Covering 70% of the Earth's surface, the sea surface microlayer (SML) is recognized as a critical boundary between the ocean and atmosphere. Its unique position places the SML at the center of various global processes in biogeochemistry and climate science. This session welcomes recent advancements in understanding the SML's distinctive chemical, biological, and physical characteristics, with a focus on understanding the underlying mechanisms of processes. Particular emphasis is given to the SML's function in modulating air-sea exchanges of heat, freshwater, gases, particles, and biota, but also exchange processes between the SML and the underlying bulk water, which are crucial for a more comprehensive understanding.. The concept of the SML as a biogeochemical reactor is also a central theme in the session to highlight the roles of environmental interfaces in marine biogeochemistry. Of further interest is the accumulation of pollutants such as hydrocarbons, microplastics, soot and pharmaceuticals, but also pathogenic microorganisms and viruses. In this context, the formation of (bio)aerosols as well as deposition processes play a role. To advance future studies, new observational, experimental and genomic approaches to the study of SML are particularly welcome. This multidisciplinary session welcomes participants from all research fields interested in the SML and its impact on surrounding environments. The session aims to bring together insights and findings from field observations, laboratory experiments, and models. By exploring the interplay between physical, chemical, and microbiological processes at the ocean-atmosphere interface, we seek to further develop a holistic perspective and foster new collaborations across research disciplines.