Elemental fluxes into 3.0-billion-year-old marine environments: evidence from trace elements and Nd isotopes in banded iron formations from the Murchison Greenstone Belt, South Africa

Banded Iron Formations (BIFs) are authigenic, marine sediments directly reflecting the chemical composition of ancient seawater. BIFs serve as prime geochemical archives for the reconstruction of Precambrian marine environments. However, due to the scarcity of well preserved Archean rocks, atmospheric and hydrospheric environmental conditions within this time frame are still incompletely understood. In particular, elemental fluxes derived from continental weathering and submarine hydrothermal fluxes that affected ancient seawater chemistry are cornerstones for our understanding of the evolution of marine habitats through time. Here we present major- and trace element concentrations in combination with Nd isotopic compositions of 13 samples of Mesoarchean Algoma-type greenschist-facies BIFs from the ca 3.0 Ga old Murchison Greenstone Belt, South Africa. Individual Fe- and Si-rich layers are monitored for sample purity based on their chemical composition. Neodymium isotope compositions, in combination with trace element contents of BIF samples with varying amounts of clastic detritus, are further used to reconstruct the Murchison depositional environment and identify the origin of dissolved and detrital components entering the ancient ocean around 3.0 Ga ago.

Eight samples with low immobile element concentrations display typical shale-normalized Archean seawater-like rare earth and yttrium (REY_SN) patterns with positive La_SN, Eu_CN, and Gd_SN anomalies, super-chondritic Y/Ho ratios, and an enrichment of heavy REY_SN over light REY_SN, implying an open marine-dominated depositional setting with contributions from submarine high-temperature, hydrothermal systems. A Sm-Nd regression line yields an age of 2.98 ± 0.19 Ga that overlaps with the proposed depositional age, suggesting negligible post-depositional alteration on the REY composition of the pure BIF layers. In contrast, higher concentrations of immobile elements (e.g., Zr) and/or non-seawater-like REY_SN patterns are characteristic for the remaining five BIF samples, indicating elevated detrital input or post-depositional alteration. A regression line of the impure BIF layers yields an age of 2.49 ± 0.15 Ga, reflecting a potential post-depositional overprinting event such as the 2.6 Ga old Limpopo orogeny. The Nd isotopic compositions of pure and impure BIF samples cover a wide range of ca. two epsilon units suggesting a mixture of weathered mafic and felsic sources for the dissolved and suspended fluxes into the Murchison ocean.