Deformation of carbonated serpentinite controlled by Al- and Si-partitioning in phyllosilicates: a record of deep episodic tremor and slip?

Fluids are generally thought to assume a key role in controlling fast and slow earthquakes, not only because they lower the effective stress, but also because they act as catalysers of mineral reactions, moving chemicals in the rock mass. Serpentinites are particularly prone to carbonation reactions, which cause bulk-rock and volume change. The feedback between CO₂ ingress in serpentinites, H₂O-release, and tectonic appears to be able to sustain cycles of fluid pressure build-up and stress release that may be compatible with slow slip and tremor. However, the carbonation of pure serpentine (Mg₃Si₂O₅(OH)₄) should run to completion over geologic time scales, bearing the question if carbonation can sustain slow earthquakes in the long term at the subduction interface. On the other hand, the presence of Al, which does not enter the structure of talc, should slow down carbonation reactions and the products of serpentinite carbonation, allowing the process to be sustainable over long time scales.

We, therefore, investigated natural samples of sheared carbonated serpentinite from a fossil shear zone in the Sanbagawa metamorphic belt exhumed from ~ 35–45 km and ~ 450–550 °C, corresponding to the present-day conditions of the source region of deep episodic tremor and slow slip in the nearby Nankai Trough. The shear zone preserves ‘intact’ antigorite-serpentinite, talc- and chlorite-bearing serpentinite breccia, and complex brittle/ductile shear zone consisting of quartz-bearing carbonate-chlorite-talc schists, talc - carbonate veins, and talc-rich mylonitic shear zones. We document that the presence of Al in antigorite and spinel causes the formation of abundant chlorite which inhibits carbonation reaction. We show that the formation of talc- and carbonate-rich domains is primarily related to the formation of veins crosscutting the carbonated rock fabric. Hence, the formation of talc mylonites is primarily associated with parts of the rock that became Si-rich, whereas Al-rich domains deform primarily by fracturing and veining. Finally, the presence of fractured sulphides in the rock documents multiple cycles of fracturing, sulphide precipitation, and healing, compatible with successive embrittlement, stress release, fluid infiltration, and fluid pressure drop events.

We suggest that the presence of Al in the protolith serpentinitic material, which is common for ultramafic rocks, (1) slowed-down carbonation reactions, (2) prevented the rapid formation of talc-rich domains, and (3) kept the fabric heterogeneous and the rheology mixed, overall preventing the formation of weak domains that should have localized aseismic creep and possibly hosting episodic tremor and slow slip.