Ocean Alkalinity Enhancement efficiency in the North Pacific under influence of the Pacific Decadal Oscillation

Carbon Dioxide Removal (CDR) technologies are imperative for achieving net zero emissions, a crucial feat to meet the 2º target set in the Paris Agreement. Ocean Alkalinity Enhancement (OAE) is a marine CDR technology that consists of increasing the Total Alkalinity (TA) of the ocean by depositing alkaline minerals to ocean surface waters. The increase in TA reduces the sea surface partial pressure of CO₂ (pCO₂), thereby enhancing oceanic CO₂ uptake or reducing oceanic CO₂ outgassing. Despite the potential of OAE to reduce atmospheric CO₂ concentrations, the realistic implementation of OAE faces substantial impediments, including logistical feasibility and the lack of international ocean governance for its deployment in open waters. To address these obstacles and incentivize the development of a policy framework for OAE, we set forward optimal conditions that maximize the efficiency of OAE in the North Pacific Ocean, leveraging natural climatic variability induced by the Pacific Decadal Oscillation (PDO). The addition of TA at high Dissolved Inorganic Carbon (DIC) concentrations has the potential to induce a stronger decrease in pCO₂ than at lower DIC concentrations. Therefore, natural temporal increases in surface DIC concentrations could potentially predispose the system for enhanced OAE efficiency. The PDO induces multi-decadal variations in the carbonate system, with the potential to influence the spatiotemporal variability in OAE efficiency. PDO phases have been shown to be predictable up to a decade ahead, thereby providing a practical indication for logistical planning of OAE deployment. We analyze the influence of the PDO on OAE efficiency in the North Pacific Ocean through four Earth System Model simulations under a high emission scenario (RCP8.5) spanning from 2020 to 2100. Using theoretical CO₂ uptake efficiencies, as defined by Tyka et al. (2022) and Renforth and Henderson (2017), we describe how PDO states modulate variability in uptake efficiency via their control on DIC and TA concentrations. Subsequently, we analyze the realized uptake efficiency by contrasting oceanic air-water CO₂ fluxes (FCO₂) in simulations with continuous and homogenous global OAE deployment against simulations without CDR intervention per unit of added TA. Early results show regional differences in OAE efficiency rates during different PDO phases. During positive PDO phases, theoretical CO₂ uptake efficiencies decrease in the Northeast Pacific while increasing in the central Western Pacific, corresponding to respectively lower and higher DIC concentrations. The inverse responses are observed during negative PDO phases. We discern differences between theoretical and realized CO₂ uptake efficiencies, indicating the role of additional influential variables. Our study provides new insights into the impact of the PDO on OAE efficiency and the potential to optimize CDR strategies by aligning them with natural climatic variations.