It’s on the way up! Syn-exhumation paragenesis of glaucophane-phengite-quartz veins

Subvertical glaucophane + quartz ± phengite veins exposed in the footwall of a major extensional detachment on southern Evia (NW Cyclades, Greece) record mode-I brittle fracturing with variable principal stress orientations. The dense network of veins displays systematic cross-cutting relationships with a prominent youngest vein set spaced 5-10 cm apart transecting all other veins. Interlayered jadeite-rich metabasalt and quartzite host the veins and promote a pronounced rheological control on fracturing, with veins preferentially hosted in metabasalt layers and terminating abruptly as pressure solution seams or shear bands at contacts with the ductily deformed quartzite. Vein-hosted ferromagnesian minerals do not exhibit recrystallization or dissolution-reprecipitation microstructures. Jadeite in the metabasalt forms both i) 'fuzzy' euhedral crystals overgrown by hematite and ii) symplectitic intergrowths with quartz and albite. Vein-hosted glaucophane and phengite grew at fixed angles (normal and oblique) to vein walls. Phengite is compositionally homogeneous with elevated Si content (3.41–3.52 apfu). Glaucophane from all veins shows a homologous concentric compositional zoning with core chemistry intermediate between glaucophane and magnesioriebeckite, glaucophane-rich mantles, and rims of magnesioriebeckite or winchite. Phengite yields consistent single-grain total-fusion ⁴⁰Ar/³⁹Ar dates with a weighted mean of 22 ± 1 Ma (n: 22), whereas the low-K glaucophane produced equivocal and dispersed dates. Phengite (n: 44, 20) and glaucophane (n: 8, 42) in-situ ⁸⁷Rb/⁸⁷Sr isochrons from two samples yield mutually indistinguishable dates of 21 ± 5 Ma and 25 ± 4 Ma, within uncertainty of the ⁴⁰Ar/³⁹Ar dates. The uniform mineral chemistry, compositional zoning, and geochronology indicate that the veins formed over a short time without major shifts in ambient pressure-temperature conditions. Contrary to the apparent mineralogically-defined high pressure-low temperature paragenesis of the veins, dates obtained from pristine high-Si phengite support crystallization in the latest Oligocene to earliest Miocene, coincident with regional extension and widespread greenschist-facies retrogradation in the Aegean. Abundant hematite and the predominance of Fe³⁺-rich sodic amphibole and clinopyroxene species implicates a highly oxidizing fluid in the stabilization of these nominally ‘high-pressure’ minerals under conditions widely responsible for producing retrogradational greenschist-facies assemblages throughout the Cyclades.