T5b | Containers for final disposal of high-level radioactive waste
Containers for final disposal of high-level radioactive waste
Main Session Organizers: Anja Kömmling, Stefan Schöbel
Orals
| Thu, 18 Sep, 13:40–15:00 (CEST)|Room Studio 2
Posters
| Attendance Thu, 18 Sep, 17:20–18:20 (CEST)|Poster area
Orals |
Thu, 13:40
Thu, 17:20
Final disposal containers for HLW like spent nuclear fuel and vitrified high-level waste from reprocessing are a crucial component both for the handling and emplacement of the waste and (depending on the safety concept) as a barrier for ensuring post-closure safety of the repository. As the inventory, geology and safety concept differs from country to country, various types of containers are being developed worldwide.

The session should provide insights to national and international developments in e. g., container design, material selection, safety and design requirements, both from the regulator’s and the implementer’s perspective, on the way to long-term safe HLW repositories worldwide.

Potential contributions:
- Presentations about research projects related to HLW final disposal containers in Germany, e.g. by BASE, BAM, BGE, GNS
- Presentations about international container concepts (e. g. from Switzerland, Sweden, Czech, EURAD-2 InCoManD)

Orals: Thu, 18 Sep, 13:40–15:00 | Room Studio 2

13:40–14:00
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safeND2025-72
Ansgar Wunderlich, Amin Bannani, and Matthias Dittrich

A consortium of GNS Gesellschaft für Nuklear-Service mbH and BGE TECHNOLOGY GmbH started the joint project ELBRock in 2022 on behalf of BGE mbH. It will be completed at the end of 2025. Its main objective has been the development of initial container concepts for the deep geological disposal of high-level waste, which was pursued in a systematic, 4‑phase development process. Based on a thorough analysis of state of the art in science and technology, the legal requirements in Germany, the applicable technical regulations, and project-specific specifications (phase 1), fundamental requirements for HLW containers for crystalline host rock were derived and summarized in a requirements catalogue (phase 2).

The requirements for such containers are manifold and complex. Depending on the safety concept, the high-level waste containers, as technical barriers, and the surrounding backfill (bentonite in ELBRock), as geotechnical barriers, must safely retain radionuclides for up to 1,000,000 years. Consequently, long-term safety aspects such as criticality safety, corrosion protection, compatibility (thermic, radiological, and chemical) with the other barriers and the host rock or the preservation of mechanical integrity during final disposal are fundamental. Based on these and additional operational safety requirements, for example, suitable material pairings were compiled, evaluated, and ranked (phase 3). The three most promising combinations – outer walls made of copper, stainless steel, or nickel-based alloys, paired with baskets made of either cast iron or unalloyed steel – are currently further elaborated as "initial concepts" in the final project phase 4.

This contribution focuses on the main results for derived ELBRock concepts, indicates ELBRock scope limits, and addresses fundamental research needs.

How to cite: Wunderlich, A., Bannani, A., and Dittrich, M.: ELBRock – Development of High-Level Radioactive Waste Container Concepts for Final Disposal in Crystalline Host Rock, Third interdisciplinary research symposium on the safety of nuclear disposal practices, Berlin, Germany, 17–19 Sep 2025, safeND2025-72, https://doi.org/10.5194/safend2025-72, 2025.

14:00–14:20
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safeND2025-2
|
Ayantika Banerjee, Anja Kömmling, and Holger Völzke

The research project KAnnE aims to identify, concretize, and quantify requirements for high-level radioactive waste (HLW) disposal containers in Germany, considering potential types of host rock and repository concepts. The primary goal is to establish a transparent and comprehensible regulatory framework that accounts for different host rocks and operational phases, ensuring the safe long-term containment of radioactive waste. Given the current general legal formulation of these requirements, this study provides a systematic approach to defining them more precisely by integrating scientific and regulatory perspectives. An extensive review is conducted to gather relevant information about safety and design requirements for disposal containers in the respective types of host rock. The analysis considers host rock properties and conditions, operational repository conditions, and their impact on the container design, including key factors such as structural integrity, corrosion resistance, and shielding. Additionally, design specifications, boundary conditions, and expected loads (thermal, mechanical, radiological, chemical, and biological) are systematically reviewed, with quantified values provided where available.

The findings support a comprehensive evaluation of both quantitative and qualitative container requirements concerning potential German host rock types, waste forms, and repository concepts. By establishing a clearer basis for defining these requirements, this project serves as a foundation for further refinement, with a more detailed structuring of requirements currently in progress. Such regulatory basis allows a more targeted approach to container development and ensures a transparent evaluation within the repository licensing procedure. Additionally, it supports decision making on the most favorable container design by considering repository conditions that provide the highest level of safety over one million years.   

This contribution explains the goals and concept of the research project KAnnE, presents its preliminary findings and conclusions, and provides an outlook on the final project phase

How to cite: Banerjee, A., Kömmling, A., and Völzke, H.: Enhancing Requirements for HLW Disposal Containers and Developing Transparent Safety Evaluation Concepts in Collaboration between BAM and BASE (Research Project KAnnE), Third interdisciplinary research symposium on the safety of nuclear disposal practices, Berlin, Germany, 17–19 Sep 2025, safeND2025-2, https://doi.org/10.5194/safend2025-2, 2025.

14:20–14:40
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safeND2025-40
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Holger Völzke, Aurélien Debelle, Bojan Zajec, Andrea Cherkouk, Patrick Ganster, Fabrice Rossignol, Ursula Alonso de los Rios, Mahamed Merroun, Andressa Trentin, and Janne Pakarinen

Deep geological disposal of high-level radioactive waste (HLW) is the internationally preferred final waste management option to prevent the biosphere from radiologically relevant release of radioactive nuclides for at least 100,000 to 1 million years. Current repository concepts are based on a multi-barrier system consisting of geological, geo-technical and technical barriers as an engineered barrier system (EBS). Considered host rocks are e.g. crystalline rocks, claystone, or rock salt. In all cases disposal containers are a crucial technical barrier to safely enclose the HLW, either spent nuclear fuel (SNF) or vitrified high-level waste (VHLW) from reprocessing. Depending on the repository concept and the respective safety case disposal containers guarantee the safe confinement of their radioactive inventory not just during handling, emplacement, and potential retrieval but also during the post-closure phase of the repository for a certain period. Required container lifetimes usually vary between 1,000 and 100,000 years depending on the selected host rock and repository concept.

During container operation and their long-term disposal, they are subject to various mechanical, thermal, radiological, and geo-chemical/biological loads. Thus, mechanical stability and corrosion resistance in the long-term are among the most crucial challenges. Disposal container components lifetimes are typically calculated based on their time-dependent corrosion behaviour, with the implicit assumption that the design remains structurally stable for the required period.

Even though, the durability of several component materials subjected to corrosion processes have been previously studied in detail, the interaction of mechanical processes and corrosion calls for further study, and assessment of the impact of joint degradation modes on component lifetimes will result in a more robust and defensible safety case. Besides, as corrosion occurs in a thin interfacial surface layer between the component outermost surface and the environment, specific R&D work is required to understand the long-term performance controlled by the entire engineered barrier system (EBS) and to feed simulation and extrapolations tools by representative experimental data for validation.

Another approach to tackle the corrosion issue is to prevent and/or minimize it, thereby ensuring an even safer disposal. In this approach, materials much less prone to corrosion (e.g., copper, ceramic materials) can be used to fabricate the containers. Alternatively, protective coatings (e.g. copper coating) can be applied to current selected reference materials like steels. Both ways require validation of the materials durability under realistic, accelerated field conditions. 

The InCoManD work package 9 (Innovative and new Container/canister materials under disposal field conditions), part of the EURAD-2 European Partnership on Radioactive Waste Management (2024 – 2029), will address these issues through a collaborative project involving many countries across Europe (and beyond) with a shared goal. Building on the results of the ConCorD work package 15 (Container Corrosion under Disposal Conditions), part of the EURAD-1 programme (2019 - 2024), the InCoManD work package specifically aims to: (i) provide a better understanding of material degradation mechanisms, (ii) define optimised and innovative material solutions, (iii) develop comprehensive predictive models and common methodologies to enhance confidence in the results produced by each partner, and (iv) train new scientists in this field.

How to cite: Völzke, H., Debelle, A., Zajec, B., Cherkouk, A., Ganster, P., Rossignol, F., Alonso de los Rios, U., Merroun, M., Trentin, A., and Pakarinen, J.: Innovative Disposal Container Materials: Improved Durability and Manufacturing Feasibility, Third interdisciplinary research symposium on the safety of nuclear disposal practices, Berlin, Germany, 17–19 Sep 2025, safeND2025-40, https://doi.org/10.5194/safend2025-40, 2025.

14:40–15:00
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safeND2025-110
Aurélien Debelle, Clémence Besnard, Samuel Couillaud, Valentin Alvarez, Catherine Ellisalde, Jean-Marc Heintz, Patrick Ganster, and Fabrice Rossignol

The concept of a safe geological repository for managing radioactive waste relies on a multi-barrier system comprising both the host rock and various engineered barriers, these latter being referred to as the engineered barrier system (EBS). The robustness of the EBS depends directly on the materials used, which play a crucial role in ensuring its performance. These materials must demonstrate exceptional durability, stability, and compatibility with the host rock and the types of waste expected in the future repository. Moreover, they must remain intact over timescales ranging from hundreds to thousands of years, depending on the repository’s design.

Regardless of the repository concept, a disposal container is required to encase the primary HLW package. Currently, reference materials are primarily metals such as steel or copper. In the case of steel, particularly carbon steel, one significant drawback is the production of H₂(g) during corrosion under anoxic conditions. Minimising or eliminating this phenomenon would facilitate easier and even safer waste management within the disposal facility. This issue is a key motivation for exploring alternative solutions, such as ceramic materials, which do not generate gas when altered.

Research on ceramics as alternatives to metals began in the late 1970s and has periodically regained interest. However, the topic has largely been addressed conceptually, with few concrete research programmes dedicated to tackling this challenge. Since the mid-2000s, Andra has initiated a long-term R&D programme to assess the technical feasibility of a ceramic HLW container that meets the safety requirements of the Cigéo repository concept.

This presentation aims to provide an overview of global research activities related to ceramic options for HLW containers, with a particular focus on the Cigéo concept. Both bulk ceramics and ceramic coatings will be considered. The advantages and limitations of these solutions will be discussed, along with potential approaches to address identified challenges. It is important to note that this contribution does not seek to provide exhaustive details on all related topics but rather offers a scientific and technical overview of ongoing work in this field, which may be of interest to stakeholders in the field of radioactive waste geological disposal. 

How to cite: Debelle, A., Besnard, C., Couillaud, S., Alvarez, V., Ellisalde, C., Heintz, J.-M., Ganster, P., and Rossignol, F.: Ceramic materials as innovative solutions for the HLW disposal containers: global overview and focus on Andra's R&D programme, Third interdisciplinary research symposium on the safety of nuclear disposal practices, Berlin, Germany, 17–19 Sep 2025, safeND2025-110, https://doi.org/10.5194/safend2025-110, 2025.

Posters: Thu, 18 Sep, 17:20–18:20 | Poster area

P25
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safeND2025-95
Louisa Panjiyar, Nicolas Finck, and Christiane Stephan-Scherb

In the multi-barrier system for deep geological repositories of high-level nuclear waste, the stability of potential canister and geotechnical barrier materials are essential for long-term safety. Over time, the canister near-field is expected to become saturated with groundwater, leading to a shift in the geochemical environment from oxic – warm – unsaturated to anoxic – cool – saturated conditions. At the current status of the German site selection act, the geochemical environment as well as the electrolyte in contact with the canister and surrounding buffer material are not defined yet. However, a change in geochemical conditions over longer time is expected and it will affect the long-term behavior of the canister and buffer materials. Corrosion of the canister materials may occur, potentially altering the properties of both the canister and the buffer material.

Here we present a study on the effect of corrosion of potential canister materials on alteration of compacted Wyoming bentonite in a synthetic ground water with composition close to electrolyte compositions within crystalline host rocks. The salt concentrations of the synthetic water were calculated based on given ionic compositions of Bucher and Stober [1]. All metal coupons (cast iron type EN-GJS-400-15 and oxygen-free phosphorous copper) were ground with 600, 800 and 1200-grit SiC papers and subsequently cleaned with acetone to guarantee a defined surface state before start of exposure experiments. Metallographic pre-characterization of the coupons was performed by light optical (LOM) and scanning electron microscopy (SEM). Exposure experiments were undertaken for 1 and 3 months in compacted bentonite in tailor made corrosion cells under anoxic conditions. Granulated bentonite was uniaxially compacted to a dry density of 1.50 g/cm³. To ensure anaerobic conditions, the corrosion cells were assembled and dismantled within an Ar-filled glovebox. After the exposure experiments subsequent analysis of the physico-chemical changes at the metal/bentonite interface was performed by (µ)-X-ray diffraction (XRD), µ-X-ray-fluorescence (µXRF) analysis, SEM, LOM and Raman spectroscopy.

After exposure of cast iron (type: EN-GJS-400-15) for one month at 60 °C in compacted bentonite, changes were observed on the metal coupon and at the interface in the bentonite. The shown Raman spectra indicate the formation of mackinawite (FeS) and magnetite (Fe3O4) on the metal coupon. The same results were observed with complementary SEM-EDX analysis. Additionally, metal/bentonite interfaces after exposure for 4.5 and 7.1 years in the MaCoTe experiment at Grimsel Test Site were studied by µXRF, XRD and SEM for comparison. The impact of the observed bentonite alteration for the long-term safety will be discussed.

 

[1] Bucher, K., Stober, I. (2000). The Composition of Groundwater in the Continental Crystalline Crust. In: Stober, I., Bucher, K. (eds) Hydrogeology of Crystalline Rocks. Water Science and Technology Library, vol 34. Springer, Dordrecht.

How to cite: Panjiyar, L., Finck, N., and Stephan-Scherb, C.: Early anaerobic corrosion of potential canister material in compacted bentonite, Third interdisciplinary research symposium on the safety of nuclear disposal practices, Berlin, Germany, 17–19 Sep 2025, safeND2025-95, https://doi.org/10.5194/safend2025-95, 2025.