an attenuated performance in carbonate rocks, surface coatings are expected to resolve this question. Surface functionalisation will also allow the properties of the reservoir, such as temperature to be measured by altering the frequency of the emerging CQDs.