Melting relations for putative mantles of Mercury and the compositional diversity of the crust

The compositional diversity of volcanic rocks revealed by NASA’s MESSENGER at the surface of Mercury has been interpreted to result from partial melting of a heterogenous sulfur-rich Mercurian mantle. However, melting relations and the composition of partial melts for iron-free and sodium-rich mantle, together with the effect of sulfur as a key volatile, have not yet been studied in detail. In this study we present results from high-pressure and high-temperature experiments on the mineralogical and geochemical evolution of the mantle residue and melting products of primitive deep Mercury’s mantle with two starting compositions differing by their Mg/Si ratios. Both compositions have sulfur added as FeS. Experiments were conducted using a multi-anvil press under reduced conditions (by controlling the Si/SiO₂ ratio of the starting composition) at pressures of 3 and 5 GPa.

The residual mantle of Mercury with the lower Mg/Si ratio of 1.02 contains olivine + orthopyroxene above ~15 wt% melting at 3 and 5 GPa, and olivine disappears at melting over ~30 wt.% at 5 GPa. The Mercurian mantle with the Mg/Si of 1.35 contains olivine + orthopyroxene in the residue above ~15 wt% melting at 3 and 5 GPa, and olivine only when the melting degree is over ~50 wt.%. Our experiments also show that the majority of chemical composition of the High-Magnesium region (HMR) can result from ~25±15 wt.% melting of a deep primitive mantle. Further work will enable us to evaluate the compositional diversity of the mantle that is needed to explain the broad range of surface lavas. We also aim at understanding the role of the highly refractory residual mantle as a controlling factor for the end of major volcanic activity on Mercury at 3.5 Ga.