Magmatic controls on skarn-type Cu–Fe–Au mineralization in the Tonglushan ore field, Middle–Lower Yangtze River Metallogenic Belt

Skarn-type Cu–Fe–Au mineralization in the Middle–Lower Yangtze River Metallogenic Belt (MLYRB) is closely associated with Early Cretaceous intermediate to felsic magmatism; however, the links between magmatic evolution and ore-forming efficiency remain poorly constrained. In the Tonglushan ore field, one of the largest Cu–Fe–Au skarn systems in eastern China, multiple intrusive phases are spatially distributed, providing an ideal opportunity to investigate how magmatic processes control metallogenic potential. Here we present new geochronological and geochemical constraints on quartz monzodiorite porphyry, quartz monzodiorite, quartz diorite, and their mafic microgranular enclaves (MMEs) from different sectors of the Tonglushan ore field.

Zircon U–Pb ages indicate synchronous emplacement of all intrusive phases and MMEs at ca. 142–140 Ma. Whole-rock geochemistry and Sr–Nd–Hf isotopes indicate that these intrusive rocks belong to a high-K calc-alkaline to weakly adakitic series and were derived from an enriched lithospheric mantle source modified by slab-derived components, followed by extensive fractional crystallization. The MMEs record efficient mixing between mafic and felsic magmas, highlighting the role of mafic recharge in supplying heat and metal components to the evolving system. Estimates of magmatic water contents and oxygen fugacity from zircon compositions reveal systematic variations among different intrusions. The Jiguanzui and Tonglushan quartz monzodiorite porphyries are characterized by high water contents and elevated oxidation states, consistent with intense Cu–Au and Cu–Fe–Au mineralization, whereas the weakly mineralized Zhengjiawan quartz diorite exhibits lower values. These observations suggest that, beyond structural controls, the metallogenic fertility of intrusions in the Tonglushan ore field was primarily governed by fractional crystallization, mafic magma input, and the development of highly hydrous and oxidized magmatic systems.

Our study demonstrates that integrated whole-rock and zircon geochemical indicators provide effective tools for evaluating the ore-forming potential of skarn-type Cu–Fe–Au mineralization related intrusions in the MLYRB.