Underground mining is increasing in Korea, primarily due to the depletion of high quality mineral resources from surface open pit mining, and also due to the fact that environmental regulations are gradually tightened and strengthened. For sustainable mine design, safety and environmental issues are the most important factors forcing more specified and systematic guidelines to secure the stability of the mine openings and adits. However, with complex geological settings and various types of rock discontinuities, a geological mapping process to analyze the behavior of fractured rockmass is generally time-consuming. Information on the geologic structures are often collected by visual observation and analyzed based on two-dimensional drawings. Even worse, very limited and unrepresentative data are collected specially at operating mines leading to unreliable conclusions. Hence, construction of three-dimensional hydrogeological models adopting sophisticated surveying techniques has become a routine site investigation process. Laser scanners of high-end specifications are widely used in Korea. In this study, the Trimble X7 with automatic calibration and in-field registration capability has been used to collect accurate geospatial information at an underground limestone mine adopting the room-and-pillar method, with three drifts 9~12m wide and 6m high. For the two pillars of major stability concern, laser scanning was performed to obtain point-cloud data from which a total of 581 discontinuities were extracted. A discrete fracture network was simulated and the stability was evaluated based on the safety factor and displacement using a numerical model.

How to cite: Baek, H. and Kim, D.: Application of the 3-D laser scanning method for assessing the stability of fractured rockmass at an underground limestone mine in Korea, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-1750, https://doi.org/10.5194/egusphere-egu23-1750, 2023.

ROBOMINERS (Bio-Inspired, Modular and Reconfigurable Robot Miners, Grant Agreement No. 820971, http://www.robominers.eu) is a European project funded by the European Commission's Horizon 2020 Framework Programme. The project aims to test and demonstrate new mining and sensing technologies on a small robot-miner prototype (~1-2T) designed to target unconventional and uneconomical mineral deposits (technology readiness level 4 to 5) (Lopez and al. 2020).

As part of the ROBOMINERS sensor array development, a set of mineralogical and geophysical sensors are designed to provide the necessary data to achieve a “selective mining” ability of the miner to reduce mining waste production and increase productivity of a small mining machine. To achieve this, the robot should have the ability to react and adapt in real time to geological changes as it progresses through a mineralized body. This study focuses on a set of compact sensors designed for ultrahigh-resilience and continuous operation in high pressure/vibrations/temperature environment. They are based on reflectance/fluorescence measurements in the visible/near infrared range, using a broadband light source (tungsten-halogen lamps) in reflectance mode and 365nm UV LED in fluorescence mode. 

The ROBOMINERS reflectance/fluorescence spectrometer “Mk1” was developed in collaboration with Taltech University. The spectrometer is built around a monolithic spectrometer (Hamamatsu C12800MA and a wifi capable microcontroller (Arduino RP2040 Connect).. As the ROBOMINERS prototype will be operated by ROS2 (Robotic Operating System v2 - https://www.ros.org/ ), we decided to implement a Micro-ROS publisher on the microcontroller.

The first field trials of the sensor have been carried out in the entrance of abandoned mine (baryte and lead mine, Ave-et-Auffe, Belgium), with the sensor integrated directly in the propulsion mechanism of the “RM3”’ ROBOMINERS prototype. This test allowed to demonstrate the immunity of the sensors to  to shocks, water and dust with no measurable de-calibration of the spectrometer.

References.

Lopes, B. Bodo, C. Rossi, S. Henley, G. Žibret, A. Kot-Niewiadomska, V. Correia, Advances in Geosciences, Volume 54, 2020, 99–108

How to cite: Burlet, C., Stasi, G., Godon, S., Gkliva, R., Piho, L., and Ristolainen, A.: ROBOMINERS resilient reflectance/fluorescence spectrometers, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-12056, https://doi.org/10.5194/egusphere-egu23-12056, 2023.

Recently, due to the active spread of electric vehicles, the demand for batteries is increasing fast, and for this reason, the exploration for lithium that is an essential mineral for battery production, is increasing. In Korea, lithium exploration is also being conducted around deposits where lithium was identified in the past. However, most lithium mines are located in very rough terrain, so it is not easy to conduct a surface geological and geophysical exploration. Without considering complex topography, errors may occur in the inversion of surface geophysical exploration data, and in particular, it is necessary to use precise topographic information for the three-dimensional inversion. In this study, we would like to introduce a case study using high-resolution topographic data obtained from a drone-mounted LIDAR in the three-dimensional inversion of surface resistivity and IP data conducted for lithium exploration. The target area is the Boam Mine, located in the Middle East of Korea. Surface geophysical exploration was conducted along a road and ridge of the mountain, which are relatively easy to set up the survey line. Because existing topographic maps that are publically available did not include mining traces related to mining development and topographical changes formed by nearby roads, it is not adequate for the 3D inversion of surface resistivity and IP data. To acquire precise topographical information, aerial photography and LIDAR measurements using drones were performed. A numerical topographic model was constructed using the obtained high-precision DEM (digital elevation map). By applying this to the three-dimensional inversion, the distribution of the underground mineralization zone was estimated. The interpreted results were compared with the existing drilling results performed near the mine. Comparing the two results, drilling surveys using only surface geological information proceeded in the direction in which the mineralization zone did not develop. Drone LIDAR measurement is a costly exploration method and is difficult to use actively at all exploration sites. However, if three-dimensional inversion is required where the surface topography is very complex, as in this survey area, it could give more reliable inversion results.

How to cite: Son, J., Kim, C., and Bang, E.: Three-dimensional interpretation of DC resistivity/IP survey for Lithium exploration using high-precision topographic information from drone-mounted LIDAR., EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-10680, https://doi.org/10.5194/egusphere-egu23-10680, 2023.

Geological face mapping is a frequently recurring task in mining operations, the results of which have an immediate influence on the mines’ profitability, safety, and environmental impact. Hyperspectral imaging is an increasingly applied technology to improve the efficiency and accuracy of mapping tasks. The rapid and non-destructive acquisition of spectral material properties allows meaningful material information such as mineralogical surface composition to be obtained in a safe and efficient manner. The fusion product of backprojected hyperspectral data with 3D surface information (so-called “hyperclouds”) further enhances the data value by enabling easier data correction, integration, and implementation into digital archives and models. Mining environments, however, remain a challenge for operational hyperspectral mapping, particularly underground where inadequate lighting, access, and safety of operation make data collection difficult. Data processing and interpretation require expert knowledge and are typically performed semi-manually and offline. To be economically viable in such mining environments, the hypercloud technology has to mature toward autonomy and real-time delivery of results. In recent years, terrestrial autonomous platforms have entered the market that are suited to the challenging conditions of underground mining and can maneuver and navigate even in confined, uneven, and poorly lit environments. They provide optimal carriers for hyperspectral sensors, which have simultaneously evolved into lighter, faster, and more robust devices. However, implementing hyperspectral sensors as payload for terrestrial autonomous robots remains challenging, especially in terms of  technical compatibility, ensuring data quality under complex conditions,  and processing large amounts of data quickly and autonomously. In our contribution, we demonstrate the potential of autonomous terrestrial robots combined with hyperspectral technology and advanced data processing for the automation of geological mapping. We present results of hyperspectral data acquisition using an autonomous robotic platform in a confined underground mining environment and discuss strategies for adapted sensor design, autonomous validation, real-time hypercloud processing, and enhanced autonomous navigation supported by hyperspectral information. 

How to cite: Lorenz, S., Kirsch, M., Fuchs, M., Thiele, S., and Gloaguen, R.: Robot-aided autonomous hyperspectral mapping in mining environments, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-13899, https://doi.org/10.5194/egusphere-egu23-13899, 2023.

Gamma ray is routinely used for correlation, evaluation or classification of minerals and rocks on continent and ocean. Using natural gamma radiation (NGR) derived from Integrated Ocean Drilling Program (IODP) and Ocean Drilling Program (ODP), this study focuses on the correlation between lithology and REE (Rare Earth Element)-bearing sediments in two deep-sea areas, IODP Expedition 329 in the Southwest Pacific and ODP Leg 199 Sites in the Northeast Pacific basins, where values of the REEs are abundant. Deep-sea sediments are consisting mainly of clays, calcareous oozes and siliceous oozes. As a result of the correlation, the REEs prefer to the clays rather than oozes and high values of the REEs correspond with intervals of the clays where the upper sediments (0–70 mbsf) are. The clays show relatively high values of the gamma radiation and the differences between significant elements (Th, U and K) for gamma radiation, derived from geochemical analysis at every site, show two trends reflecting characteristics of regions. Therefore we suggest that the gamma radiation is fully useful for detecting REEs in the deep-sea sediments and plays a role as a predictable tool for finding quantitative REEs. 

How to cite: Lee, C., Kim, Y., Kim, Y.-M., Hong, S. K., and Hong, S.-H.: Gamma radiation for rare earth elements (REEs) in deep-sea sediments, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-4661, https://doi.org/10.5194/egusphere-egu23-4661, 2023.

Recently, the demands for energy storage minerals such as vanadium and lithium are increasing as the use of the batteries for electrical vehicles has increased. Vanadium is one of the energy storage minerals occurred in Korea. In this study, vanadium mineralized zones of the ore deposit, named as Gwanin deposit, was investigated using geophysical exploration techniques. The mineralized zone is known as vanadiferous titanomagnetite (VTM) deposit, originated from pre-cambrian igneous intrusions (850-870 m.a.), located in the northwest region of Korea. Since the vanadium has occurred along with magnetite (low electrical resistivity and high magnetic susceptibility) in the study area, geophysical exploration techniques such as magnetic and electrical resistivity surveys were employed. For magnetic exploration, the drone magnetic survey technique was used since it provides more precise and higher resolution data than any other aerial magnetic exploration techniques for relatively small and mountainous areas. In addition, electrical resistivity data were obtained from the six survey lines in the study area. 3D inversion was performed with magnetic and resistivity data. The anomaly zones of low electrical resistivities and high magnetic susceptibilities were interpreted as VTM mineralized zones from the two different inversion results. The mineralized zones were identified from the drilling investigation for overlapping locations of the anomaly zones. The results of the study have shown that magnetic and electrical resistivity techniques are very effective tools for exploring ore deposits of vanadium resource accompanied with magnetite. In the future, drone magnetic exploration technique combined with other (surface) geophysical exploration techniques would provide more effective results of precise geophysical surveys for relatively small and mountainous areas with similar ore deposit environments.

How to cite: Kim, C., Son, J., Bang, E., Park, G., and Kim, B.: Investigations of Vanadiferous Titanomagnetite Deposit using Drone Magnetic and Electrical Resistivity Surveys in Korea, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-10689, https://doi.org/10.5194/egusphere-egu23-10689, 2023.

The increasing global demand for the rare earth elements (REE), that are critical for green energy production, justifies the necessity of understanding REE ore formation processes [1]. The main type of REE mineralization is mostly found in association with carbonatites and alkaline rocks [1,2]. In addition, in some cases the REE can also reach economical levels in secondary products called supergene REE resources [3]. Primary ore mineralizations mostly are composed of mineral phases that are highly unstable and easily soluble in the near-surface conditions in time. The secondary concentration of the REE in weathering regolith into economic deposits is more favourable than those in primary igneous rocks. As the main source of global heavy-REE, weathering deposits in southern China are the most studied ores of this type [4]. Recently, because of the recent surge in REE deposit exploration and their geological importance, other potentially similar deposits are being studied worldwide. Most of these works focus on mineralogical and elemental aspects of these systems. However, those weathering (in cooperation with alteration) systems are complex and a lot of questions on their formation remain unanswered.

In this work, we focus on the isotopic characterization of regolith hosted REE deposits. To better understand their formation, we utilize stable ⁸⁸Sr/⁸⁶Sr and radiogenic ⁸⁷Sr/⁸⁶Sr ratios, which have been used widely in understanding chemical weathering [5]. Mainly controlled by the incongruent weathering of primary minerals, Sr isotopes can help to identify the sources involved and the main factors affecting regolith hosted REE deposit formation. Strontium is especially important because, as Ca and K, it occurs in different REE-bearing primary and secondary minerals such as carbonates, ancylite, apatite, clays etc.

We will present different regolith profiles’ Sr isotopic data from Asia and Africa. Combining with the elemental and mineralogical data, we will devise a formation model for regolith hosted REE deposits.

References: [1] Goodenough et al. (2016) Ore Geo. Rev., 72, 838. [2] Chakhmouradian & Zaitsev (2012) Elements 8, 347. [3] Estrade et al. (2019) Ore Geo. Rev., 112, 103027. [4] Li et al. (2019) Econ. Geol., 114, 541. [5] Pett-Ridge et al. (2009) GCA, 73, 25.

How to cite: Pourkhorsandi, H., Debaille, V., Decrée, S., de Jong, J., Yaraghi, A., Ndzana, G., Smith, M., Goodenough, K., and Kynický, J.: Radiogenic and stable Sr isotope geochemistry of regolith hosted REE deposits: a preliminary report, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-3180, https://doi.org/10.5194/egusphere-egu23-3180, 2023.

Carbonatites are known to host over 95% of light rare earth element (REE) resource, and the REEs are commonly hosted in minerals with well-established extraction methods. Most REE mineralized carbonatites are associated with hydrothermal alteration/recrystallization. Identifying the source composition and role of recrystallization is crucial for understanding the formation of the giant carbonatite-associated REE deposit. Here we report the first in-situ carbon and magnesium isotopic compositions for the hosting dolomite in the Bayan Obo deposit.

In-situ carbon isotope analyses of dolomite from the coarse-grained (CM), fine-grained (FM) and heterogeneous-grained (HM) samples show a wide range of δ¹³C values (-5.19‰ to 2.08‰), which is distinct from the common mantle-derived carbonatite and slightly overlaps the range of sedimentary carbonate. CM dolomite displays almost homogeneous carbon isotope compositions (δ¹³C=-1.29‰ to 0.16‰) with the average δ¹³C of -0.82‰. Recrystallized dolomites from both FM and HM samples vary greatly, and FM dolomite generally displays a heavier δ¹³C range (-3.94‰ to 2.08‰) compared to that for HM dolomite (-5.19‰ to 0.64‰). CM dolomite also shows relative consistent Mg isotope compositions in the range of -0.27‰ to 0.05‰ with an average of -0.10‰, which is similar to the mantle value. δ²⁶Mg values of FM and HM dolomites vary greatly from -1.18‰ to 0.06% with averages of -0.40‰ and -0.32‰, which are lighter compared to that of CM dolomite. The recrystallized dolomites (FM and HM) are characterized by depleted light REE (LREE) and increased Pb/Ce_N features compared to the pristine dolomite (CM). Moreover, the LREE depletion and Pb/Ce_N increase correlate with the lighter Mg isotope compositions. The highly variable C isotopes recorded by FM and HM dolomites (lighter or heavier compared to the pristine dolomite) involve both recrystallization and degassing. The combined in-situ Mg and C isotope compositions of the pristine dolomite suggest the Bayan Obo carbonatite sourced from the mantle previously fertilized by fluids derived from the carbonate-bearing subduction slab.

How to cite: Chen, W., Yang, F., and Lu, J.: In-situ C and Mg isotopes of dolomite from the giant Bayan Obo REE deposit: Implications for recrystallization and recycled carbonate in the source, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-4823, https://doi.org/10.5194/egusphere-egu23-4823, 2023.

Karstic bauxite deposits are the main resource of aluminum in Europe and are formed through a combination of weathering, leaching, and deposition processes known as bauxitization. Bauxites have recently been proposed as unconventional resources of rare-earth elements (REE) as well. The studied karstic bauxite deposits are located on the salt-detached Serres Marginals thrust sheet, at the external most unit of the south-central Pyrenees (Catalonia, NE Spain). The Pyrenean bauxites are found overlaying and filling karstic surfaces forming aligned pockets up to several meters thick. These deposits have been mined for more than 20 years and present high variability in SiO₂, Al₂O₃ and Fe₂O₃ contents. Here, we characterize these deposits for the first time by a combination of field geology, XRD, FTIR and XRF to determine their formation, mineralogy, and geochemistry and to understand the causes affecting their compositional variations. Field data indicate that the bauxite deposits fill a paleokarst system affecting Dogger dolostones and/or Tithonian-Berriasian limestones. XRD data indicate that the studied karstic bauxites are mainly composed of Al-rich minerals kaolinite and boehmite, in addition to the Fe-oxide hematite, and lesser amounts of the Ti-oxides rutile and anatase. The detailed study of the FTIR spectra also confirmed the presence of diaspore and dickite. XRF data confirm the presence of varying amounts of Al, Fe and Si in addition to varying low contents of REE. These results suggest that boehmite was formed first during bauxitization and later transformed to diaspore, kaolinite and finally to dickite upon metasomatism. The presence of dickite in faults and fractures provides a direct proof for such fluid circulation. Our results suggest that the mechanisms responsible of the compositional variations in karstic bauxites are rather complex and fall beyond the standard bauxitization processes. The observed metasomatism should be further assessed, since the inferred fluid-rock interactions are susceptible to affect and mobilize REE not only in the south-central Pyrenees karstic bauxites but elsewhere in similar geological settings.

How to cite: Roqué-Rosell, J., Granado, P., Martín-Martín, J. D., Ibáñez-Insa,, J., Pérez Bustos, I., Roca-Miró, R., and Jiménez Franco, A.: The metasomatism affecting karstic bauxites from the south-central Pyrenees, Catalonia (NE Spain) and its implications on the REE geochemistry in similar geological settings., EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-8008, https://doi.org/10.5194/egusphere-egu23-8008, 2023.

The rare earth elements (REE), and in particular neodymium and dysprosium, are essential for the development of renewable energy. At present the REE are sourced from either low concentration weathered granitoid (ion adsorption clay) deposits in southern China, or from high concentration carbonatite-related deposits [1], especially the World’s dominant REE mine at Bayan Obo, China, but also including the Mt Weld weathered carbonatite, Australia. Weathered carbonatites (e.g. Tomtor, Russia; Mount Weld, Australia) are some of the world’s highest grade REE deposits. As part of the NERC Global Partnerships Seedcorn fund project WREED, we have carried out preliminary investigations in weathering products from carbonatite hosted REE deposits. Three end member deposit styles can be identified – in situ residual deposits, where carbonate dissolution has generated primary REE mineral enrichment on palaeosurfaces or in karst; supergene enrichment from dissolution and reprecipitation of REE phosphates and fluorcarbonates forming hydrated phosphates or authigenic carbonate minerals; clay and oxide caps (either from in situ weathering or from soil transport from surrounding rocks) that may hold the REE adsorbed to mineral surfaces (c.f. the ion adsorption deposits). High grade weathered carbonatite deposits typically consist of supergene horizons, that may be phosphate-rich due to dissolution and re-precipitation of apatite and monazite during the weathering process (Mount Weld [2][3]), overlain by later sediments that may be REE enriched by accumulation of residual minerals (e.g. Tomtor [4]). The mineralogy of the ore zone is linked to, but distinct from, the unweathered carbonatite rock, and includes phosphates, crandallite-group minerals, carbonates and fluorcarbonates and oxides. We have carried out leaching studies, SEM examination and XPS characterisation of soil and weathered rock samples from a range of deposits. Residual and supergene processes can result in enrichments up to 100x times bedrock concentrations, with residual enrichments in particular hosted in monazite and bastnäsite. Supergene enrichment results in more complex mineralogy which may present processing challenges. Clay-rich soils have much lower REE concentrations. However, sequential leaching studies demonstrate that a significant proportion of REE are present at trace levels in the oxide fraction in residual and supergene deposits. In clay caps the easily leachable fraction of REE matches that of ion adsorption deposits and may represent a potentially easily extractable resource.

References

[1] Wall and Chakhmouradian, 2012, Elements 8, 333-340;

[2] Duncan and Willett, 1990, Geology of Mineral Deposits of Australia pp. 591-597;

[3] Lottermoser, 1990, Lithos 24, 151-167;

[4] Kravchenko and Pokrovsky, 1995, Econ. Geol. 90, 676-689;

How to cite: Smith, M., Beard, C., Watkins, I., Broom-Fendley, S., Wall, F., Cheng, X., Liu, Y., Chen, W., and Kynicky, J.: The surface chemistry of carbonatite soils: Implications for REE resources., EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-13081, https://doi.org/10.5194/egusphere-egu23-13081, 2023.