Soil CO₂ Emissions as Indicators of Fluid Pathways in Volcanic–Tectonic Environments: Insights from Vulcano Island

Soil CO₂ emission is a key proxy for investigating fluid migration processes associated with volcanic and tectonic activity. In particular, the analysis of the spatial distribution of geochemical anomalies represents an effective tool for identifying active structures and zones of ongoing deformation. Numerous studies have shown that faults and fracture systems play a fundamental role in controlling the localization and evolution of surface geochemical anomalies.

Vulcano Island (Aeolian Archipelago, Italy) is characterized by intense hydrothermal activity and persistent soil CO₂ emissions, providing a natural laboratory to investigate the relationships between fluid circulation and active tectonic structures. In this study, we present an integrated analysis of soil CO₂ fluxes based on results obtained from periodic surveys and continuous soil CO₂ flux records acquired at key sites across the island.

Periodic measurements are performed on fixed spatial grids, allowing the production of soil CO₂ flux maps and the identification of areas characterized by elevated degassing rates. At selected sites, the carbon isotopic composition of gases is analyzed to constrain gas sources.

These spatial datasets provide insights into the structural control exerted by the main tectonic lineaments on gas release at the surface. Continuous CO₂ flux monitoring enables the investigation of temporal variations and transient degassing signals potentially related to seismic and tectonic processes. In particular, the recent volcanic crisis at Vulcano Island, started on 2021, characterized by a marked increase in soil CO₂ flux, allowed a more detailed identification of preferential CO₂ emission pathways, highlighting zones of enhanced permeability associated with fault and fracture systems.

This work is carried out within the framework of the CAVEAT project (Central-southern Aeolian islands: Volcanism and tEArIng in the Tyrrhenian subduction system), which aims to provide a comprehensive understanding of the current geodynamics of the southern Tyrrhenian region.