EMRP3.5
Open session in Paleomagnetism and Environmental Magnetism

EMRP3.5

Open session in Paleomagnetism and Environmental Magnetism
Convener: Fabio Florindo | Co-conveners: Anita Di Chiara, Saioa A. Campuzano
Presentations
| Wed, 25 May, 17:00–18:03 (CEST)
 
Room -2.31

Presentations: Wed, 25 May | Room -2.31

Chairpersons: Anita Di Chiara, Saioa A. Campuzano, Fabio Florindo
17:00–17:07
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EGU22-8839
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ECS
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On-site presentation
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Hassan Aftab Sheikh and Richard John Harrison

Real-time monitoring of particulate matter (PM) is performed by traditional air quality monitors using size-fractionated light-scattering laser photometers or gravimetric analysis. However, these quick methods do not fully characterise the particulates, in particular, the more toxic metals such as Fe. Here, we propose the use of first order reversal curves (FORCs) as a method to discriminate different sources of anthropogenic magnetic particles. FORCs is a useful magnetic characterisation technique that is sensitive to particle size, mineralogy and domain state. By measuring known sources of particulates, we hope to come up with a ‘magnetic’ proxy in a heterogenous source of PM in the air using principal component analysis (PCA). FORC fingerprints for exhaust, non-exhaust vehicular sources, resuspended dust and train-related PM are distinct, providing a cost-effective way to monitor relative proportions in the ambient air. The first set of specimens involved measuring FORCs on known, size-fractionated brake abrasion dust on an accelerating gradient magnetometer. Processed FORCs for brake dust residue specimens show a distinct combination of narrow central ridge, extending from 0 to up to 200 mT, and a low-coercivity, vertically spread multi-domain signal. Similarly, known exhaust-pipe residue samples were measured, displaying a more conventional ‘magnetite-like’ signal comprising a lower coercivity central ridge (0-80 mT) and a tri-lobate signal attributed to vortex state and/or magnetostatic interactions. Tyre and road wear samples are generally low-coercivity and vertically spread, hinting at mostly coarser, resuspended dust that has settled down. Third set of data involved measuring gravimetric specimens from London Underground. The source of magnetic particulates in fundamentally the same but different ventilation rates on platforms meant the ‘fingerprints’ were different. Principally, FORC fingerprints are sensitive to grain size, mineralogy and total magnetic content, demonstrating a low-cost approach for identifying different proportions of magnetic particulates. These data will be complemented by measurements with high-resolution microscopy such as TEM and EELS to characterise the magnetic state of particulates and add value to conventional air quality monitoring systems.

How to cite: Sheikh, H. A. and Harrison, R. J.: First order reversal curves (FORCs) as indicators of magnetic PM sources, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-8839, https://doi.org/10.5194/egusphere-egu22-8839, 2022.

17:07–17:14
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EGU22-8871
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ECS
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Presentation form not yet defined
Michael Volk, Raisa Trubko, Roger Fu, and Brendan Meade

Paleomagnetic measurements of natural remanent magnetization were – until recently -- performed on large, millimeter to centimeter-sized rock samples using classical rock magnetometers. Developments of magnetic imaging (i.e., quantum diamond microscope (QDM) and scanning SQUID microscope) allow for the measurement of individual, weakly magnetic (10-16 Am2) particle clusters within a sample. However, this increased spatial resolution adds to the complexity of the magnetic signal and requires novel approaches in analyzing the data.

Commonly, the magnetic moment of sources within a sample are analyzed by dipole inversion, meaning fitting a dipole signal to a cropped part of a magnetic map. While this gives accurate results for sources that are well separated and dipole-like in character, recovering net magnetic moments from complex maps proved difficult. 

Machine learning (ML) has been used to study a vast number of problems and has become a part of our daily lives. Here, we present the first ML model to predict net magnetic moments from magnetic maps. Our ML models consist of three simple convolutional neural networks for source declination, inclination, moment magnitude, each of which has been trained on a large (500k) synthetic map dataset. The models are tested against several datasets, varying in size, source distribution and resolution. Our models can quickly and accurately recover the magnetic moment, even for very complex (i.e., low dipolarity) maps. The accuracy of the models is < 8˚ for inclination and declination and < 10 % for moment. Surprisingly, we find little correlation in the prediction accuracy to the dipolarity of the map. These results show that ML is a promising alternative to dipole inversions, especially for maps with low dipolarity parameters, where traditional dipole inversions can fail.

How to cite: Volk, M., Trubko, R., Fu, R., and Meade, B.: Machine Learning models for Moment Magnetometry applied to High-Resolution Magnetic Maps, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-8871, https://doi.org/10.5194/egusphere-egu22-8871, 2022.

17:14–17:21
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EGU22-12541
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ECS
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Presentation form not yet defined
Annemarieke Béguin, Karl Fabian, Nathan Church, and Suzanne McEnroe

The stability and acquisition of remanent magnetization in Earth and planetary rocks is controlled by the magnetization state of magnetic particles. Magnetic properties are often characterized by magnetic grain size. Besides grain size, also stress, magnetostatic interactions, and grain shape influence and modify magnetic stability. Moreover, internal stress in magnetite may substantially affect remanence acquisition and might be responsible for enhanced remanence for which the processes are often still enigmatic.

To better understand the impact of internal stress on the efficiency of remanence acquisition, their contribution needs to be separated from the magnetostatic and demagnetizing energy contributions. Direct observations of the influences of magnetocrystalline and stress anisotropy on the magnetic behavior of magnetite are obscured by the large demagnetizing energy. A new temperature-dependent hysteresis measurement and evaluation procedure was developed by Béguin & Fabian, (2021), which allows the determination and separation of demagnetizing energy and internal stress. The validity of the method was demonstrated for a suite of synthetic magnetite samples under different stress conditions.

Here we present the first results of applying the new scaled reversible work (SRW) method to a set of natural magnetite bearing samples. We used samples with homogeneous and heterogeneous microstructures and end-member stress-free magnetite samples. The magnetic behavior as function of temperature is less ideal for the natural samples than for the previously studied synthetic magnetite samples, for example, the Curie temperatures are less distinct. Here we present how these challenges can be overcome, and present additional evaluation steps to ease the interpretation of the temperature-dependent hysteresis data.

How to cite: Béguin, A., Fabian, K., Church, N., and McEnroe, S.: Determining Demagnetization Energy and Internal Stress in Natural Magnetite Bearing Samples, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-12541, https://doi.org/10.5194/egusphere-egu22-12541, 2022.

17:21–17:28
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EGU22-6653
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Virtual presentation
Mat Domeier, Maëlis Arnould, Athena Eyster, Leandro C. Gallo, Derya Gürer, Ágnes Király, Boris Robert, Tobias Rolf, Facundo Sapienza, Grace E. Shephard, Nick Swanson-Hysell, Bram Vaes, Annique van der Boon, Lei Wu, and Yiming Zhang

The last few years have been marked by a number of motivating novel ideas and methodological advancements in paleomagnetic analysis (e.g. trans-hierarchical uncertainty propagation), observational and theoretical geodynamics, and paleogeographical modeling (e.g. optimisation and Bayesian approaches). Many of these developments offer new insights on, and/or approaches to estimating, the past motions of tectonic plates—but so far these developments have largely unfolded in isolation of one another. In November 2021 an international group of 15 young scientists with highly complementary backgrounds (spanning the aforementioned fields) gathered to explore and discuss these exciting new developments and to brainstorm strategies that may enable their integration. We anticipate that the integration of these diverse new ideas and methods will open new frontiers in plate tectonic research, and notably lead to much better-constrained paleogeographic models. In this presentation, we will share some of the insights and strategies that emerged from the workshop, including the advantages of conducting paleomagnetic analysis at the site-level, the application of emerging paleomagnetic Euler pole analysis frameworks, and the use of insights extracted from Earth-like geodynamic models (which self-generate plate tectonic behavior) to further constrain the results of these paleomagnetic methods. We also present some preliminary results of early experiments putting these strategies into practice on a paleomagnetic dataset from North America.  

How to cite: Domeier, M., Arnould, M., Eyster, A., Gallo, L. C., Gürer, D., Király, Á., Robert, B., Rolf, T., Sapienza, F., Shephard, G. E., Swanson-Hysell, N., Vaes, B., van der Boon, A., Wu, L., and Zhang, Y.: Frontiers in quantitative paleogeography and paleomagnetism, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-6653, https://doi.org/10.5194/egusphere-egu22-6653, 2022.

17:28–17:35
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EGU22-13036
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Presentation form not yet defined
Paleomagnetism of Portuguese stalagmites: advances and perspectives
(withdrawn)
Eric Font, Elisa Sanchez-Moreno, Javier Pavón-Carrasco, Luca Dimuccio, Claude Hilaire-Marcel, Bassam Ghaleb, Joana Ribeiro, Cristina Veiga-Pires, Ricardo Trindade, Joshua Feinberg, Eduardo Lima, Roger Fu, Larry Edwards, Jorge Ponte, Alexandra Pais, Lucio Cunha, and Benjamin Weiss
17:35–17:42
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EGU22-4141
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On-site presentation
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Helena Sant'Ovaia, Claudia Cruz, and Eric Font

The North of Portugal is particularly rich in metallic mineral resources, whose exploitation dates back to the 19th century. The important amount of mining wastes resulting from the tungsten mining activities deposited in tailing represent a source of pollutants that are emitted, released, or leached to the surrounding environment.  It is well documented that improper mining waste disposal will result in air, soil, and water pollution. This environmental legacy, and the contamination caused by the mining waste disposal, is far from being properly assessed, namely the impact on the soils of the surrounding areas. We studied the mining area associated with Regoufe granite where several tungsten-rich deposits occur in and around the granite body, and whose exploitation stopped in the fifties of the 20th century.

In this study, magnetic methods are used to identify ferromagnetic minerals in soils sampled in the surrounding area of Regoufe mine, which serve as tracer for anthropogenic pollutants. We measured the mass specific (χ) and frequency-dependent (Kfd%) magnetic susceptibility and we acquired isothermal remanent magnetization (IRM) curves of eight granitic soil samples from the mining area. Our results show that χ is comprised between 2.82 and 477.20 × 10-8 m3/kg, which indicates that besides diamagnetic and paramagnetic particles, ferromagnetic minerals are present in variable concentrations. Kfd%, which reflects the concentration of superparamagnetic (SP) grains, and particularly those close to the threshold SP – single domain  is relatively low and comprised between 1.21 and 2.48%, indicating a very weak contribution of SP particles. IRM curves were treated by a  cumulative Log-Gaussian (CLG) and a Skewed Generalized Function (SGG) using the the software developed by Kruiver et al. (2001) and the MAXUnMix software (Maxbauer et al., 2016), respectively. All IRM curves were fitted by using a single component with mean coercivity (B1/2) of 53.7-61.7 mT and DP of 0.27-0.29, typical of fine-grained magnetite. SIRM values are comprised between 1.69 and 14.71 × 10-2 Am2/kg, suggesting that the large variability observed in the values of magnetic susceptibility results from a heterogenous distribution of magnetite among the studied samples. The S-ratio varies between 0.989 and 0.992, indicating that magnetite is the main magnetic carrier of the studied samples. The mean coercivity (B1/2~60mT) of this magnetite population is significantly higher than the typical mean coercivity of pedogenic or detrital magnetite (Egli, 2003). DP of 0.27-0.28 are also lower than the DP values for pedogenic or detrital magnetite (typically ~0.34-0.36) pointing to the presence of authigenic magnetite resulting from the pollution of the mining waste deposits. More investigation is required to evaluate the extent of the polluted areas and their impacts on the environment.

Acknowledgements: This work is financed by the project SHS - PROJETO NORTE-01-0145-FEDER-000056, and also by national funding awarded by FCT - Foundation for Science and Technology, I.P., projects UIDB/04683/2020 and UIDP/04683/2020. References: Egli, R., 2003. J. Geophys. Res. 108, 2081. Kruiver, P.P., Dekkers, M.J., Heslop, D. 2001. Earth Planet. Sci. Lett. 189, 269–276. Maxbauer, D.P., Feinberg, J. M., Fox, D.L. 2016.  Computers & Geosciences 95, 140–145.

 

How to cite: Sant'Ovaia, H., Cruz, C., and Font, E.: Authigenic magnetite in soils: pollution fingerprints in a former wolfram mining, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-4141, https://doi.org/10.5194/egusphere-egu22-4141, 2022.

17:42–17:49
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EGU22-187
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ECS
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Virtual presentation
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Serena D'Arcangelo, Fátima Martín-Hernández, and Josep M. Parés

Magnetic properties of sediments can furnish an environmental reconstruction of the deposition time. In our study we intend to understand the climatic – paleoenvironmental conditions at the time the earliest hominins found in Europe, and especially the well-known archaeological sites at Sierra de Atapuerca, in Burgos, Spain. The sites assemblage is found in a multi-layered karstic system, and includes a number of caves filled with both interior (distal) and entrance sediments. We focused our attention on two caves, which belong to the so-called “Trinchera” (trench) sites, namely Galería and Gran Dolina. The latter has produced thousands of fossils and artefacts since 1995, when the first hominin remains were reported, and soon became a Pleistocene landmark in studies on early human settlement outside the African continent. Our already published study on Gran Dolina presents more variability of magnetic properties in cave-entrance sediments than in the cave-interior, as expected for the exterior influence on the grain size and iron oxides concentration.

Now, we start to investigate the Galería site to correlate it with the nearest cave and to better understand the paleoenvironmental context at the time early humans inhabited the area. In particular, we confined our attention to identify the magnetic minerals present into Covacha de los Zarpazos (the lower studied part of Galería) with backfield and IRM curves determined by a magnetic Variable Field Translation Balance (VFTB). This analysis allows us to individuate a more precised reconstruction of the environmental conditions of the deposition time, also with a comparison of a pollen study and X-Ray Fluorescence (XRF) in-situ study for a major precision.

How to cite: D'Arcangelo, S., Martín-Hernández, F., and M. Parés, J.: Rockmagnetic based environmental reconstruction of Galería and Gran Dolina caves in Sierra de Atapuerca (Burgos, Spain), EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-187, https://doi.org/10.5194/egusphere-egu22-187, 2022.

17:49–17:56
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EGU22-7425
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ECS
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On-site presentation
Joonas Wasiljeff, Johanna Salminen, and Joonas Virtasalo

Ferromanganese concretions are abundant in many parts of the coastal Baltic Sea and hence provide an important yet underused archive to investigate these shallow sea areas in detail. Coastal sea areas can be best described as filters, and they have a focal role in the biogeochemistry of riverine nutrients and suspended particles during their transport to open sea. Colloidal iron and manganese oxyhydroxides, originating from the surrounding catchment area and/or from adjacent anoxic sediments, accumulate and ultimately lead to the authigenic formation of ferromanganese concretions at an unusually fast growth rate, generally in low-carbon environments with limited sedimentation. The porous concretions come in various sizes and shapes, and host diverse microbial communities with reductive and oxidative metabolisms that can affect both the concretion growth and dissolution. Despite that, the specific formation mechanisms and (bio)mineralization processes of different concretion morphotypes are poorly constrained.

We have investigated the magnetic properties of Baltic Sea ferromanganese concretions of different morphotypes, depositional environments, water depths and geographical locations. While the magnetic mineral concentrations change according to salinity and water depth, the concentrations are also seemingly controlled by the concretion morphotype. Preliminary results of laboratory remanences also indicate the magnetic mineral assemblages are dominated by SD-sized ferrimagnetic particles with magnetic properties similar to those of magnetosomes. The possible presence of magnetotactic bacteria within the concretions provides novel insights into the biogeochemistry of low sediment accumulation and low-carbon coastal environments of the Baltic Sea.

This research is part of the Fermaid project, funded by the Academy of Finland grant 332249.

How to cite: Wasiljeff, J., Salminen, J., and Virtasalo, J.: Magnetic properties of Baltic Sea ferromanganese concretions, EGU General Assembly 2022, Vienna, Austria, 23–27 May 2022, EGU22-7425, https://doi.org/10.5194/egusphere-egu22-7425, 2022.

17:56–18:03
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EGU22-8897
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Virtual presentation
Paleomagnetic research of the Upper Miocene sections of Taman Peninsula (Eastern Paratethys)
(withdrawn)
Natalia Salnaia, Yuliana Rostovtseva, and Olga Pilipenko