Quantifying the role of interactive chemistry on the anthropogenic effective radiative forcing in Earth System Models

Many global climate and Earth system models that participated in CMIP6 did not include fully interactive chemistry mechanisms mainly due to the large associated computational cost of these schemes. A number of studies have recently highlighted the potential importance of enhanced aerosol-chemistry-climate coupling and associated feedbacks for the anthropogenic effective radiative forcing (ERF) of a number of key climate forcing agents such as aerosols (Thornhill et al., 2021), methane (O’Connor et al., 2022) and ozone. The different levels of complexity in both aerosol and chemistry schemes in CMIP6 models has been highlighted as a leading contributor to the large inter-model diversity in the ERF of aerosols and trace gas species (Thornhill et al., 2021). To this end, as part of the EU Horizon project, ESM2025, advanced stratospheric-tropospheric chemistry schemes have been developed and implemented in 2 ESMs, CNRM-ESM and NorESM2, for the first time. Dedicated experiments have been conducted to determine the pre-industrial (1850) to present-day (2014) ERF with these updated models and the UKESM1.1 model, to assess the impact of fully interactive chemistry on the ERF of key forcing agents. In UKESM1.1, which already includes interactive chemistry, the interactive chemistry scheme is switched off and run with a much-simplified aerosol-chemistry mechanism driven by prescribed oxidant fields. We argue the improved realism of representing these aerosol-chemistry-climate interactions is essential for improved cross-model consensus on the magnitude of anthropogenic ERFs of aerosol and key trace gas species.

References:

Thornhill et al., Effective radiative forcing from emissions of reactive gases and aerosols – a multi-model comparison, Atmos. Chem. Phys., 21, 853–874, https://doi.org/10.5194/acp-21-853-2021, 2021.

O’Connor et al., Apportionment of the pre-industrial to present-day climate forcing by methane using UKESM1: The role of the cloud radiative effect. Journal of Advances in Modeling Earth Systems, 14, e2022MS002991. https://doi.org/10.1029/2022MS002991, 2022.