Evaluation of Oil Source Rocks Using Temperature-dependent Infrared Spectroscopy

Kerogen is typically categorized in three types: type I is associated with lacustrine, type II associated with marine, and type III associated with terrestrial sources, respectively. The Kerogen type is a crucial factor affecting oil-generative properties as it significantly influences the initiation and potential for hydrocarbon generation in source rocks. Geoscientists traditionally use Rock-Eval pyrolysis to determine kerogen types, maturity, and pyrolysis reaction temperature (Tmax), and calculate hydrocarbon potential, essential factors in assessing oil reserves and understanding the oil window. Such method, however, has insufficient resolution and is time-consuming. In this study, we employ a temperature-dependent infrared (IR) spectroscopy method to precisely determine kerogen type, maturity, and Tmax. Specifically, our IR spectroscopy is combined with a numerical analysis model developed for the analysis of various organic matter samples. Through measurements of the IR spectra of samples at different temperatures (Heating-FTIR), we determine the maximum sedimentary burial temperature and the pyrolysis Tmax of kerogen. By applying the conversion formula by Shibaoka & Bennett (1977), (R₀)^a=R^a+bt_I*exp(cT_m), we derive a virtual vitrinite reflectance, which is strongly correlated with our IR spectroscopy results, with insights into the maturation. This Heating-FTIR technique is a valuable tool for petroleum geology, facilitating the assessment of oil potential and maturity. Future refinement of the numerical model and improvement of the instrumentation are required to apply this technique to broader fields, such as sedimentary temperature for ancient geothermal gradient with better understanding of the sedimentary history.