EGU26-19790, updated on 14 Mar 2026
https://doi.org/10.5194/egusphere-egu26-19790
EGU General Assembly 2026
© Author(s) 2026. This work is distributed under
the Creative Commons Attribution 4.0 License.
Oral | Wednesday, 06 May, 08:55–09:05 (CEST)
 
Room 0.49/50
Does it matter whether benthic foraminifera achieve clumped-isotope thermodynamic equilibrium?
Mathieu Daëron1 and William Gray2
Mathieu Daëron and William Gray
  • 1Centre National de la Recherche Scientifique, Laboratoire des Sciences du Climat et de l'Environnement, Gif Sur Yvette, France (daeron@lsce.ipsl.fr)
  • 2Commissariat à l'Énergie Atomique, Laboratoire des Sciences du Climat et de l'Environnement, Gif Sur Yvette, France (william.gray@lsce.ipsl.fr)

In many carbonate archives, Δ47 signatures appear to be primarily driven by crystallization temperatures, with little evidence for other influencing factors, implying that 13C and 18O isotopes are effectively (re)distributed among carbonate isotoplogues in accordance with thermodynamic stability during or just before mineralization. This is not the case for all types of carbonates, but appears to hold true for biocarbonates such as bivalves, gastropods, or planktic foraminifera. For historical reasons, things are not as clear-cut when it comes to benthic foraminifera, a particularly important source of information on past marine environments at the scale of the Cenozoic and beyond. In hope of fostering productive discussions, we revisit this issue with a focus on the following questions:

  • What is the current body of evidence from modern/recent observations?
  • How much do the various Δ47 calibrations currently applied to foraminifera differ?
  • Is there any practical difference between Δ47 calibrations based exclusively on modern/recent foraminifera and "composite" calibrations based on many different types of carbonates?
  • What should be the foraminifer Δ47 community's next steps to try and resolve these issues?

How to cite: Daëron, M. and Gray, W.: Does it matter whether benthic foraminifera achieve clumped-isotope thermodynamic equilibrium?, EGU General Assembly 2026, Vienna, Austria, 3–8 May 2026, EGU26-19790, https://doi.org/10.5194/egusphere-egu26-19790, 2026.