Water-induced superplastic deformation and its mechanism of quartz

The deformation behavior and mechanisms of mineral grains play a pivotal role in comprehending the solid-state rheological behavior of the lithospheric crust. However, the fluid present during the deformation processes of grains is often overlooked. The study presents a comprehensive analysis of water-induced superplastic deformation within deformed quartz veins exposed in the continental-scale exhumed Gaoligong shear zone by combining microstructure analysis with EBSD mapping and infrared spectroscopy. We observe fine-grained aggregates of quartz form micro-shear zones that are either localized at the rims or within the coarse clasts during deformation. The nucleation of these fine-grained zones is controlled by microcracks/fracturing, which are further associated with dynamic recrystallization. Numerous fluid inclusions are leaked and water is pumped into thicker fine-grained shear zones. The water migration plays a crucial role in accommodating boundary plasticity, with tiny water clusters being sealed within grain boundaries. The recycling of water is linked to a superplastic flow process, involving water influx, grain boundary sliding (GBS), accommodation of strain incompatibilities, and sealing of water. Our findings suggest that water migration into fine-grained aggregates within micro-shear zones not only restrict grain growth but also releases strain incompatibilities, enhancing grain boundary sliding. This process delays brittle fracturing of quartz, highlighting the significant role of water in influencing the deformation behavior of quartz.