A similarly warm but drier Mediterranean region at the Miocene - Pliocene transition

Between 5.97-5.33 Ma, kilometre-thick evaporite units were deposited in the Mediterranean Basin during an event known as the Messinian Salinity Crisis (MSC). The MSC was characterised by a strongly negative hydrological budget, with a net evaporative loss of Mediterranean basin water exceeding precipitation and riverine runoff inputs. Despite evident proves of environmental crisis at the end of the Messinian, the Mediterranean domain still lacks quantitative estimates of temperature change across the transition from the (brackish) Lago Mare, marking the end of the Miocene, to the fully marine Pliocene. Here we reconstruct continental mean annual temperatures (MAT) using branched glycerol dialkyl glycerol tetraether (brGDGT) biomarkers for the time period corresponding to the MSC Stage 3 (5.55-5.33 Ma) and compare them with continental temperature values obtained from Δ₄₇ clumped isotope geochemistry measured on paleosol carbonate nodules found at few locations in the Mediterranean basin. The well-preserved organic biomarkers were extracted from outcrops onshore and offshore covering a vast portion of the Mediterranean Basin; onshore (Malaga, Sicily, Cyprus) and offshore (DSDP core holes 124 and 134 from the Balearic abyssal plane, hole 374 from the Ionian Basin and hole 376 drilled west of Cyprus). Calculated MATs for the 5.55 to 5.33 Ma time interval show values around 16 to 19 ºC for the Malaga, Sicily and Cyprus outcrops. The MAT values calculated for DSDP Leg 13 holes 124, 134 and Leg 42A holes 374 and 376 are lower, around 13 to 16 ºC. Comparing the brGDGT-MAT values with Δ₄₇-MAT values from carbonate nodules, shows high congruence between both approaches. For the northern Mediterranean Δ₄₇-MAT is 24.6 ± 1.6 °C and brGDGT-MAT is 19 ± 4.8 ºC. For Cyprus Δ₄₇-MAT is 20.3 ± 1.7 °C and brGDGT-MAT is 18 ºC ± 4.8 ºC. Given the very different nature of the used paleoproxies, the similarity of the obtained MAT values provides a strong indication of their (cross)validity in sampled sections. Additionally, the measured δ¹⁸O values for the carbonate nodules used for the Δ₄₇-MAT show high δ¹⁸O of the soil water (in the range of -5 ±0.7‰) indicate highly evaporative conditions for the two onland sites where these were collected (Northern Apennines and Cyprus). We conclude that between 5.55 to 5.33 Ma the temperatures in the Mediterranean region were similar to present-day conditions, yet the region has suffered from excess evaporation as indicated by combined high δ¹⁸O values from (inorganic) carbonate nodules and δ²H values from (organic) biomarkers.