Mineralogy and P-T condition of Algoma type Banded Iron Formation from Bundelkhand Craton, North-Central India and their implications

The BIFs in Bundelkhand Craton occurred as a discontinuous unit within the east-west trending Bundelkhand Tectonic Zone (BTZ). The BIFs were associated with amphibolite, calcsilicate rocks, and quartzite. The BIFs were massif in appearance in the Mauranipur (east of Bundelkhand Tectonic Zone, BTZ) that graded to layered variety in the Babina area (west of the BTZ).

The Bundelkhand BIFs were characterized by 45 to 55 wt.% SiO₂ and 44 to 55 wt.% Fe₂O₃ content. The Al₂O₃ content was usually low and varied between > 1 to 3 wt%. Barring a few samples, the MnO and CaO contents are < 1 wt.%. The higher MnO (~ 3.70 wt.%) and CaO (~ 1 wt.%) implied a different redox condition and involvement of CaCO₃ in the early stages of BIF formations. The ΣREE content of Bundelkhand BIFs varied between 10 – 38 ppm, with Eu/Eu*_SN values between 1.1 to 1.5. Geochemically, the BIFs were classified as Algoma-type BIFs deposited by low-temperature hydrothermal fluids. Monoclinic amphiboles, quartz and garnet were the dominant silicate phase for Mauranipur BIFs. Hornblende was present with monoclinic amphibole in the garnet-absent BIFs. Isolated grains of magnetite were dispersed throughout the Mauranipur BIFs. In contrast, alternate hematite and SiO₂-rich layers with locally developed low-T amphiboles characterized Babina BIFs. The Fe-rich oxides were mostly hematite. Mineral microstructure and P-T pseudo-section modeling implied Minnesotaite and Fe-Ca carbonate phases were the primary minerals in BIFs, deposited at temperature ~ 200°C at 0.05 to 0.1 GPa. The primary minerals experienced dehydration and decarbonization reactions, leading to the stabilization of amphibole and garnet at a temperature of ~450°C and pressure of 0.1—0.2 GPa. When plotted in a P-T diagram, the increase in temperature corresponds to tectonic activity and plutonism, leading to micro-bock accretion and growth of Bundelkhand Craton.