Nitrous Oxide, N2O: Spectroscopic Investigations for Future Lidar Applications

Nitrous Oxide, N2O, is the third most important GHG contributing to human-induced global warming, after carbon dioxide and methane. Its growth rate is constantly increasing and its global warming potential is estimated to be 273 times higher than that of CO2 over 100 years. The major anthropogenic source is nitrogen fertilization in croplands. Soil N2O emissions are increasing due to interactions between nitrogen inputs and global warming, constituting an emerging positive N2O-climate feedback. The recent increase in global N2O emissions exceeds even the most pessimistic emission trend scenarios developed by the IPCC, underscoring the urgency of mitigating N2O emissions (Global Carbon Project, 2020). Estimating N2O emissions from agriculture is inherently complex and comes with a high degree of uncertainty, due to variability in weather and soil characteristics, in agricultural management options and in the interaction of field management with environmental variables. Further sources of N2O are processes in the chemical industry and combustion processes. The sink of N2O in the stratosphere increases the NOx concentration which catalytically depletes ozone. Better N2O measurements thus are urgently needed, particularly by means of remote sensing.

Airborne or satellite based N2O lidar remote sensing combines the advantages of high measurement accuracy, large-area coverage and nighttime measurement capability. Past initial feasibility studies revealed that Integrated-Path Differential-Absorption (IPDA) lidar providing vertical column concentrations of N2O would be the method of choice. In this current study we use the latest HITRAN spectroscopic data in order to identify appropriate N2O absorption lines in the wavelength region between 2.9 and 4.6 µm. The infrared spectral region challenges both lidar transmission and detection options. On the transmitter side, the use of optical parametric conversion schemes looks promising, while HgCdTe avalanche photodiode (APD), superconducting nanowire single-photon (SNSPD) or upconversion detectors (UCD) could offer high-efficiency low-noise signal detection. These options are implemented into a lidar simulation model in order to identify the optimal lidar system configuration for measuring N2O from aircraft or satellite using state-of-the-art technology.