Long-term analysis of Raman lidar water vapour profiles over the ACTRIS AGORA Granada station

Water vapour is a crucial and highly variable greenhouse gas in the Earth's atmosphere that plays a major role in the radiative balance, energy transport and photochemical processes. It can also affect the radiative budget indirectly through cloud formation and by altering the size, shape, and chemical composition of aerosol particles. Moreover, monitoring water vapour remains challenging due to its high temporal and spatial variability. Consequently, systematic and accurate observations of water vapour are essential to improve our understanding of its role at both local and global scales and for enhancing climate projections.

Advances in remote sensing techniques have enabled continuous acquisition of precipitable water vapour (PWV) measurements using sun/star photometry, microwave radiometry and the Global Navigation Satellite System (GNSS). Nevertheless, none of these instruments provides information on the vertical distribution of water vapour, a critical information considering that water vapour concentrations typically vary by up to three orders of magnitude between the surface and the upper troposphere. In this context, Raman lidar has demonstrated its ability to capture the spatial and temporal evolution of water vapour in the troposphere. Accurate retrievals of the water vapour mixing ratio from Raman lidar measurements rely on robust and well-characterised calibration procedures as well as on an accurate estimation of the differential atmospheric transmission term, which accounts for extinction differences between the molecular reference (nitrogen and oxygen) and water vapour wavelengths.

In this study, the lidar calibration constant was determined using a hybrid calibration method, which combines correlative PWV measurements for lidar calibration with Numerical Weather Prediction (NWP) data to reconstruct the water vapour profile within the incomplete overlap region of the lidar system. The differential transmission was estimated using an automated method to account for the aerosol contribution, based on sun photometer Aerosol Optical Depth (AOD) measurements and an exponential decay function with attitude to model aerosol extinction (Díaz-Zurita et al., 2025). Subsequently, a long-term database of water vapour profiles over the period 2009-2022 was generated, providing high vertical and temporal resolution measurements of water vapour over the city of Granada, in Southern Spain. A comprehensive statistical analysis was conducted to characterise the vertical distribution of water vapour over a 14-year period, representing the first long-term vertical characterisation of water vapour in this region. Mean interannual and seasonal water vapour profiles were derived for the entire study period, and trend analyses were performed to assess long-term variations in water vapour content in the lower troposphere. Additionally, lidar-derived PWV values were compared with those obtained from microwave radiometer and GNSS observations.

This research was funded by Grant PID2021-128008OB-I00 funded by MICIU/AEI/ 10.13039/501100011033 by ERDF/EU European Union, and by the Spanish national projects CNS2023-145435, PID2023-151817OA-I00 and Marie Skłodowska-Curie Staff Exchange Actions with the project GRASP-SYNERGY (grant agreement no. 10113163).

 

Diaz-Zurita et al. (2025).  Remote Sens. 2025, 17(20), 3444; https://doi.org/10.3390/rs17203444