Decoding 3-D monazite textures using LA-ICP-MS raster mapping

Texturally complex monazite grains within two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry to quantitatively determine the spatial variation in trace element chemistry with a 4-5 μm resolution (with up to 1883 analyses per grain). The maps demarcate growth zones, some of which were cryptic with conventional imaging, highlighting the 3-D complexity of monazite grains that have experienced multiple episodes of growth and resorption during high-grade metamorphism. Associated monazite trace element systematics are highly variable, both within domains interpreted to have grown in a single event, and between samples that experienced similar metamorphic conditions and mineral assemblages. This result cautions against generalised petrological interpretations being made about monazite trace element signatures as it suggests sample-specific controls. Nevertheless, by quantifying monazite textures, a related U-Pb dataset is re-interpreted, allowing ages to be extracted from a continuum of concordant data. The results reveal a ~45 Myr interval between prograde metamorphism and retrograde melt crystallisation in the study region, emphasising the long-lived nature of heat flow in high-grade metamorphic terranes. Careful characterisation of monazite grains suggests that continuum-style U-Pb datasets can be decoded to provide insights into the rates of metamorphic processes.