Geochemical characterisation of Permian lower continental crust: case study from Ivrea-Verbano Zone (NW Italy)

Investigating the main geochemical characteristics of the lower continental crust is essential to understand its formation and evolution, identifying crustal differentiation processes and possible crust-mantle interactions. We performed bulk rock (major and trace elements), noble gases isotopes (He, Ne, Ar), and fluid inclusions (Raman spectroscopy) analyses on metamorphic rocks from Ivrea-Verbano Zone (Southern Italian Alps). Specifically, we studied various lithologies (metapelite, metagabbro, mafic and felsic granulite, amphibolite, and gneiss) to analyse the continuous metamorphic gradient from amphibolite- to granulite-facies.

Bulk rock analyses confirm the mafic nature of the protoliths for metagabbros (MgO = 5.36-10.25 wt.%), mafic granulites (MgO = 8.32-25.80 wt.%) and amphibolite (MgO = 7.98 wt.%) plotting in the metabasite field of the ACF chemographic diagram. Felsic granulite and sillimanite-gneiss fall within metamorphosed quartz-feldspar rocks, except for metapelite, which approaches the metacarbonate field, due to the presence of secondary carbonates. Metagabbros, mafic granulites and amphibolite show low REE concentrations (∑REE between 3 and 25 ppm) and high Cr and Ni contents (up to 1865 and 265 ppm respectively in mafic granulite), reflecting the mafic/ultramafic nature of the protoliths, whereas felsic granulite, sillimanite-gneiss and metapelite show higher REE contents (∑REE between 48 and 197 ppm).

³He/⁴He isotope ratios in metamorphosed quartz-feldspar rocks (0.06-0.30 Ra) and metabasites (0.15 and 0.45 Ra) are significantly radiogenic, although the metabasites show slightly higher values, corroborating a more primitive component in their source. Most samples plot near the air component in the ²⁰Ne/²²Ne vs ²¹Ne/²²Ne diagram, except for mafic granulites which show a crustal-air mixing trend. As regards the Ar isotope ratios, all samples appear rich in radiogenic component (⁴⁰Ar/³⁶Ar up to 2645 in metagabbros).

Raman spectroscopy analyses on fluid inclusions in orthopyroxene from mafic granulites show the coexistence of talc, graphite and magnesite with methane, providing direct evidence of a complex history in terms of post-metamorphic reactions and P-T-fO₂ conditions.

Our preliminary results show the compositional diversity and evolution of the lower continental crust, highlighting the interplay between mafic and sedimentary sources and the importance of fluid interactions and post-metamorphic processes.