Solid organic matter (SOM) is an important component of natural sediments and plays a crucial role in providing substrate for microbial reactions and the degradation of contaminants in soil and groundwater. Knowledge about its distribution in the subsurface is crucial for the delineation of potential hotspots of microbial activity. The subsurface is, however, difficult to access, limiting our ability to reliably delineate the spatially heterogeneous distribution of SOM. Recently, the geophysical method induced polarization (IP) has been shown to be a potentially promising mapping tool, able to detect the presence of SOM. However, the mechanisms controlling IP signals in the presence of SOM are not (yet) well understood, with a handful of studies highlighting inconclusive results (Katona et al., 2021; Mellage et al., 2022; Ponziani et al., 2012; Schwartz & Furman, 2014). Moreover, a non-negligible contribution of polarization from the organic matrix can yield signals that may cause misinterpretation of other petro-physical relationships in unconsolidated sediments.

In this study, we measured the spectral IP (SIP) response of aquifer sediment cores (2 – 8 m depth) collected from an alluvial floodplain aquifer in southwest Germany. The total organic carbon (TOC) content in the cores and the cation exchange capacity (CEC) exhibit a positive correlation with the magnitude of polarization (i.e. imaginary conductivity). In addition, strong differences in the frequency dependence of the IP measurements as a function of TOC fraction were observed for the otherwise calcareous matrix devoid of other strongly polarizing mineral phases (e.g. pyrite or clay minerals). While the CEC at the site is strongly dominated by the amount of SOM, polarization is more strongly linked to SOM than CEC. We hypothesize that the weaker correlation between SOM and CEC highlights the contribution of poorly understood charge storage mechanisms within the polydisperse organic matrix that differ from polarization at mineral surfaces. Ongoing experiments with artificial soil mixtures of calcitic sand and varying fractions of peat, under controlled conditions (i.e. constant electrical conductivity of the pore fluid), will help to shed light on the controls behind our field-derived relationships. We expect that our combined field and laboratory investigations will provide insights into the petro-, or rather, organo-physical relationship between SOM and the imaginary conductivity, and thus contribute to a conceptualization of the underlying polarization mechanisms in organic matrices.

References

Katona, T., Gilfedder, B. S., Frei, S., Bücker, M., & Flores Orozco, A. (2021). High-resolution induced polarization imaging of biogeochemical carbon-turnover hot spots in a peatland. Biogeosciences, 18(13), 4039–4058.

Mellage, A., Zakai, G., Efrati, B., Pagel, H., & Schwartz, N. (2022). Paraquat sorption- and organic matter-induced modifications of soil spectral induced polarization (SIP) signals. Geophysical Journal International, 229(2), 1422–1433. https://doi.org/10.1093/gji/ggab531

Ponziani, M., Slob, E. C., Vanhala, H., & Ngan-Tillard, D. (2012). Influence of physical and chemical properties on the low-frequency complex conductivity of peat. Near Surface Geophysics, 10(6), 491–501. https://doi.org/10.3997/1873-0604.2011037

Schwartz, N., & Furman, A. (2014). On the spectral induced polarization signature of soil organic matter. Geophysical Journal International, 200(1), 589–595. https://doi.org/10.1093/gji/ggu410

How to cite: Strobel, C., Dörrich, M., Cirpka, O. A., Huisman, J. A., and Mellage, A.: Organic matter matters - The imaginary conductivity of sediments rich in solid organic carbon, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-1838, https://doi.org/10.5194/egusphere-egu23-1838, 2023.

Clays are sedimentary minerals that are ubiquitous in the Earth’s continental crust. They have remarkable adsorption, catalytic and containment properties due to their high surface charge and very large specific surface area. However, their microstructural and electrochemical properties are not completely understood. In this study, we have developed a new petrophysical model to interpret laboratory spectral induced polarization measurements on kaolinite, illite and montmorillonite muds when salinity increases (from around 0.01 mol L^-1 to 1 mol L^-1 NaCl initially). Our model considers electrical conduction in the bulk and diffuse layer waters as well as polarization of the Stern layers of illite aggregates and Stern layers and interlayer spaces of Na-montmorillonite aggregates with different shapes and sizes. Maxwell-Wagner polarization was considered as well. By fitting predicted to measured SIP spectra, we found that the basal surface of clays controls Stern layer polarization and that the interlayer space of Na-montmorillonite may polarize in the mHz to kHz frequency range. Our study is a step forward to better understand the high surface conductivity response of clays inferred from resistivity and induced polarization measurements.

How to cite: Leroy, P., Maineult, A., Mendieta, A., and Jougnot, D.: A petrophysical model for the spectral induced polarization of clays, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-6640, https://doi.org/10.5194/egusphere-egu23-6640, 2023.

In a context of energy transition and water resources crisis, studying the fluid flow in the critical zone appears to be a major issue. The O-ZNS (Observatory of transfers in the Vadose Zone, Orleans, France) site has been designed for the development of innovative tools that can characterize and monitor the dynamics of the vadose zone (VZ). The geological structure of this VZ is composed mainly by a lacustrine limestone formation located between 10 and 20 m-deep, characterized by multiscale heterogeneities (facies variations, presence of cracks, fractures, pores, cavities and karstification). In order to predict fluid flow, heat transfer, and aquifer recharge through this VZ, the limestone heterogeneities have to be integrated into geological concepts and numerical models.

This study is a key part of the O-ZNS project, as it aims at (i) understanding and classifying the microstructural and petrophysical properties at laboratory scale; (ii) predicting these properties through quantitative geophysical parameters and; (iii) developing new geophysical interpretations through coupled approaches.

From well logs analysis of O-ZNS site, we collected limestone samples from four main facies (with four samples per facies). We performed a state-of-the-art petrophysical characterization including connected and total porosity, density, and permeability measurements. Then we carried out acoustic measurements on dry and water-saturated plugs (2.5 and 4 cm diameter) with P- and S-waves at two frequencies 0.5 and 1 MHz.

The measurement results show a large dispersion of the petrophysical properties. For example, connected porosity ranges from 4 to 12 %, and density from 2,3 to 2,5 g/cm³. This dispersion of petrophysical properties is interpreted in terms of heterogeneity of the type of porosity (micro to cm pore size, presence of cracks and fracture) and mineralogy. However, it appears that the deepest facies (located at the aquifer level) is more homogenous and shows the highest porosity. This is consistent with directly observed (micro)structure from 3D sample and well scans.

Acoustic velocity results show coherent values for fractured limestone rocks. The different facies show dispersion, such as Vp varying from 4950 to 5600 m/s for the shallowest facies at 9 m-deep. Here also, the deepest facies appears to be the most homogeneous with the lowest velocities (around 4875 m/s). Thus, velocities are consistent with the petrophysical measurements and one can draw a simple relationship between the porosity, density and acoustic velocities. However, other petroacoustic relationships are necessary to better discriminate between each facies and therefore predict their microstructure and transport properties.

The following step of this work is to add electric measurements and develop petro-acoustico-electrical models and enhance our capacity to upscale these properties from the laboratory to the field.

How to cite: Yacouba, A. N., Mallet, C., Deparis, J., Leroy, P., Laurent, G., Azaoural, M., and Jougnot, D.: Petroacoustic characterization of fractured and weathered limestone from the O-ZNS Critical Zone Observatory, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-3097, https://doi.org/10.5194/egusphere-egu23-3097, 2023.

Since the great paradigmatic revolution initiated by Mandelbrot, we know that fractals are ubiquitous in nature. From coastlines to plant growth, fractal mathematics help us to describe and quantify many of nature’s properties. In the same way, the fractal theory can be applied to porous and fractured media. In recent decades, numerous research studies have shown that fractal theory provides a solid framework to describe the properties of geological media. Based on advanced physical knowledge at the microscale, it is possible to use fractal patterns to describe transport properties in porous and fractured media. Fractal laws can be applied to describe the size distribution of pores and fractures, fracture widths, and pore irregularities, but also to relate these pore sizes to pore tortuosities. In this contribution, we review the significant advances that have been made in the field of petrophysics by applying fractal mathematics to describe fundamental petrophysical properties such as porosity, permeability, electrical conductivity, thermal conductivity, and electrokinetic and electroosmotic coupling coefficients. These new petrophysical models are based on the upscaling procedure applied to different fractal objects such as the Sierpinski carpet, Koch curves, Pigeon holes, and Menger sponge, among others. Among the interesting results obtained by means of fractal-based petrophysics, one can derive transport properties of saturated or partially saturated media, above and below freezing temperature, and considering hysteretic behavior and reactive media dissolution/precipitation processes. Integrating these fractal-based petrophysical relationships into the laboratory or field-scale, numerical simulations are now opening a wide range of potential avenues for progress in near-surface and reservoir geophysics.

How to cite: Jougnot, D., Guarracino, L., Soldi, M., Rembert, F., Luo, H., Solazzi, S., and Thanh, L. D.: Predicting transport properties in porous and fractured media, how fractal-based models can help petrophysicists?, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-6657, https://doi.org/10.5194/egusphere-egu23-6657, 2023.

Access to top research equipment facilitates top research. However, the research equipment needed may not always be available within individual institutes, while access to external facilities may not in all cases be affordable. This restricts the research that any individual can do and hampers scientific breakthroughs, particularly across disciplines. To overcome this limitation, a collaborative infrastructure network was initiated: EPOS-NL (European Plate Observing System- Netherlands). EPOS-NL provides free-of-charge access to geophysical labs at Utrecht University and Delft University of Technology, both in the Netherlands, for research within rock physics, analogue modelling of tectonic processes, X-ray tomography and microscopy. These labs include capabilities for among others: A) Mechanical and transport testing at crustal stress, temperature and chemistry conditions; B) Analogue tectonic modelling, including dynamic model imaging in 2D and 3D; C) X-ray tomography at sub-µm resolution; and D) A correlative workflow for imaging and microchemical mapping, down to nm resolution. As such, these labs can provide you with the means and expertise for your research into the physical behavior of the Earth’s crust and upper mantle.

Access to EPOS-NL can be requested by applying to a bi-annual call, posted on www.EPOS-NL.nl. This involves submitting a short (1-2 page) research proposal. Research proposals are reviewed on the basis of feasibility and excellence, but generally have a high chance of success (~80% in previous rounds). Interested? Have a look on the EPOS-NL website – and apply!

How to cite: Wessels, R. and Pijnenburg, R.: Access for free: How to get free-of-charge access to Dutch Earth scientific research labs through EPOS-NL, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-2834, https://doi.org/10.5194/egusphere-egu23-2834, 2023.

Field geological studies have revealed the heterogeneous structure of fault zones down to the sub-metric scale due to the juxtaposition of rocks presenting distinct deformation intensity and physical-transport properties. However, such internal variability is not generally resolved by most seismic tomography techniques due to spatial resolution limits. Quantifying the heterogeneous internal structure of fault zones is fundamental to understand their mechanical and hydrological characteristics. In this sense, determining seismic wave velocities and related physical properties (elastic moduli, porosity and fracture intensity) within fault zones, at different observational scales, is crucial.

Here, the near-surface velocity structure of two active seismogenic fault zones located in the Central Apennines of Italy was quantified at different length scales, from laboratory measurements of ultrasonic velocities (rock samples of few centimeters, 1 MHz source) to high-resolution first-arrival seismic tomography (spatial resolution of few meters). Detailed structural mapping was conducted within the Vado di Corno and Monte Marine fault zones, two NW-SE trending structures with length of ~ 15 km and up to 1.5 km of extensional displacement. Distinct structural units separated by fault strands were recognized in the fault zone footwall blocks cutting Mesozoic dolomitic carbonates: (i) fault core cataclastic units, (ii) breccia unit, (iii) high-strain damage zone, (iv) low-strain damage zone. The single units were systematically sampled along transects orthogonal to the average strike of the faults and characterized in the laboratory in terms of directional P and S ultrasonic wave velocities, porosity and microstructures. The fault core cataclastic units were significantly “slower” (V_P = 4.5±0.4 kms^-1, V_S = 2.7±0.2 kms^-1) compared to the damage zone units (V_P = 5.6±0.6 kms^-1, V_S = 3.2±0.3 kms^-1) at short length scales (i.e. few centimeters). A general negative correlation between ultrasonic velocity and porosity was observed, with some variability within the fault core mostly related to the textural maturity (clast/matrix volume ratio) of the fault rocks and the degree of pore space sealing by calcite cements.

Multiple P- and S-wave high-resolution seismic profiles (length 90-116 m, geophone spacing 1-1.5 m) were acquired across the two fault zones at different structural sites, moving from the principal fault surface into the outer damage zone. The derived first-arrival tomography models highlighted fault-bounded rock bodies with distinct velocities and characterized by geometries which well compared with those deduced from the structural mapping. At the larger length scale investigated by the active seismic survey, relatively “fast” fault core units (V_P ≤ 3.0 kms^-1, V_S ≤ 1.8 kms^-1) and very “slow” high-strain damage zones (V_P < 1.6 kms^-1, V_S < 1 kms^-1) were recognized. These velocity ranges were significantly different from those determined in the laboratory on small samples. This apparent discrepancy could be reconciled using an effective medium approach, considering the effect of mesoscale fractures density and size distributions affecting each structural unit.

This combined study highlighted the high petrophysical variability of carbonate-hosted fault zones, with structural units characterized by sharp contacts and different velocity scaling. In particular, the persistence of compliant high-strain damage zones at shallow depth might strongly affect near-surface deformation.

How to cite: Fondriest, M., Vassallo, M., Garambois, S., Mitchell, T. M., Giuseppe, D. G., Doan, M.-L., and Voisin, C.: The heterogeneous near-surface velocity structure of carbonate-hosted seismogenic fault zones investigated at different length scales: from ultrasonic measurements to subsurface seismic tomography, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-3376, https://doi.org/10.5194/egusphere-egu23-3376, 2023.

Fractures are ubiquitous through out the Earth's upper crust and dominate the mechanical and hydraulic properties of the affected rock masses. Indeed, open fractures act as fluid conduits and, commonly, flow is controlled by larger fractures, which are, in turn, likely to be connected to smaller ones. Therefore, fracture characterization is of paramount importance for many pertinent applications, such as geothermal energy production, CO₂ sequestration, nuclear waste storage, and hydrocarbon exploration. Seismic reflection methods are useful tools for fracture characterization due to the generally high reflectivity that large fractures exhibit as a consequence of their strong mechanical contrast with the embedding intact background. The magnitude of this mechanical contrast is known to be strongly affected by fracture-to-background wave-induced fluid pressure diffusion (FPD). Conversely, the FPD effects associated with secondary connected fractures remain so far unexplored. We investigate the influence of FPD on the normal compliance and on the vertical incidence PP reflectivity of a large fracture that is hydraulically connected to smaller fractures. To this end, we use several models that consist of an infinite horizontal main fracture connected to multiple vertical secondary fractures of finite length. This fracture system is embedded in impermeable background. The individual models differ only with regard to the geometrical (e.g., length and aperture), and physical properties (e.g., permeability and bulk modulus) of the secondary fractures. For comparison, we also calculate the normal compliance and the reflectivity of an isolated infinite horizontal fracture. To assess the changes of fracture compliance due to FPD, we perform a vertical compressional oscillatory test over samples of the aforementioned models that include part of the fracture system and the embedding background. This test simulates the FPD effects that a vertically propagating P-wave generates between the main and secondary fractures. Specifically, the wave produces a pressure increase in the horizontal fracture that equilibrates as fluid flows into the secondary vertical fractures. Based on this oscillatory test, we compute the average of the vertical components of strain and stress over the main fracture, which we use to estimate its normal compliance. We then proceed to calculate the PP reflectivity at normal incidence using its inferred P-wave modulus. Our results show that both the compliance and the PP reflectivity of the main fracture increase as much as two-orders of magnitude in response to the presence of secondary fractures. We also find that the physical and geometrical properties of the secondary connected fractures have an influence on the normal compliance and reflectivity of the main fracture.

How to cite: Sotelo, E., Rubino, J. G., Barbosa, N. D., Solazzi, S. G., and Holliger, K.: Seismic reflectivity of fractures: the impact of secondary connected fractures, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-1059, https://doi.org/10.5194/egusphere-egu23-1059, 2023.

The seismic characterization of fractured geological formations is of importance for a wide range of applications throughout the Earth, environmental and engineering sciences, such as, for example, hydrocarbon exploration and production, CO­­₂ sequestration, monitoring of enhanced geothermal reservoirs, nuclear waste storage, and tunneling operations. Seismic methods are indirect in nature, and, hence, comprehensive modelling techniques are required to translate corresponding observations into rock physical properties. In this regard, numerous works have employed the theoretical framework of poroelasticity in order to explore the seismic response of particularly complex and elusive parameters of fluid-saturated fracture networks, such as their fracture density and interconnectivity. This is motivated by the fact that poroelasticity allows to account for fluid pressure diffusion effects between connected fractures as well as between fractures and their embedding background. Fluid pressure diffusion prevails when zones of contrasting compliance are traversed by a seismic wave, as this results in pressure gradients, which induce oscillatory fluid flow and, consequently, energy dissipation. This form of energy dissipation has a significant impact on seismic velocity dispersion, attenuation, and anisotropic characteristics, which are key seismic observables. While a wide range of approximations are employed to represent fracture properties in order to compute the seismic response of formations, they do tend to inherently ignore the complex interrelationships between the lengths, compliances, apertures, and permeabilities of fractures remains, as of yet, unaccounted for. In this work, we seek to alleviate this in combination with a poroelastic modelling approach to explore how length-dependent fracture scaling characteristics affect the effective seismic properties of fractured rocks. We start by revisiting canonical models with two orthogonally intersecting fractures of different lengths to analyze the interactions occurring when fractures are affected by a seismic wavefield. We then proceed to explore how scaling relations affect these results. Finally, we consider fracture networks with realistic stochastic length distributions, for which we compare the effective seismic response with and without the proposed length-dependent scaling of the fracture characteristics. Our results demonstrate that the scaling of fracture properties does indeed have a significant effect on the seismic response, as it dramatically reduces the contribution of smaller fractures to fluid pressure diffusion between connected fractures, which, in turn, affects the overall seismic characteristics of the formation.

How to cite: Quiroga, G., Solazzi, S., Barbosa, N., Rubino, J. G., Favino, M., and Holliger, K.: Effective seismic properties of fractured rocks: the role played by fracture scaling characteristics, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-8860, https://doi.org/10.5194/egusphere-egu23-8860, 2023.

Quantifying in-situ stress is crucial for predicting drilling-induced tensile fractures, wellbore failures, proper well placement, hydro-fracture treatment optimization and sand production. A comprehensive mechanical earth model incorporating pore pressure, stress state, and rock mechanical properties enable us to study the cause of failure observed in the well. The study is focused on a petroleum reservoir in Western Offshore India. In this study, an attempt is made to estimate in-situ stresses present in the field. Well-log data calibrated with available direct pressure measurements viz. Modular Dynamic Test (MDT) and Leak Off Test (LOT) data are used to predict the pore pressure and minimum horizontal stress. Vertical stress is estimated by extrapolating the density log; for minimum and maximum horizontal stress, the poroelastic approach is adopted. Key rock strength parameters were estimated using standard correlations and regional studies. Wellbore stability analysis was carried out, and the results were calibrated with the actual mud weight used. Natural fractures present in the reservoir are sensitive to stress distribution which in turn is sensitive to changes in pore pressure distribution. Many exploratory and development wells have been drilled in the area, but very few have recorded DSI (Dipole Shear Sonic Image) and FMI (Formation Micro-Scanner Image) logs. With the available log data, the study was carried out to quantify the rock mechanical parameters and the stress magnitudes of the field. The study aims to model the study area's geomechanical aspect for better prediction of drilling-induced challenges, thereby reducing NPT and optimizing drainage.

How to cite: Pradhan, S. P. and Sundli, K. C.: Mechanical Earth Modelling for Petroleum Reservoir in Western Offshore India: Tensile Failure Study, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-11037, https://doi.org/10.5194/egusphere-egu23-11037, 2023.