Silicate+metal worlds like Earth form hot owing to gravitational heating from accretion and differentiation, and intrinsic radioactive decay. Concurrent cooling sets off a chemical and mechanical cascade wherein siderophile elements (Fe+Ni) form a metallic core, and lithophile elements (Mg, Si, Al, Ca, Na, etc.) partition into mantle and siliceous crust. The outcome is a rocky surface beneath an outgassed fluid envelope composed of atmophile elements and compounds (CO₂, H₂O, H₂, etc.). In its first 500 Myr (q.v. Hadean eon), Earth’s crust co-existed with liquid water; it was molded by volcanism, affected by late accretion bombardments and harbored diverse hydrothermal systems. Volcanism and differential buoyancy of the crust mandates the presence of scattered emergent landmasses. Such Hadean surfaces could host diverse (sub-)aqueous where organic chemical ingredients became concentrated to reactivity beneath a dense atmosphere bathed by the active young Sun. Soon after planet formation, it seems proto-biochemical reactions led to full-fledged living biochemistry. We do not know whether the earliest environments for life were ideally suited for its origin, or merely just good enough to accomplish the task. The inferred complexity for even the minimum biological entity means that operative and persistent biochemistry are the most difficult developmental stages to reach.

How to cite: Mojzsis, S. J. and Medvegy, A.: Recipes for a Hadean Earth, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-1479, https://doi.org/10.5194/egusphere-egu24-1479, 2024.

Magmas from mantle plumes are potentially the best monitors of Earth's compositional and thermal evolution over time. However, their erupted products are commonly modified by syn- and post-magmatic processes and thus do not fully retain original information about their mantle sources. Such data can be recovered from melt inclusions in olivine phenocrysts in the most primitive magmas from mantle plumes. Such inclusions, shielded by host olivine, retain original isotopic and critical trace element signatures of deep mantle sources even for Archean and Hadean Eons.

We will present the results of a study of chemical and Rb-Sr isotope composition (EPMA, LA-ICP-MS and RAMAN) of melt inclusions and chemical (EPMA, LA-ICP-MS) compositions of host olivines for komatiites and plume-related picrites with eruption age from 3.3 Ga to 1 Ka.

Recent advances in in-situ split stream LA-ICP-MS measurements of ⁸⁷Sr/⁸⁶Sr ratios and trace element contents of olivine-hosted melt inclusions revealed significant mantle source heterogeneities of magmas from individual plumes. The results are confirmed by geodynamic modelling (Jain et al., this meeting).

We show that the melt inclusions of most studied mantle plumes display heterogeneous populations in age-corrected ⁸⁷Sr/⁸⁶Sr ratios and include groups with model ages more than 1 Ga older than the emplacement age. The oldest inclusion groups found in Archean komatiites correspond to Hadean (4.3±0.2Ga, Vezinet et al., in review) and Eo-Paleoarchean (3.6±0.2 Ga) model ages. These and most inclusions from studied komatiites and picrites display Nb/U, Nb/Th and Ce/Pb significantly higher than in BSE.

Evolution over time of canonical proxies of continental crust generation (Nb/U, Th/U and Ce/Pb, Hofmann et al., 1986) in mantle plumes, combined with geodynamic modelling, suggests:

• Most of the continental crust was generated in several Hadean and Archean pulses by plume-induced subduction and melting of the hydrated mafic/ultramafic crust or mantle. Hadean continental crust was subducted or/and reworked.
• Restites left after extraction of continental crust were continuously subducted to the core-mantle boundary from the mid-Hadean and later recycled in Archean mantle plumes.
• Active formation of both continental and oceanic crust in Hadean was governed by plume-induced subduction, which ceased after cold subducted material hindered the propagation of large plumes at the core-mantle boundary. After heating the recycled lithosphere at the core-mantle boundary, the process repeats, producing oscillating subduction and crustal formation in Hadean-Archean.

How to cite: Sobolev, A., Vezinet, A., Chugunov, A., Esteban, M., Batanova, V., Arndt, N., Jain, C., Sobolev, S., Asafov, E., and Valley, J.: Earth's evolution over time revealed by the Nb/U, Ce/Pb and Nb/Th ratios in the sources of mantle plumes., EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-4334, https://doi.org/10.5194/egusphere-egu24-4334, 2024.

The scarce geological record of Earth’s infancy, particularly before 3 billion years ago (Ga), is restricted to cratons, many of which likely originated as volcano-plutonic plateaus in a non-mobile lid geodynamic regime. However, this scarcity is at odds with the significant volumes of continental crust at 3 Ga that multi-proxy models of mantle depletion and crustal growth predict. This challenges the notion that plateau-type cratonic nuclei represent the predominant tectonomagmatic settings operating on the early Earth. Reconciling this paradox necessitates a “silent majority” of missing off-craton Archean crust of an uncharacterized affinity.

To investigate a potential rare remnant example of an Archean crust constructed away from cratonic nuclei, we report major and trace-element chemostratigraphic data from the 3.1 Ga Whundo Group of the Pilbara Craton, investigating the petrogenetic processes related to its formation. These data reveal three magmatic cycles of intercalated supracrustal successions comprising six groups: tholeiites, boninites, calc-alkaline BADR (basalt-andesite-dacite-rhyolite), high-magnesium ADR (including a subset of transitionally adakitic affinity), Nb-enriched basalts (NEB), and boninite-calc-alkaline hybrids. Th/Yb-Nb/Yb, Gd/Yb_N-Al/Ti_N, and Nd isotope systematics are inconsistent with contamination by felsic basement characteristic of cratonic cores, suggesting eruption onto thin, juvenile lithosphere that was only later incorporated into the Pilbara Craton.

How to cite: Vandenburg, E., Nebel, O., Cawood, P., Capitanio, F., Miller, L., Millet, M.-A., and Smithies, H.: A widespread, short-lived, off-craton subduction source for hidden crustal growth in Earth’s infancy, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-21184, https://doi.org/10.5194/egusphere-egu24-21184, 2024.

¹ Deep Space Exploration Laboratory / School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui, China.

²Department of Earth Sciences, The University of Hong Kong, Hong Kong, Hong Kong.

³Department of Geology, State Key Laboratory of Continental Dynamics, Northwest University, Xi'an, China.

* Corresponding author: wuzq10@ustc.edu.cn.

The origins of the Archean cratons were most important events in the early Earth and crucial for understanding how the early Earth worked. The mechanisms for the origins of the Archean cratons remain unclear. It is widely accepted that Archean tonalite-trondhjemite-granodiorite (TTG) plutons were derived from hydrous mafic magmas in the garnet/ amphibole stability field. Although the subduction can bring water to the mantle to produce granitic magma, the island Arc Model for the origin of continents meets fundamental challenges. The growing evidences support the plume-driven oceanic plateau models for the origin of continents. However, the lower parts of the oceanic plateau have been thought to be dry. How to generate the hydrous meta-basalt at the base of the oceanic plateau remain an open question.

Here we show that the Archean cratons resulted from the evolution of the hydrous magma ocean (Wu et al., 2023). The whole-mantle magma ocean created by the moon-forming giant impact likely evolved into an outer magma ocean and a basal magma ocean because the magma ocean would initially crystallize in the mid mantle and the basal magma ocean is denser than the overlying solid mantle. The basal MO at the beginning should contain a certain amount of water since extensive studies suggest substantial accretion of water-rich bodies during core formation. The major lower-mantle minerals have limited water storage capacity. Therefore, with progressive crystallization, the basal magma ocean becomes increasingly enriched in water. The basal magma ocean eventually becomes gravitationally unstable because of the enrichment of water. The triggered massive mantle overturns transported a large amount of water upward to the shallow part of the Earth and resulted in the major pulses of the crust and thick SCLM generations. The model can account for many observations including the source of water needed for generation of the continental crust, the major pulse of crustal growth around the end of the Archean, why the TTG and thick SCLM basically occurred in the Archean, and why only the Earth among inner planets was covered with the continental crust.

Wu, Z., Song, J., Zhao, G., & Pan, Z. (2023). Water-induced mantle overturns leading to the origins of Archean continents and subcontinental lithospheric mantle. Geophysical Research Letters, 50, e2023GL105178. https://doi.org/10.1029/2023GL105178

How to cite: Wu1, Z.: Water-induced mantle overturns and the origins of Archean cratons, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-2870, https://doi.org/10.5194/egusphere-egu24-2870, 2024.

Granitoids of the Tonalite-Trondhjemite-Granodiorite (TTG) group are a prime constituent of Archean cratons. Differences in the composition of these rocks relative to modern-day, more potassic granitoids have been proposed to reflect changes in the conditions and mechanisms of crust generation. By extension, these differences may indicate changes in the tectonic regime through geological time. Despite a continuously growing body of TTG research, consensus on TTG generation and Archean tectonic settings has not yet been reached. A remaining open question regarding TTGs is whether a reworked crustal component is present. Silicon and O isotopes have been previously employed to address this question and both isotope systems suggest that at least some TTGs indeed contain reworked material. Boron provides an alternative isotope system that can trace surface-altered material in magmatic rocks because B isotopes fractionate significantly at Earth’s surface but remain relatively unaltered at high temperatures. On modern-day Earth, the deep recycling of isotopically heavy seawater-derived B through subduction results in a diverse, but on average heavy, B isotope composition in arc granitoids. Conversely, juvenile granitoids formed in settings unrelated to subduction typically have mantle B-isotope values. These systematics are likely uniform and would apply to the Archean as well, given that Archean seawater also appears to exhibit isotopically heavy B. The B isotope system may thus be used to investigate the presence of subducted or otherwise surface-derived material in Archean granitoids. To this end, B isotopes were analyzed for a geographically and temporally spread sample set of pristine TTGs and related granitoids (n=45, from 9 different Archean terranes covering an age range of 3.78 to 2.68 Ga). This is a considerably larger and more geographically spread sample set than a B-isotope pilot study on TTGs (Smit et al., 2019), and may as such provide more globally representative results. The B isotope signature of TTGs seem to diversify over time, diverging more from mantle-derived values starting between 3.3 and 2.9 Ga. TTGs younger than 2.9 Ga exhibit up to δ¹¹B = +10.5 ± 0.2‰, and 48% of the samples have δ¹¹B values heavier than depleted mantle, whereas this is 18% for TTGs older than 3.3 Ga. The B isotope signature additionally diversifies with decreasing K₂O/Na₂O and La/Sm. Boron isotope compositions do not correlate with geochemical or petrological proxies for (post-)magmatic processes, such as weathering, metamorphism, hydrothermal alteration, or the loss of magmatic fluids, and therefore seem to be at least not significantly altered by these processes. Instead, isotopically heavy B in TTGs may be explained by the addition of a sodic and ¹¹B-rich contaminant into the TTG source. These contaminant characteristics point to seawater-altered oceanic crust, possibly introduced to the TTG source through subduction. If this is correct, the temporal trend observed in the δ¹¹B values in TTGs may reflect a shift from local and episodic to global and systematic subduction of oceanic crust in the Mesoarchean.

Smit, M.A. et al., 2019, Formation of Archean continental crust constrained by boron isotopes: Geochemical Perspectives Letters, doi:10.7185/geochemlet.1930.

How to cite: Goumans, J., Smit, M., and Musiyachenko, K.: Boron isotopes in global TTGs trace the increase in deep crustal recycling in the Mesoarchean  , EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-12762, https://doi.org/10.5194/egusphere-egu24-12762, 2024.

Oxygen is the most abundant element in the terrestrial mantle and crust. We have recently reported on a 0.2‰ δ¹⁸O decrease of continental mantle peridotites from the original primary Bulk Silicate Earth-Moon value of 5.57‰ [1] in the mid-Archean to the Phanerozoic explained by the initiation of surface recycling (linked to intensity and style of plate tectonics) sometime in the Archean. Even small variations in the volatile mass balance are critical in explaining phenomena such as the Great Oxidation Event at ~2.4 Ga that may have mantle origin. As low-δ¹⁸O subduction fluids are derived by the dehydration (and potentially oxidation) of low-δ¹⁸O interiors of subducted slabs, this work further explores this process to observe temporal changes related to the progressive input of volatile elements and potential lithospheric mantle oxidation. This study presents a record of trace elements measured in same olivines (Li, Na, Al, P, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Ga, Y, Zr) including oxidation-sensitive elemental ratios V/Sc and Zn/Fe for this collection. Prior melt-depletion of mantle peridotites, estimated using bulk Al₂O₃ content of the xenoliths, increases with age from ~25 to 35%, leading to depletion of Yb, Y, Co, Mn, Ca, P, with smaller effects on the elemental ratios.  We observe significant ranges of V/Sc (0.2-14), Li/Y and other ratios, not related to prior melt depletion that may be linked to subduction-related re-distribution of incompatible elements by subduction [2], and scattered correlation with age and δ¹⁸O values. Further trends will be analyzed during the talk after considering craton-specific domains and global trends. This work can potentially contribute to constraining a global mass balance of crustal growth and recycling based on co-variations of isotopes of a major element oxygen and trace elements in the predominant lithospheric reservoir of subcontinental mantle.

^[1]Bindeman ea, (2022) Nat Comm 13, 3779; ^[2] Doucet ea, (2020) NatGeosci 13, 511.

How to cite: Bindeman, I., Batanova, V., Sobolev, A., Ionov, D., and Danyushevsky, L.: Evolving Chemistry of Lithospheric Mantle Based on Oxygen Isotope and Trace Element Analyses of Olivines from Mantle Xenoliths across Earth’s History, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-6614, https://doi.org/10.5194/egusphere-egu24-6614, 2024.

Large swaths of juvenile crust with tonalite-trondhjemite-granodiorite (TTG) composition were added to the continental crust from about 3.5 billion years ago. Although TTG magmatism marked a pivotal step in early crustal growth and cratonisation, the petrogenetic processes, tectonic setting and sources of TTGs are not well known. Part of this issue is the general difficulty in disentangling the chemical effects of fractional crystallization and partial melting, which impedes constraining primitive melt compositions and, by extension, investigating source-rock lithology and composition. To investigate these aspects, we assessed the composition and petrogenesis of Archaean TTGs using high field-strength elements that are fluid immobile, uniformly incompatible, but differently compatible between various residual minerals. The Nb concentrations and Ti anomalies of TTGs show the overwhelming effects of amphibole and plagioclase fractionation and permit constraints on the composition of primary TTGs. The latter are relatively incompatible element-poor and characterised by variably high La/Sm, Sm/Yb and Sr/Y, and positive Eu anomalies. Differences in these parameters do not represent differences in melting depth, but instead indicate differences in the degree of melting and fractional crystallisation. Primary TTGs formed by the melting of rutile- and garnet-bearing plagioclase-cumulate rocks that resided in the roots of mafic proto-continents. The partial melting of these rocks likely was part of a causal chain that linked TTG magmatism to the formation of sanukitoids and K-rich granites. These processes explain the growth and differentiation of the Archean continental crust, without requiring external forcing such as meteorite impact or the start of global plate tectonics.

How to cite: Smit, M., Musiyachenko, K., and Goumans, J.: Archean continental crust formed by melting mafic cumulates, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-18408, https://doi.org/10.5194/egusphere-egu24-18408, 2024.

Plate tectonics exerts a first-order control on the interaction between Earth’s reservoirs. Atmospherically-altered surface materials are recycled to the mantle via subduction, while volatiles from the mantle are liberated to the atmosphere via volcanism. This cycle regulates much of Earth’s climate, ocean levels and metallogenetic processes within the continental crust. However, the interplay between Earth’s atmospheric changes and the geochemical evolution of mantle-derived magmas has remained obscure for the ancient geological history. This has led to multiple conflicting models for the crustal evolution in the early Earth.

A time-integrated evolution of the mantle-crust-atmosphere-hydrosphere interaction is yet to be fully established. For instance, secular change of the ocean and atmosphere system is evident from several proxies but the feedback of these changes to magmatic and geochemical processes in the lithosphere remain unclear. Moreover, no clear consensus has been reached on the timing of modern-style plate tectonic initiation and the evolution of net growth of the continental crust.

To explain overt and cryptic global trends in the geochemistry of magmatic rocks, a better understanding of mineral reactions and how these control trace element evolution in magmas at the lithosphere-scale is paramount. For example, the elemental and isotopic composition of apatite inclusions hosted by zircon offers a way to better understand the evolution of magmas and, to some extent, the nature of magma sources. These proxies rely on the robust data acquisition of other isotope systems with different geochemical behaviour, such as U-Pb and Lu-Hf analyses in the host zircon crystal.

A combination of methods and proxies including the elemental composition of apatite via EPMA and the oxygen fugacity based on sulphur speciation via μ-XANES of apatite inclusions was applied to ancient sub-arc magmas formed in regions akin to modern subduction zones. These magmas share a common mantle source but crystallised more than 200 million years apart (at 2.35 and 2.13 billion years ago). Importantly, they bracket the Great Oxidation Event, when atmospheric oxygen levels increased by five orders of magnitude, causing a permanent and dramatic change in Earth’s surface chemistry. As such, these sub-arc magmas were investigated as potential tracers of the interaction between Earth’s atmosphere and the mantle.

The information from several inclusions from co-magmatic rocks can then be interpreted in the light of U-Pb, Lu-Hf, trace elements and oxygen isotope analyses of the host zircon grains. Altogether, the results show a shift in oxygen fugacity of sub-arc magmas across the Great Oxidation Event. The change in oxygen fugacity is thought to be caused by recycling into the mantle of sediments that had been geochemically altered at the surface by the increase in atmospheric oxygen levels. This study opens a wide window of opportunities for the time-integrated investigation of the interaction between atmosphere and oceans with the evolving terrestrial mantle.

How to cite: Moreira, H., Storey, C., Bruand, E., Darling, J., Fowler, M., Cotte, M., Villalobos-Portillo, E. E., Parat, F., Seixas, L., Philippot, P., and Dhuime, B.: Linking early Earth’s internal and external reservoirs: a change in oxygen fugacity of sub-arc magmas across the Great Oxidation Event, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-16380, https://doi.org/10.5194/egusphere-egu24-16380, 2024.

The oxidation of iron from rocks during subaqueous alteration is a key source of the molecular hydrogen (H₂) used as an energy source by chemosynthetic organisms, which may represent some of the earliest forms of life on Earth. In the Archean, a potential source of ultramafic material available for serpentinisation reactions that release H₂ are komatiites. Komatiites are highly magnesian lavas, which contain evidence of extensive serpentinisation and magnetite (Fe²⁺Fe³⁺₂O₄) production close to the Archean seafloor. H₂ production in komatiitic compositions has been modelled and experimentally investigated; however, the natural rock record has remained unexplored. Here, we examine the geological evidence of H₂ production from the basaltic to komatiitic rock record held in Archean cratons. From the petrological investigation of thirty-eight samples of komatiitic basalt to komatiite, we identify the unique serpentinisation reaction responsible for H₂ production from these lithologies. With support from over 1100 bulk rock geochemical analyses, we directly quantify Fe³⁺ and therefore H₂ production of komatiites in the Archean. The chemical (high Mg) and physical (low viscosity flow) characteristics of komatiite flows allowed for extensive hydration and serpentinisation in oceanic plateaus, and therefore high H₂ production available to chemosynthetic early life.

How to cite: Tamblyn, R. and Hermann, J.: The geological record of H2 production in the Archean, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-3563, https://doi.org/10.5194/egusphere-egu24-3563, 2024.

The interplay of geological, chemical and biological processes that drive the oxygenation of the oceans-atmosphere of the early earth are spatially linked to the emergence of biosphere. Banded Iron Formations (BIFs) from the Archean greenstone belts form important archives for understanding the redox conditions of Archean surface environments. The Archean Dharwar craton preserves BIFs in the volcano-sedimentary greenstone belts of two distinct stratigraphic units (older Sargur Group and younger Dharwar Supergroup) corresponding to a time span of 3300-2600 Ma.  These BIFs are confined to the highest stratigraphic levels forming summits of greenstone belts.  They show alternate layers of chert and iron oxides, and petrographic data reveal diverse mineralogy including oxides, carbonate, sulphide and silicate facies. The occurrence of riebeckite and stilpnomelane in BIFs of younger Dharwar Supergroup indicates recrystallization under low-grade metamorphism. Slightly higher abundances of CaO and Al₂O₃ reveal significant influence of crustal source and precipitation of CaCO₃ during BIFs formation. Mesoscopic layers of chert and iron oxide with variable thickness suggest fluctuating redox state of surface environments. The higher enrichment of Ni (6-26 ppm) than the Cr content (3-19 ppm) with variable Sr concentrations may be attributed to feldspar breakdown during hydrothermal fluid acceleration. Trace element ratios (Y/Ho, Sm/Yb, Eu/Sm) coupled with positive Eu anomalies of the BIFs from both older Sargur Group and younger Dharwar Supergroup BIFs reveal dominant hydrothermal input in BIFs origin. The PAAS normalized REE data preclude major continental input in the origin of BIFs. The variable negative Ce anomalies imply periodic fluctuating surface environments (oxic to anoxic) at the dawn of the Great Oxidation Event close to 2340 Ma. This is consistent with the published Fe, N, and S isotope data on the BIFs of the Western Dharwar craton.

How to cite: Mukherjee, A., Mudlappa, J., Nasipuri, P., and Krishnasamy Raveendran, A.: Redox state of Archean surface environments: Insights from the Banded Iron Formations (BIFs) of the Western Dharwar Craton, Southern India , EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-3303, https://doi.org/10.5194/egusphere-egu24-3303, 2024.

The difficulty in direct differentiation of the felsic crustal components from Earth’s mantle peridotite leads to a requirement for the presence of a large amount of hydrated mafic precursor of TTG in Earth’s proto-crust, the origin of which, however, remains elusive. The mafic proto-crust may have formed as early as  4.4 Ga ago as reflected by the Hf and Nd isotopic signals from Earth’s oldest geological records, i.e., zircons. The Archean continents, primarily composed of the felsic tonalite–trondhjemite–granodiorite (TTG) suite, were formed or conserved since  3.8 Ga, with significant growth of the continental crust since  2.7 Ga. Such a significant time lag between the formation of the mafic proto-crust and the occurrence of felsic continental crust is not easily reconciled with a single-stage scenario of Earth’s early differentiation. 
Here, inspired by the volcanism-dominated heat-pipe tectonics witnessed on Jupiter’s moon Io and the resemblances of the intensive internal heating and active magmatism between the early Earth and the present-day Io, we present a conceptual model of Earth’s early crust-mantle differentiation and the formation of habitability, which involves the tremendous heat obtained by the Moon-forming giant impact. It  forces Earth to choose an Io-like tectonics, which can efficiently dissipate heat and extract a mafic proto-crust from the early mantle, then followed by an intrusion-dominating regime that could account for the subsequent formation of the felsic continents as Earth cools. The episodic heat-pipe tectonics destroy most of rocks formed during Hadean era. The cool and hard rock layer formed due to the heat-pipe tectonics is essential for the formation of habitability of the earth. By this way, the required conditions by a habitable Earth, e.g., adequate surface temperature, aqueous sphere, and towering mountains, etc., would be appeared within a surprisingly short time. Therefore, the Moon-forming giant impact is the most important reason to make a habitable Earth. It not only brought tremendous heat into Earth and forced Earth to choose the volcanism-dominated heat-pipe tectonics but also completely destroyed the proto-atmosphere to avoid over-heated situations occurred like that of Venus at present. 

How to cite: Liu, Y.: The conceptual model of the formation of Earth’s habitability, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-19385, https://doi.org/10.5194/egusphere-egu24-19385, 2024.

Banded Iron Formations (BIFs) are authigenic, marine sediments directly reflecting the chemical composition of ancient seawater. BIFs serve as prime geochemical archives for the reconstruction of Precambrian marine environments. However, due to the scarcity of well preserved Archean rocks, atmospheric and hydrospheric environmental conditions within this time frame are still incompletely understood. In particular, elemental fluxes derived from continental weathering and submarine hydrothermal fluxes that affected ancient seawater chemistry are cornerstones for our understanding of the evolution of marine habitats through time. Here we present major- and trace element concentrations in combination with Nd isotopic compositions of 13 samples of Mesoarchean Algoma-type greenschist-facies BIFs from the ca 3.0 Ga old Murchison Greenstone Belt, South Africa. Individual Fe- and Si-rich layers are monitored for sample purity based on their chemical composition. Neodymium isotope compositions, in combination with trace element contents of BIF samples with varying amounts of clastic detritus, are further used to reconstruct the Murchison depositional environment and identify the origin of dissolved and detrital components entering the ancient ocean around 3.0 Ga ago.

Eight samples with low immobile element concentrations display typical shale-normalized Archean seawater-like rare earth and yttrium (REY_SN) patterns with positive La_SN, Eu_CN, and Gd_SN anomalies, super-chondritic Y/Ho ratios, and an enrichment of heavy REY_SN over light REY_SN, implying an open marine-dominated depositional setting with contributions from submarine high-temperature, hydrothermal systems. A Sm-Nd regression line yields an age of 2.98 ± 0.19 Ga that overlaps with the proposed depositional age, suggesting negligible post-depositional alteration on the REY composition of the pure BIF layers. In contrast, higher concentrations of immobile elements (e.g., Zr) and/or non-seawater-like REY_SN patterns are characteristic for the remaining five BIF samples, indicating elevated detrital input or post-depositional alteration. A regression line of the impure BIF layers yields an age of 2.49 ± 0.15 Ga, reflecting a potential post-depositional overprinting event such as the 2.6 Ga old Limpopo orogeny. The Nd isotopic compositions of pure and impure BIF samples cover a wide range of ca. two epsilon units suggesting a mixture of weathered mafic and felsic sources for the dissolved and suspended fluxes into the Murchison ocean.

How to cite: Krayer, J., Viehmann, S., Mayer, A., Schulz, T., Koeberl, C., Hofmann, A., Jodder, J., Willbold, M., and Weyer, S.: Elemental fluxes into 3.0-billion-year-old marine environments: evidence from trace elements and Nd isotopes in banded iron formations from the Murchison Greenstone Belt, South Africa, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-5245, https://doi.org/10.5194/egusphere-egu24-5245, 2024.

The potential impact of the increased rates of tidal energy dissipation on the climate on early Earth is usually assessed in terms of the global contribution to the energy balance which is small compared to the incoming solar radiation. However, tidal energy dissipation depends strongly on the distribution of landmasses, and regional energy input could, in principle, impact the local and global climate state via changes in circulation patterns and feedbacks in the Earth system. Here we investigate these effects by calculating tidal energy dissipation for a randomly generated continental distribution representative of early Earth, and three different rotation rates, and feeding it into a coupled climate model. Despite marginal global impacts, tidal energy dissipation can have significant regional effects caused by changes in ocean circulation and amplified by the ice-albedo feedback. These effects are strongest in climate states and regions where meridional heat transport close to the sea-ice margin is altered. This suggests that tidal heating could have contributed to sustaining regions with no significant ice cover.

How to cite: Feulner, G., Biewald, B., Green, J. A. M., Hofmann, M., and Petri, S.: Spatially explicit simulations of the effect of tidal energy dissipation on the climate on early Earth, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-9476, https://doi.org/10.5194/egusphere-egu24-9476, 2024.

The operation of a hydrological cycle (i.e., exchange of water between the land, oceans, and atmosphere) has significant implications for the emergence of life. The oldest confirmed single-celled organisms at ~3.48 billion years ago (Ga) (Pilbara Craton, Western Australia) are thought to have formed in the presence of meteoric (fresh) water on emerged (subaerial) land in a hot spring environment. However, when widespread interaction between fresh water and emerged continental crust first began is poorly constrained. In this study, we use >1000 oxygen isotope analyses of Jack Hills detrital zircon to track fluid-rock interactions from the Hadean to the Paleoarchean (~4.4–3.1 Ga). We identify extreme isotopically light O (i.e., δ¹⁸O < 4.0 ‰) values older than 3.5 Ga. The data define two periods of magmatism with extreme isotopically-light O as low as 2.0 ‰ and –0.1 ‰ at around 4.0 and 3.4 Ga, respectively. Using Monte Carlo simulations, we demonstrate that such values can only be generated by the interaction of crustal magmatic systems with meteoric water. Our data constrains the earliest emergence of continental crust on Earth, the presence of fresh water, and the start of the hydrological cycle that likely provided the environmental niches required for a life less than 600 million years after Earth’s accretion.

How to cite: Gamaleldien, H., Wu, L.-G., Olierook, H. K. H., Kirkland, C. L., Kirsche, U., Li, Z.-X., Johnson, T., Makin, S., Li, Q.-L., Jiang, Q., Wilde, S. A., and Li, X.-H.: Fresh water on Earth four billion years ago, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-7106, https://doi.org/10.5194/egusphere-egu24-7106, 2024.

The results of the U-Pb-Hf-O isotope study of zircon from (meta)igneous rocks sampled in all domains of the Ukrainian Shield allow recognition of the four main stages of continental crust formation:

1. The Eoarchean stage (ca. 4000-3600 Ma). Rocks of this stage occur in the Dniester-Bouh and Azov domains. In the former, they are represented by heavily metamorphosed enderbites and mafic schists reaching an age of 3.8 Ga. In contrast, tonalites with an age of 3.67 Ga were identified in the Azov Domain. The oldest zircon reaching an age of 3970 Ma was found in the Mesoarchean metadacite in the Azov Domain. The Eoarchean rocks are rare, but their presence indicates that crust-forming processes have started already in the Eoarchean, or even in Hadean, time.

2. The second major event took place between c. 3.2 and 2.7 Ma. Rocks, formed during this age interval, compose around half of the Ukrainian Shield. Considering the long duration of this event, it may have consisted of several separate episodes. The whole set of rock associations typical for the Archean continental crust, including TTG series, greenstone belts and sedimentary basins, has been formed. Hafnium isotope composition in zircon reveals the juvenile nature of this event. Some remobilization of the older crust is also recorded from several samples.

3. Nearly half of the rock assemblages were dated at ca. 2.15-1.90 Ga. In contrast to the Archean events that resulted in the formation of apparently more or less equant terranes, the Paleoproterozoic events led to the formation of orogenic belts. These belts comprise metamorphosed in amphibolite or epidote-amphibolite facies supercrustal sequences, and abundant granitic intrusions. According to the existing models, the formation of the orogenic belts was related to the assembly of Baltica as a part of the Columbia/Nuna supercontinent. Hafnium-in-zircon and whole-rock Nd isotopes indicate the predominantly juvenile nature of these rocks, with some contamination by the Archean crust.

4. The last major stage of the Ukrainian Shield evolution was linked to the formation of the Prutivka-Novohol large igneous province, which between 1.8 and 1.72 Ga affected the whole Shield. It resulted in the emplacement of numerous mafic dykes and layered massifs, alkaline intrusions, and huge anorthosite-mangerite-charnockite-granite complexes. All igneous rocks formed during this stage reveal signs of crustal contamination, although input of moderately depleted mantle material is also evident.

Obtained isotope and geochronological data demonstrate that the growth of the continental crust in the Ukrainian Shield was episodic. The mechanisms of the crustal growth were different at different times. During both Archean events, the main mechanism was mafic underplating with further remelting and generation of TTG series, whereas greenstone belts represent the results of mantle plume activity. In the Paleoproterozoic, the main mechanism of crustal growth was the subduction of the oceanic lithosphere that led to the formation of volcanic arcs. Mantle plumes remained an important mechanism of the input of mantle-derived material into the continental crust.

How to cite: Shumlyanskyy, L.: The main stages of the Ukrainian Shield evolution and plate tectonics, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-4724, https://doi.org/10.5194/egusphere-egu24-4724, 2024.

The depleted mantle and the continental crust are largely geochemically and isotopically complementary. However, the question of when the depleted mantle reservoirs developed on Earth remains a topic of considerable debate. In this study, we report the existence of a ca. 3.8 Ga detrital zircon from the quartzite of the Paleoproterozoic Songshan Group in the southern North China Craton. In situ zircon hafnium isotopic characteristics of the 3.8–3.2 Ga detrital zircons indicate the presence of source rocks as old as ca. 4.5 Ga in the southern North China Craton. Together with the global zircon U-Pb-Hf isotope dataset from the North China Craton, Jack Hills, Acasta as well as available μ¹⁴²Nd values of ancient rocks from Archean craton worldwide, the new results indicate that the silicate Earth has differentiated at 4.5–4.4 Ga almost immediately after accretion, developing continental crust and a complementary depleted mantle reservoir at that same time.

How to cite: Si, B., Diwu, C., and Si, R.: Eoarchean-Paleoarchean crustal material in the southern North China Craton and possible mantle reservoir of early Earth, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-406, https://doi.org/10.5194/egusphere-egu24-406, 2024.

An Archean ancestral landmass of Columbia supercontinent is a matter of concern to geologists. A single supercontinent called “Kenorland” or several supercratons have been mainly proposed, but more evidence from geological records and palaeomagnetism argue for the latter supercraton solution, in which two long-lived supercratons Sclavia and Superior were recently reconstructed. Studies has shown that the Northern China blocks, including the North China and Tarim cratons, the Alxa, Quanji blocks, were involved in the reconstruction of Columbia. However, their affinity in Archean supercratons remained little constrained. Owe to the lack of reliable palaeomagnetic data old than 1.8 Ga, the geological piercing points in these blocks could allow us to figure out the question. Then, compilation and comparison of Neoarchean–early Paleoproterozoic magmatism, metamorphism, and sedimentary records, have been conducted among these blocks. As a result, 2.4-2.2 Ga magmatism and khondalite-like sedimentary sequence may be used as indicators of the affinity of these blocks in northern China. Consequently, the Kuruktag Block, Quanji Block, Alxa Block, TNCO, Khondalite Belt have similar evolutionary history during the Neoarchean-Paleoproterozoic, suggesting their close affinity at that period. Besides, the North China craton and Dharwar craton of India shield were proved to be connected during the Archean-Proterozoic. And latest study indicate the Dharwar craton was one of the Sclavia supercraton. Therefore, we speculate that during the Neoarchean–early Paleoproterozoic, the Kuruktag-Quanji-Alxa-TNCO-Khondalite Belt link was close to the Dharwar craton in Sclavia supercraton. The absence of Siderian glacial event (ca. 2.4 Ga) in the Alxa, Quanji, Kuruktag blocks and TNCO, Khondalite Belt of the North China craton rule out the link with Superia, which is common in Superia supercraton. Further geological and paleomagnetic studies are required to constrain the above hypothesis, the relation between these blocks clusters and other cratons, which is crucial to understand the origins of blocks in northern China.

How to cite: Zhang, Q. and Yao, J.: Paleogeographic affinity of Northern China block clusters in Archean-Paleoproterozoic supercraton solution, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-2507, https://doi.org/10.5194/egusphere-egu24-2507, 2024.

The position of the Tarim craton within the Rodinia supercontinent has long been the focus of scientific debate, with competing models varying from internal to external positions. The Altyn belt in the southeast Tarim margin records an extensive Neoproterozoic magmatic-sedimentary successions which likely recorded the convergence of Tarim to Rodinia. Thus, we here investigated the granitoids exposed in the Kuoshi-Kalaqiaoka and Tula areas in the eastern and western segment of the South Altyn belt. We present new field geology, zircon U–Pb–Hf–O isotopes and H₂O, and whole rock geochemistry data from these granitoids. Zircon U–Pb data yielded ages of 914 ± 3.9 Ma for the Tula granite, 919 ± 5.2 Ma and 932 ± 6.5 Ma for the Kuoshi granite. The Tula and Kalaqiaoka granite samples mostly display high ACNK values that are typical of S-type granitoids, consistent with the presence of Al-rich minerals, such as garnet and muscovite. In addition, the Tula granite have higher zircon δ¹⁸O (7.62 to 10.85‰, peaked at 8.9‰) and lower εHf(t) (-4.0 to +0.3) values, along with lower H₂O content (medium values at 102 and 251 ppmw), indicating that the primary magmas were generated from recycled ancient crust in a water-deficient syn-collisional setting, with minor juvenile contribution. On the other hand, the Kuoshi granite have high Sr (169–259 ppm), Sr/Y (17.85–19.33) and (La/Yb)_N (30–49) ratios that are indicating of adakitic affinity. The Kuoshi granite are also characterized by lower δ¹⁸O (4.15 to 9.81‰, peaked at 8.2‰) and εHf(t) values(−2.4 to 0.6), along with higher H₂O content (medium values at 255 and 795 ppmw) and MgO. These signatures suggest that the Kuoshi pluton was formed by recycling ancient crust and subducted continental crust. Overall, the granitoids across the South Altyn belt reflect a transformation of tectonic regime from water-enriched subduction setting to water-deficient syn-collisional setting. Moreover, the Hf isotopes evolution tend of the early Neoproterozoic granitoids and Suoerkuli Group across the South Altyn belt also suggest a transformation from slab retreat to syn-collision in the early Neoproterozoic. Therefore, overall data and field relations across the Altyn belt indicate an early Neoproterozoic magmatic-sedimentary successions that are similar to that of the Eastern Ghats Belt in India. Given the available paleomagnetic data and detrital zircon age patterns, we conclude a position of the Tarim craton between Australian and North India block in the periphery of Rodinia, close to East Antarctica as well. This research was supported by NSFC Projects (42322208 and 41972238), National Key Research and Development Programs of China (2022YFF0802700 and 2023YFF0803604) and Hong Kong RGC GRF (17308023).

How to cite: Li, W., Yao, J., Zhao, G., and Han, Y.: Reconstruction of the Tarim craton within Rodinia: constraints from magmatic- orogenic records in the Altyn belt, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-3114, https://doi.org/10.5194/egusphere-egu24-3114, 2024.

The Isua and Tussaap supracrustal belts of the Itsaq gneiss complex, southwestern Greenland, form the largest and best-preserved exposure of Eoarchean supracrustal materials on Earth. Previous studies have almost exclusively focused on the ∼35-km-long, arc-shaped Isua supracrustal belt and adjacent ca. 3.8–3.7 Ga meta-tonalite bodies, which are the basis for competing Archean tectonic regime interpretations (i.e., plate versus heat-pipe tectonics). In this study, we performed geologic field mapping of the seldom-explored Tussaap supracrustal belt, located ~11 km south of the Isua supracrustal belt, to better constrain its litho-structural framework and test the predictions of existing Eoarchean tectonic models. Observations from this study and previous works show that the Tussaap supracrustal belt consists of a east-northeast-striking, ~12-km-long and <1-km-wide, mostly continuous belt of greenstone rocks flanked to the north and south by ca. 3.8 Ga meta-tonalite. Lithologies of the Tussaap supracrustal belt consist of interlayered garnet ± staurolite ± sillimanite paragneiss, felsic schist, garnet mafic schist, amphibole-rich garbenschiefer, and minor pegmatite bodies and meta-ultramafic rocks. The northern and southern contacts between the Tussaap supracrustal belt and meta-tonalite are ~100-m-wide transitional zones featuring interlayered and folded meta-tonalite and greenstone rocks that increase in abundance towards each lithologic unit. Both the Tussaap supracrustal belt and adjacent meta-tonalite feature well-developed, southeast-dipping foliation and southeast-plunging stretching lineation (average 162° trend, 40° plunge). Macroscopic sheath and often rootless, disharmonic folds with hinges parallel to stretching lineation occur throughout the study area. In contrast with previous interpretations, no discrete tectonic discontinuities (i.e., brittle faults and ductile shear zones) were observed within the Tussaap supracrustal belt and meta-tonalite. Similarly, no apparent metamorphic field gradient was observed in the study area. This litho-structural framework is consistent with that of the Isua supracrustal belt and meta-tonalite bodies to the north, indicative of spatially-uniform strain and metamorphism. Based on our preliminary observations, the Archean development of the region can be explained by uniform subvertical shearing and folding of an interlayered volcanic-intrusive sequence (i.e., heat-pipe tectonics). Additional structural, geochronologic, and geochemical analyses of the Tussaap supracrustal belt and meta-tonalite are required to further elucidate their emplacement and metamorphic histories and differentiate end-member models of Archean tectonics.

How to cite: Haproff, P., Webb, A., Leung, C. Y. E., Hauzenberger, C., Zuo, J., and Ramírez-Salazar, A.: Litho-structural framework of the Eoarchean Tussaap supracrustal belt, Itsaq gneiss complex, southwestern Greenland, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-1792, https://doi.org/10.5194/egusphere-egu24-1792, 2024.

The BIFs in Bundelkhand Craton occurred as a discontinuous unit within the east-west trending Bundelkhand Tectonic Zone (BTZ). The BIFs were associated with amphibolite, calcsilicate rocks, and quartzite. The BIFs were massif in appearance in the Mauranipur (east of Bundelkhand Tectonic Zone, BTZ) that graded to layered variety in the Babina area (west of the BTZ).

The Bundelkhand BIFs were characterized by 45 to 55 wt.% SiO₂ and 44 to 55 wt.% Fe₂O₃ content. The Al₂O₃ content was usually low and varied between > 1 to 3 wt%. Barring a few samples, the MnO and CaO contents are < 1 wt.%. The higher MnO (~ 3.70 wt.%) and CaO (~ 1 wt.%) implied a different redox condition and involvement of CaCO₃ in the early stages of BIF formations. The ΣREE content of Bundelkhand BIFs varied between 10 – 38 ppm, with Eu/Eu*_SN values between 1.1 to 1.5. Geochemically, the BIFs were classified as Algoma-type BIFs deposited by low-temperature hydrothermal fluids. Monoclinic amphiboles, quartz and garnet were the dominant silicate phase for Mauranipur BIFs. Hornblende was present with monoclinic amphibole in the garnet-absent BIFs. Isolated grains of magnetite were dispersed throughout the Mauranipur BIFs. In contrast, alternate hematite and SiO₂-rich layers with locally developed low-T amphiboles characterized Babina BIFs. The Fe-rich oxides were mostly hematite. Mineral microstructure and P-T pseudo-section modeling implied Minnesotaite and Fe-Ca carbonate phases were the primary minerals in BIFs, deposited at temperature ~ 200°C at 0.05 to 0.1 GPa. The primary minerals experienced dehydration and decarbonization reactions, leading to the stabilization of amphibole and garnet at a temperature of ~450°C and pressure of 0.1—0.2 GPa. When plotted in a P-T diagram, the increase in temperature corresponds to tectonic activity and plutonism, leading to micro-bock accretion and growth of Bundelkhand Craton.

How to cite: Raza, M. B. and Nasipuri, P.: Mineralogy and P-T condition of Algoma type Banded Iron Formation from Bundelkhand Craton, North-Central India and their implications, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-2992, https://doi.org/10.5194/egusphere-egu24-2992, 2024.

Iron Formations (IF) are economically significant sedimentary rocks primarily formed in the Precambrian evolutionary history of the Earth. In the Precambrian period, Iron Formations were deposited within marine sediments on stable continental margins (superior-type) and in association with volcanic rocks and many volcanic Massive Sulphide (VMS) deposits (Algoma-type). Most scientists agree that for BIF to form, photosynthesis and changing ferrous iron from seawater into mixed-valence iron (oxy-hydroxide) oxides and carbonate phases during oxidation are needed.
The present study is based on the Superior-type BIFs from the Girar Supracrustal Belt of Southern Bundelkhand terrane, which mainly consists of Neoarchean K-rich granitoids with a minor volume of a schist complex, TTG, sanukitoids, and mafic-ultramafic layered intrusion. The Girar schist (metasedimentary) belt is mostly made up of two types of rocks: (i) quartzite and (ii) BIFs. There are also some dolomitic marble and chlorite schist lenses close to the quartzite/BIF boundary. The BIFs consist of thick-bedded quartz and hematite with magnetite. The quartzites display low-grade metamorphism of fuchsite- and hematite-bearing quartz arenite with thick meta-argillite (schist) laminae and lesser quartz pebble conglomerates.
P-T pseudosection modelling indicates that Fe-carbonates and iron-oxyhydroxides (minnesotaite) are the primary phases that stabilize at 200 – 250 ^O C, 0.1–0.15 GPa. Subsequently, the low-temperature phases experienced dehydration and decarbonisation reactions with an increase in temperature, leading to the stabilisation of hematite and magnetite. The absence of orthopyroxene in the BIFs suggests these rocks suffer amphibolite facies
metamorphism, which is uncommon in generally undeformed superior-type BIFs.

How to cite: Bisht, B. P. S.: Mineralogy and P-T conditions of Superior- type Iron Formation fromBundelkhand Craton, North Central India, EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-3109, https://doi.org/10.5194/egusphere-egu24-3109, 2024.

In recent times, the Archaean geological record of the Singhbhum Craton has been scrutinized regarding early Earth crustal processes, tectonics, magmatic-detrital zircon geochronology, early life research, and Fe-Mn mineralization associated with volcano-sedimentary successions. However, many of these studies are hampered by a lack of a basic stratigraphic framework of the various litho-stratigraphic units, complicating our understanding of the overall Archaean geology of the Singhbhum Craton. Here, we share first-hand information on the Palaeoarchaean greenstone belts and Meso-Neoarchaean intracontinental volcano-sedimentary sequence of the Singhbhum Craton.

New magmatic zircon U-Pb ages determined from felsic volcanic rocks of the Badampahar Group are represented by their crystallization age at c. 3.51 Ga. Intrusive granitoids exposed in the Daitari and Gorumahisani greenstone belts yield crystallization ages ranging from 3.38 to 3.29 Ga and having inherited zircons being 3.58, 3.55, and 3.51 Ga old. A granitoid intrusive into iron formation of the Gorumahisani greenstone belt has an age of c. 3.29 Ga.  Detrital zircons recovered from Koira Group sandstone intercalated with iron formation yield a maximum depositional age of 2.63 Ga. 

We demonstrate that Palaeoarchaean greenstones exposed in the northern and southern parts of the Singhbhum Craton consists largely of sub-marine mafic-ultramafic volcanic rocks interlayered with minor felsic volcanic and chemical sedimentary rocks. Importantly, the ca. 3.51 Ga felsic volcanic rocks from the Badampahar Group permit comparison with co-eval felsic volcanic units reported from the lower part of the Onverwacht, Nondweni, Warrawoona groups of the Kaapvaal and Pilbara cratons. Otherwise, new age constraints of the Koira Group allow for better correlations with Meso-Neoarchaean cratonic cover successions elsewhere. 

How to cite: Jodder, J., Hofmann, A., Elburg, M., and Ngobeli, R.: Archaean record of the Singhbhum Craton, India: new insights from greenstone belts and cratonic cover sequences. , EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-10889, https://doi.org/10.5194/egusphere-egu24-10889, 2024.

In this study, the c. 3.334 Ga Kromberg Formation of the Onverwacht Group, in the south-eastern limb of the Onverwacht Anticline in the Barberton greenstone belt (South Africa) is investigated. Various geodynamic models have been proposed for the evolution of the Kromberg Formation, but detailed geochemical constraints on the mafic-ultramafic sequence are sparse. The objectives are to constrain the Paleoarchean mantle source characteristics and geodynamic setting for the Kromberg mafic-ultramafic rocks, placed in the context of recent high-resolution field mapping data. To study the protolith volcanic rocks, sampling has been conducted to avoid areas affected by deformation-related alteration. In addition, screening for alteration due to Archean seawater silicification has also been conducted. In conjunction with major, trace and rare earth element data, this study presents the first whole-rock Lu-Hf isotope analyses of mafic-ultramafic rocks of the Paleoarchean Kromberg Formation type-section in the Barberton greenstone belt (Grosch et al., 2022). Three compositionally distinct volcanic rock types are identified namely Group 1 metabasalts, Group 2 metabasalts and komatiitic metabasalts. The geochemistry of these rock types will be presented, and a possible geodynamic setting on the early Earth will be explored.  

Grosch, E.G., Ndlela S., Murphy D., McLoughlin N., Trubac J., Slama J., (2022) Geochemistry of mafic-ultramafic rocks of the 3.33 Ga Kromberg type-section, Barberton greenstone belt, South Africa: Implications for early Earth geodynamic processes. Chemical Geology 605, 120947

How to cite: Grosch, E., Ndlela, S., Murphy, D., McLoughlin, N., Trubac, J., and Slama, J.: Paleoarchean volcanic stratigraphy and geochemistry of the mafic-ultramafic Kromberg Formation type-section, Barberton greenstone belt, South Africa., EGU General Assembly 2024, Vienna, Austria, 14–19 Apr 2024, EGU24-3394, https://doi.org/10.5194/egusphere-egu24-3394, 2024.