- 1Lhasa Meteorological Bureau, 850000, Lhasa, China
- 2School of Atmospheric Sciences, Chengdu University of Information Technology, 610225, Chengdu, China
- 3Dongying Meteorological Bureau, 257000, Dongying, China
- 4Xizang Meteorological Bureau, 850000, Lhasa, China
- 5College of Chemistry and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing, 100083, China
Meteorological normalization of surface ozone typically relies on air temperature to proxy both photochemical activity and boundary-layer dynamics. However, this approach implicitly assumes that the thermal state adequately represents radiative energy input—an assumption that remains untested in high-elevation environments where strong solar forcing and a thin atmosphere may decouple temperature from the surface energy balance. Here, we examine how surface energy forcing modulates ozone variability independently of air temperature using continuous station-level measurements in Lhasa (3650 m a.s.l.), Tibetan Plateau. By stratifying days based on net radiative input while explicitly constraining thermal conditions through a counterfactual matched-pair analysis, we isolate energy-driven processes without invoking reanalysis-based boundary-layer estimates. Results demonstrate that high-energy states consistently exhibit enhanced morning ozone growth (median +4.3 ppb h-1) and elevated daytime concentrations relative to temperature-matched low-energy states. These enhancements are accompanied by coherent multi-tracer responses, including moisture drying and the dilution of primary pollutants, which provide observational constraints on energy-driven vertical coupling that are distinct from temperature-dependent photochemistry. Furthermore, a rate-based robustness analysis confirms that these signals persist across varying stratification thresholds. We conclude that surface energy forcing represents a previously under-constrained structural factor in conventional ozone attribution frameworks, particularly in complex terrain where thermal and radiative states frequently decouple.
How to cite: Zhao, C., Wang, Y., Liu, Y., Li, W., Gongga, D., Quzhen, D., Ao, Y., Yue, J., Zhong, X., and Du, X.: Surface energy forcing modulates ozone variability independently of air temperature over the Tibetan Plateau, EGU General Assembly 2026, Vienna, Austria, 3–8 May 2026, EGU26-4386, https://doi.org/10.5194/egusphere-egu26-4386, 2026.