Petrogenesis of Neoproterozoic high-K intrusion in the southwestern Yangtze Block, South China: Implication for the recycled subducted-sediment in the mantle source

Abstract: The study of K-enriched intrusive rocks is essential for deciphering mantle metasomatism beneath active continental arcs. In this contribution, high-precision zircon U‒Pb‒Hf isotope, whole-rock geochemistry, Sr‒Nd isotope, and mineral chemistry analyses were performed to evaluate the petrogenesis and geodynamic system of the Yunnongfeng intrusion on the southwestern margin of the Yangtze Block. The Yunnongfeng intrusion consists of a high-K to shoshonitic rock assemblage with variable lithology from gabbro-diorite to granite. Zircon U‒Pb dating gives concordant crystallization ages of ca. 782.5 ± 3.8 Ma for gabbro-diorite, ca. 774 ± 4.1 and 776 ± 4.1 Ma for diorite, ca. 770 ± 4.7 Ma for quartz monzonite, ca. 763 ± 3.4 Ma for quartz syenite, and ca. 764 ± 16 Ma for granite. These samples also show similar Sr‒Nd, and Lu‒Hf isotopic compositions, implying a common magma source. The similar crystallization age and regular variation of major and trace element contents suggest that these rocks were formed through fractional crystallization of cogenetic primitive mantle magmas. The enriched εNd(t) (−5.7 to −5.1) and εHf(t) (−6.7 to −1.2) values, high Rb/Y and Th/La ratios, slight Nd‒Hf decoupling, and high-K and Th contents demonstrate that their lithospheric mantle source was enriched by slab-related fluid and sediment-related melt. The samples also exhibit remarkable enrichment in large-ion lithophile elements and depletion in high-field-strength elements, indicative of subduction-related arc magmatism. Taking into account previous studies, we suggest that the western margin of the Yangtze Block experienced a long-term subduction process during the Neoproterozoic, and the Yunnongfeng intrusion formed in an extensional back-arc basin. Based on the K-enriched mafic‒intermediate rocks from the western margin of the Yangtze Block commonly show high K₂O/Na₂O, Rb/Sr, low Ba/Rb ratios, and enriched εNd(t) values, our study, coupled with numerous previous reports, proposes that the K-enrichment resulted from the breakdown of phlogopite, owing to subduction-related sediment melt reacting with peridotite in the mantle source area.

Keywords: Potassium-enriched intrusive rocks; Southwestern Yangtze Block; Fractional crystallization; Lithospheric mantle; Sediment melt