Fenitization associated with the Wu carbonatite dyke at Bayan Obo (Inner Mongolia, China): Implications for REE mineralization

As the world's largest rare earth elements (REEs) deposit, the giant Bayan Obo deposit accounts for more than one third of the world's REEs resources. Fenitization is an alkali metasomatism that widely occurs around the carbonatite dykes at Bayan Obo and recent studies reveal huge quantities of REEs could be transferred from the alkaline magma to fenite (Sokół et al., 2022). However, the contribution of fenitization to REE mineralization at Bayan Obo remains unclear. Here, we present bulk rock chemical compositions, in-situ chemical and C-Sr isotopic investigations of calcite and apatite together with Th-Pb ages of monazite, aiming to provide new constraints on REE mineralization during fenitization.

Carbonatite at Wu dyke is mainly composed of calcite, aegirine and barite associated with REE minerals dominated by bastnasite and parisite, which intruded into the surrounding wall rocks of quartz conglomerate. The associated fenites include the close Na-fenite and faraway K-fenite. Na-fenite contains calcite, riebeckite, aegirine and apatite with minor monazite and bastnasite in association with barite. K-fenite consists of K-feldspar and quartz with accessory riebeckite and albite. Both REE and SO₃ contents decrease from the center to the wall rocks. REE are most enriched in the centered carbonatites (up to 7.39 wt%), and Na-fenites also display strong REE enrichment (9876-22492 ppm). Of note, high-grade Na-fenite is characterized by the highest LREE concentrations among fenites, whereas HREE is most enriched in medium-grade Na-fenite. The latter is dominantly controlled by apatite, which hosts abundant HREE (118-677 ppm). Calcite from fenites displays flat REE patterns with more depleted LREE (La/Yb_N=0.28-3.02) compared to that within carbonatite (La/Yb_N=1.66-6.52). Th-Pb ages of monazite from fenites cover a wide range from 420 Ma to 1.27 Ga, which suggests these fenites have also undergone the early Paleozoic hydrothermal alteration. In-situ Sr and C isotope analyses of calcite from carbonatite define a limited range (⁸⁷Sr/⁸⁶Sr=0.70344 to 0.70358 and δ¹³C=-4.36 to -5.1 ‰), which are consistent with a mantle origin . ⁸⁷Sr/⁸⁶Sr and δ¹³C values for calcite within Na-fenite show larger variations of 0.70358 to 0.70620 and -4.92 to -9.87 ‰, respectively. Negative shift in δ¹³C values suggest degassing through the fenitizing reaction of 18CO₃^2-+2Na⁺+3(Mg²⁺,Fe²⁺)+2Fe²⁺+8SiO₂+24H⁺+0.5O₂= Na₂(Mg,Fe²⁺)₃Fe³⁺₂Si₈O₂₂(OH)₂+18CO₂+11H₂O. More radiogenic Sr isotopic compositions of fenites result from both assimilation of wall rocks during fenitization and the redistribution of Sr isotopes among minerals during the Paleozoic hydrothermal alteration.

Carbonatite-exsolved fenitizing fluids result in predominant REE enrichment within Na-fenite accompanying with light and heavy REE mineralization. LREE mineralization is dominated by monazite precipitation, and HREE enrichment is mostly controlled by apatite. Sulfate is an important ligand for REE transportation and mineralization during fenitization. Barite crystallization and simultaneous precipitation of LREE-bearing minerals lead to fenitizing fluids abundant in HREE, promoting the further formation of HREE-rich apatite.

Reference:

Sokół K., Finch A.A., Hutchison W., et al., 2022. Quantifying metasomatic high-feld-strength and rare-earth element transport from alkaline magmas. Geology, https://doi.org/10.1130/G49471.1.