Record-breaking stratospheric smoke and record-breaking ozone depletion events in the Arctic and in Antarctica in 2020! Any link between smoke occurrence and ozone depletion?

The highlight of our multiwavelength polarization Raman lidar measurements during the 1-year MOSAiC (Multidisciplinary drifting Observatory for the Study of Arctic Climate) expedition in the Arctic Ocean ice from October 2019 to May 2020 was the detection of a persistent, 10 km deep aerosol layer in the upper troposphere and lower stratosphere (UTLS) with clear and unambiguous wild-fire smoke signatures. The smoke is supposed to originate from extraordinarily intense and long-lasting wildfires in central and eastern Siberia in July and August 2019 and may have reached the tropopause layer by the self-lifting process.

Temporally almost parallelly, record-breaking wildfires accompanied by unprecedentedly strong pyroconvection were raging in the south-eastern part of Australia in late December 2019 and early January 2020. These fires injected huge amounts of biomass-burning smoke into the stratosphere where the smoke particles became distributed over the entire southern hemispheric in the UTLS regime from 10-30 km to even 35 km height. The stratospheric smoke layer was monitored with our Raman lidar in Punta Arenas (53.2°S, 70.9°W, Chile, southern South America) for two years.

The fact that these two events in both hemispheres coincided with record-breaking ozone hole events in both hemispheres in the respective spring seasons motivated us to discuss a potential impact of the smoke particles on the strong ozone depletion. The discussion is based on the overlapping height ranges of the smoke particles, polar stratospheric clouds, and the ozone hole regions. It is well known that strong ozone reduction is linked to the development of a strong and long-lasting polar vortex, which favours increased PSC formation. In these clouds, active chlorine components are produced via heterogeneous chemical processes on the surface of the PSC particles. Finally, the chlorine species destroy ozone molecules in the spring season. However, there are two pathways to influence ozone depletion by aerosol pollution. The particles can influence the evolution of PSCs and specifically their microphysical properties (number concentration and size distribution), and on the other hand, the particles can be directly involved in heterogeneous chemical processes by increasing the particle surface area available to convert nonreactive chlorine components into reactive forms. A third (indirect) impact of smoke, when well distributed over large parts of the Northern or Southern hemispheres, is via the influence on large-scale atmospheric dynamics.

We will show our long-term smoke lidar observations in the central Arctic and in Punta Arenas as well as ozone profile measurements during the ozone-depletion seasons. Based on these aerosol and ozone profile data we will discuss the potential interaction between smoke and ozone.