The Moon is thought to have been covered initially by a deep magma ocean, its gradual solidification leading to the formation of the aluminium-rich plagioclase-bearing highland crust. We performed the first high-pressure, high-temperature experimental study of the mineralogical and geochemical evolution accompanying the full solidification of a lunar magma ocean (LMO) and provide new constraints on the presence of water in the early lunar interior. In a dry Moon, plagioclase appears after 68 per cent solidification and yields a crust with a thickness of ~68km¹, well above the lunar crustal thickness suggested by recent GRAIL mission gravitational data (34–43 km). Water-bearing experiments show a delay in the start and lowering of the volume of plagioclase formed during LMO crystallization, as observed previously for terrestrial magma. Using crustal thickness as a hygrometer we conclude that at least ~800 ppm water was present in the Moon at the time of LMO crystallization, indicating the Earth-Moon system was water-rich from the start^2,3.

Water does not only have remarkable effects on early LMO evolution, but also on the properties of Earth’s mantle rocks, however, how and how much transporting water into the deep Earth is still debated due to high mantle temperatures. Subduction of oceanic lithosphere transports surface H₂O into the mantle. Recent studies proved that stishovite and post-stishovites as high-pressure phases of SiO₂ have the potential to carry weight percent levels of water into the Earth’s interior along the geotherm of the subducting oceanic crust⁴. Regression of our experimental data indicates an H₂O storage capacity in stishovite of ~3.5 wt% in the transition zone and shallow lower mantle, decreasing to about 0.8 wt% at the base of the mantle⁵. As slabs subducted to the deepmost mantle, dehydration of these dense hydrous silica phases (DHS) can potentially change physicochemical properties of the Earth’s mantle by reducing melting point, forming new high-pressure phases and enhancing the oxygen fugacity heterogeneity of lower mantle⁶.

References:

[1] Lin Y., Tronche E. J., Steenstra E. S., and van Westrenen W. Experimental constraints on the solidification of a nominally dry lunar magma ocean. Earth Planet. Sci. Lett. 471, 104–116 (2017).

[2] Lin Y., Tronche E. J., Steenstra E. S., and van Westrenen W. Evidence for an early wet Moon from experimental crystallization of the lunar magma ocean. Nat. Geosci. 10, 14–18 (2017).

[3] Lin Y., Hui H., Xia X., Shang S., and van Westrenen W. Experimental constraints on the solidification of a hydrous lunar magma ocean. Meteorit. Planet. Sci. 55, 207–230 (2020).

[4] Lin Y., Hu Q., Meng Y., Walter M. and Mao H.-K. Evidence for the stability of ultrahydrous stishovite in Earth’s lower mantle. Proc. Natl. Acad. Sci. U. S. A. 117, 184–189 (2020).

[5] Lin Y et al. Hydrous SiO₂ in subducted oceanic crust and H₂O transport to the core-mantle boundary. Earth Planet. Sci. Lett. 594, 117708 (2022).

[6] Lin Y. and Mao H. K. Dense hydrous silica carrying water to the deep Earth and promotion of oxygen fugacity heterogeneity. Matter Radiat. Extremes 7, 068101 (2022).

How to cite: Lin, Y.: Effects of water on the evolution of the Early Moon and deep Earth investigated by experiments, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-4803, https://doi.org/10.5194/egusphere-egu24-4803, 2024.

While the deep Earth is not directly accessible, it can be explored by laboratory experiments under high-pressure and -temperature (P-T) combined with geophysical observations and geodynamical modeling. We conduct experiments using a laser-heated diamond-anvil cell (DAC) which can generate static high P-T beyond conditions at the center of the Earth. Combining such DAC experiments with in-situ X-ray observations at synchrotron sources and thermal/electrical conductivity measurements and ex-situ textural and chemical characterizations of recovered samples, we have been trying to uncover the structures, chemical compositions, physical properties, dynamics, and evolution of the deep Earth and planetary interiors. The lowermost part of the Earth’s mantle, sometimes called the D” layer, have been the most enigmatic region inside our planet, but the discovery of its main constituent crystals of post-perovskite dramatically improved our understanding of this mysterious layer. Recent hot debates on the core include its thermal conductivity and the mechanism of its convection that have sustained the planetary magnetic field since early history of the Earth. In addition, the Earth’s core is known to include substantial amounts of light elements such as sulfur, silicon, oxygen, carbon, and hydrogen, but its exact chemical composition has been highly controversial since Birch (1952). Hydrogen could be one of the important core light elements when considering that a large amount of water may have been delivered to the growing Earth and hydrogen is strongly siderophile (iron-loving) under high pressure. Nevertheless, the phase diagram and properties of iron hydrides are little known since hydrogen is least soluble into iron at ambient conditions. I will introduce these high-pressure studies on the deep mantle and core materials including our recent work on iron hydrides and discuss the possible ranges of Earth’s core composition.

How to cite: Hirose, K.: Exploring the deep Earth and planetary interiors by high-pressure experiments, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-1663, https://doi.org/10.5194/egusphere-egu24-1663, 2024.