GMPV4.1 | Solving geoscience problems using mineralogy
EDI
Solving geoscience problems using mineralogy
Including GMPV Division Outstanding Early Career Scientist Award Lecture
Convener: Jannick Ingrin | Co-conveners: Catherine McCammon, Julien Reynes, Melanie J. Sieber, Juraj Majzlan
Orals
| Mon, 24 Apr, 08:30–12:25 (CEST)
 
Room D2
Posters on site
| Attendance Mon, 24 Apr, 14:00–15:45 (CEST)
 
Hall X2
Posters virtual
| Attendance Mon, 24 Apr, 14:00–15:45 (CEST)
 
vHall GMPV/G/GD/SM
Orals |
Mon, 08:30
Mon, 14:00
Mon, 14:00
Mineralogy is the cornerstone of many disciplines and is used to solve a wide range of questions in geoscience. This broad session offers the opportunity to explore the diversity of methods and approaches used to study minerals and how minerals behave and evolve in their many contexts. We welcome contributions on all aspects of mineralogy, including environmental, soil science, metamorphic, plutonic, deep Earth, planetary, applied mineralogy, and so on. All approaches are welcome: analytical, experimental and theoretical.

Orals: Mon, 24 Apr | Room D2

Chairpersons: Jannick Ingrin, Catherine McCammon, Melanie J. Sieber
08:30–09:00
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EGU23-9133
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ECS
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solicited
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GMPV Division Outstanding Early Career Scientist Award Lecture
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On-site presentation
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Xin Zhong

Metamorphic rocks are composed of minerals formed within a wide range of pressure-temperature (P-T) conditions. These minerals possess distinct physical properties with respect to their thermo-elasticity, viscosity and plasticity etc. When far-field nonhydrostatic stress was present during tectonic deformation or the P-T conditions were changed during burial or exhumation processes, grain-scale stress variation can be developed to maintain mechanical equilibrium. The induced stress variations can also be released over geological time. The magnitude, effect and geological implications of the preserved stress variations have been investigated and better understood in recent years, but a lot remains to be explored. It is important because it may as well open an opportunity to decipher the overseen information stored in the rock that is difficult to be detected or achieved with conventional methods.

The geological implication of grain-scale stress variation is directly manifested by a simple mineral inclusion-host system, such as quartz or zircon inclusion in garnet. The different thermal-elastic response between the inclusion and host upon P-T changes will result in a residual stress stored in an entrapped mineral inclusion. The inclusion stress (strain) can be directly measured with e.g. Raman spectroscopy. Combined with an elastic model, it is possible to obtain constraints on the entrapment P-T conditions. This elastic thermobarometry technique has been applied in many recent petrological studies because no global or local chemical equilibrium assumption is needed. However, it relies on the inclusion-host system being elastic and neglects the non-elastic behavior of minerals. As an example, I will present an integrated observational, experimental and numerical modelling work that highlights the importance of considering non-elastic behaviour of the mineral. The heating experiment shows that under conditions at which free fluid is present, a garnet host will be drastically weakened and partially release the inclusion pressure. This is further correlated with a nappe-scale study in the Adula nappe, Alps. A smooth T gradient is found increasing from the north (500-550 oC) to the south (700 oC) using the Zr-in-rutile thermometer. However, the entrapment P calculated with the quartz inclusion in garnet barometer demonstrate a GPa level steep drop in the middle-south, where the rocks have been hydrated during retrograde metamorphism and abundant micro-hydrous inclusions (e.g. chlorite, amphibole) are found in the garnet. It is interpreted that a combined effect of temperature and water fugacity will drastically speed up the inclusion pressure relaxation on a regional metamorphic scale. In the end, it is highlighted that mechanics with non-elastic stress-strain (rate) relationships are potentially needed when dealing with the generation and dissipation of the stress variations in metamorphic rocks that underwent retrograde hydration or very high T conditions to better extract geological information.

How to cite: Zhong, X.: The generation, dissipation and geological implication of grain-scale stress variation in metamorphic rock, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-9133, https://doi.org/10.5194/egusphere-egu23-9133, 2023.

09:00–09:10
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EGU23-15396
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ECS
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On-site presentation
Eleanore Blereau, Sandra Piazolo, and Alice Macente

Oxide mineral phases within high-grade metamorphic rocks are often largely ignored compared to silicate minerals, except for when constraining the redox state of a sample. It is becoming increasingly apparent that unusual concentrations of oxide phases (e.g. magnetite, ilmenite and spinel) are more common in granulite facies metamorphic rocks that previously thought. However, the mechanism of their formation remains poorly constrained. For example, it is currently unclear what process or combination of processes result in high (over 50% oxide concentration in a sample in some cases) concentrations. There is an ongoing debate if a single process can be applied across all protoliths, with the goal that these assemblages could be used to pinpoint particular crustal process(es). A number of mechanisms have been suggested to form such extreme concentrations of oxides within metamorphic rocks. These include melt fluxing in a deformation zone (Ghatak et al., 2022), partial melt loss (Morrissey et al., 2016), deformation related metamorphic reactions and protolith composition or a combination thereof. Within a collection of high grade metapelites from Rogaland, SW Norway, we see variations in mineralogy, including changes in orthopyroxene and cordierite content with oxide concentrations, variations in grain size, variable layering as well as variable signature of the amount of deformation. Using a combination of microstructures, EBSD, EDS, XCT and other data we will assess and illustrate the processes behind the generation of high oxide concentrations within metapelites and what this could mean for crustal processes during high-grade metamorphism.

 

Ghatak, H., Gardner, R. L., Daczko, N. R., Piazolo, S., & Milan, L. (2022). Oxide enrichment by syntectonic melt-rock interaction. Lithos, 414–415, 106617. https://doi.org/10.1016/J.LITHOS.2022.106617

Morrissey, L. J., Hand, M., Lane, K., Kelsey, D. E., & Dutch, R. A. (2016). Upgrading iron-ore deposits by melt loss during granulite facies metamorphism. Ore Geology Reviews, 74, 101–121. https://doi.org/http://doi.org/10.1016/j.oregeorev.2015.11.012

How to cite: Blereau, E., Piazolo, S., and Macente, A.: Constraining High Oxide Mineral Concentrations in High-Grade Metamorphic Rocks: Insights from Multidisciplinary Analysis, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-15396, https://doi.org/10.5194/egusphere-egu23-15396, 2023.

09:10–09:20
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EGU23-12907
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ECS
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On-site presentation
Joanna Brau, Philippe Schmitt-Kopplin, Melanie Kaliwoda, Bettina Scheu, and Donald B Dingwell

Olivine is an abundant phase of ultramafic and mafic rocks in the earth's crust and mantle. Stony meteorites or stony-iron meteorites like pallasites also contain a lot of extraterrestrial olivines. During atmosphere entry olivine-containing meteorites experience different oxygen levels and intense heating for brief intervals, creating fusion crusts that are a few millimetres thick. As a result, various thermal pathways between the rim and the core are anticipated for meteoritic olivines. This shows different colours in natural pallasitic olivines. We are particularly interested in the effects of environmental variables on both terrestrial and interplanetary olivines, based on terrestrial olivines. Natural volcanic olivines from the 1959 Kilauea eruption in Hawaii, the Aheim mine, Norway, are employed and a stony-iron pallasite (collected 1822 – Atacama Desert). We generate two environments using a gas-tight tube furnace that produces CO-CO2 gas mixes—one in air and the second with a reduced atmosphere (fO210-12 bar). The temperatures range from 950 to 1350 degrees Celsius (i.e. within the olivine stability field). After hand-picking single grains of olivines and putting them in Pt-Rh crucibles for an hour, the samples are lifted vertically out of the tube furnace and quenched in air. EPMA, SEM, RAMAN, and optical and laser microscopy are used to characterise and analyse the samples.

Preliminary findings, olivines show thermal stability and have a homogeneous chemical composition both before and after heating. A reduced environmental exposure causes a change in colour, similar to the stony-iron pallasite which will be discussed. In association with those observations, we also see Raman bands nearby 600 cm-1 vanish, and Raman bands show up at 800 cm-1. We will compare these effects in relation to the findings from tests involving air exposure and compare the observations obtained from naturally occurring pallasitic olivines.

How to cite: Brau, J., Schmitt-Kopplin, P., Kaliwoda, M., Scheu, B., and Dingwell, D. B.: Investigation of olivine's thermostability in an oxidized and reduced atmosphere, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-12907, https://doi.org/10.5194/egusphere-egu23-12907, 2023.

09:20–09:30
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EGU23-441
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ECS
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On-site presentation
Manojit Koley, Biswajit Ghosh, Archisman Dhar, and Sankhadeep Roy

Like all the alkaline complexes, feldspar exsolution texture is common within different rock types of Koraput Alkaline Complex (KAC), India. Both perthite and mesoperthite exsolution texture are common in this alkaline complex. The former is present within nepheline syenite and granite whereas the latter is observed within alkali gabbro, syenite, granite and nepheline syenite. Shapes of plagioclase feldspar lamellae of perthite and mesoperthite texture vary widely. Plagioclase feldspar lamellae in mesoperthite at places bifurcate and merge with each other forming anastomosing pattern. On the other hand, plagioclase feldspar lamellae in perthite are commonly needle-like. Using two-feldspar and one-feldspar thermometry we have estimated the temperature of formation of these textures. Compositions of exsolved alkali feldspar and the adjacent plagioclase feldspar pairs are used in two-feldspar thermometry. In one-feldspar thermometry, we have used the reintegrated compositions of exsolved alkali feldspars. In two-feldspar thermometry compositions of alkali feldspars immediately after exsolution in these rocks are also estimated. Here we quantify the shape of perthite and mesoperthite grains to objectively understand how effects of different factors (temperature and composition) determines lamellae shape. To solve this problem, we use a multivariate shape analysis approach via geometric morphometrics tool supplemented by statistical methods such as ordinations and statistical analyses [Principal Components Analysis (PCA) and Canonical Variates Analysis (CVA)]. Our result suggests that there is no influence of composition on the shape of plagioclase feldspar lamellae. On the other hand, a strong influence of temperature on the shape of lamellae is distinctly observed. Plagioclase feldspar lamellae showing anastomosing pattern formed at higher temperature. On the other hand, needle like plagioclase feldspar lamellae formed at the lower temperature.  Our data analytics-driven results provide a new perspective to understand the relation between the feldspar exsolution shape and formation temperature of the lamellae. The shape modification of the feldspar lamellae implies that the exsolution texture in alkali gabbro formed early followed by nepheline syenite, syenite and alkali feldspar granite. This finding is also coeval with the crystallisation history of the lithological units of this alkaline complex.

How to cite: Koley, M., Ghosh, B., Dhar, A., and Roy, S.: A multivariate approach to study the shape modifications of feldspar exsolution lamellae during cooling: A case study from Koraput Alkaline Complex, India, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-441, https://doi.org/10.5194/egusphere-egu23-441, 2023.

09:30–09:40
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EGU23-10213
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On-site presentation
Yana Fedortchouk

Kimberlites are the deepest and the most enigmatic magmas that reach the surface of the Earth. Their source, origin and even composition are a subject of debates. Kimberlites form hypabyssal sills and dykes but most often occur as explosion pipes, which comprise various volcaniclastic and magmatic units. Differences in the geological composition, shape and size of kimberlite pipes worldwide arise from the differences in the eruption processes and are the base for distinguishing three kimberlite classes. However, it is not clear if these differences result from the properties of the country rocks or from variable magma composition especially H2O : CO2 ratio.

During the ascent, kimberlites transport mantle fragments including diamonds to the surface and partially dissolve them. Previous studies have shown that dissolution features on diamond reflect the conditions in the host magma and especially presence and composition of fluid. Diamonds from volcaniclastic facies of different kimberlite classes all show very similar low-relief surface features indicating presence of fluid. Geometry of the trigonal etch pits on diamonds helps to deduce H2O:CO2 ratio of kimberlitic fluid. On the contrary, “corrosive” resorption styles of diamonds from hypabyssal kimberlite (HK) units are different between the three kimberlite classes allowing to examine differences in their crystallization conditions. This study aims to reproduce corrosive resorption of diamonds in controlled experiments in order to examine the composition of kimberlite magma in different kimberlite classes and its effects on magma emplacement.

Experiments were conducted in piston-cylinder apparatus at pressure 0.5 – 1 GPa and temperatures 1000 – 1200oC using a range of volatile-undersaturated silicate and silico-carbonate melts. Experiments produced three specific resorption styles previously reported on natural diamonds from HK: (i) sharp pointy features common for diamonds from HK in class 3 kimberlites; (ii) corrosion sculptures common for diamonds from HK in class 1 kimberlite; (iii) deep channels – rare but prominent feature of natural diamonds. We compare our experimental results to the features of natural diamonds from HK units of class 1 kimberlites (Orapa kimberlite cluster, Botswana) and class 3 (Ekati Mine kimberlites, Canada) to compare magma composition and emplacement conditions of different kimberlite classes.

How to cite: Fedortchouk, Y.: Experimental study of dissolution style of diamonds from volcaniclastic vs. hypabyssal kimberlite facies: the effect of melt composition on kimberlite eruption and geology, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-10213, https://doi.org/10.5194/egusphere-egu23-10213, 2023.

09:40–09:50
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EGU23-16815
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On-site presentation
Ioana-Bogdana Radu, Henrik Skogby, Valentin R. Troll, Frances M. Deegan, Harri Geiger, Daniel Müller, and Thor Thordarson

The magmatic water content plays an important role in the evolution and explosivity of volcanic eruptions, due to the influence of water on magma density, viscosity, crystallization and melting temperatures. A reliable method for determining the pre-eruptive magmatic water content is to use nominally anhydrous minerals (NAMs) which can preserve various hydrogen configurations (as water proxy) in structural defects. This method allows to experimentally reconstruct the water lost during magmatic processes such as degassing and analyse it by infrared spectroscopy. Applying this to crystallographically oriented clinopyroxene crystals from lava samples collected in April 2021 from the Geldingadalir eruption, SW-Iceland, we obtain water contents of 0.69 ± 0.07 to 0.86 ± 0.09 wt. % H2O. Because these values are higher than those expected for typical mid-ocean ridge basalts (MORB: 0.3 – 0.5 wt. % on average) it reveals a significant plume (OIB) contribution to the magma source. The implications of such water concentrations are that water saturation was attained only at very shallow levels within the plumbing system of the ascending Geldingadalir magmas. This can further explain the occurring pulsing behaviour of the lava pond and within the upper conduits, as the result of shallow, episodic, vapour exsolution.

How to cite: Radu, I.-B., Skogby, H., Troll, V. R., Deegan, F. M., Geiger, H., Müller, D., and Thordarson, T.: A mineralogical approach to the 2021 Geldingadalir eruption of the Fagradalsfjall Fires,SW-Iceland – the study of water in clinopyroxene phenocrystals, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-16815, https://doi.org/10.5194/egusphere-egu23-16815, 2023.

09:50–10:00
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EGU23-14573
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ECS
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On-site presentation
Luca Faccincani, Giacomo Criniti, Alexander Kurnosov, Tiziana Boffa Ballaran, Anthony C. Withers, Maurizio Mazzucchelli, Fabrizio Nestola, and Massimo Coltorti

The dominant phases of Earth’s upper mantle are commonly referred to as nominally anhydrous minerals (NAMs) but may contain significant amounts of water. The colloquial term “water” in NAMs is related to the presence of hydroxyl-bearing (OH-) point defects in their crystal structure, where hydrogen is bound to lattice oxygen and is charge-balanced by cation vacancies. For this reason, the incorporation of even small amounts of water may substantially affect the physico-chemical properties of NAMs, such as their elasticity, rheology, and melting temperature. Olivine is considered the most abundant phase of Earth’s upper mantle and constitutes about 60 vol.% of a primitive upper mantle (pyrolite) phase assemblage. Although natural olivine samples originating from the shallow upper mantle are relatively dry (maximum H2O concentrations of about 400 ppm), a plethora of experimental data indicate that olivine water storage capacity significantly increases to 0.2-0.5 wt.% H2O at deeper upper mantle conditions.
In this contribution, we investigated the effect of water on the elastic properties and sound wave velocities of hydrous Mg1.8Fe0.2SiO4 (Fo90) olivine samples with realistic water contents for deep upper mantle conditions with the aim of interpreting both seismic velocity anomalies in potentially hydrous regions of Earth's upper mantle and the observed seismic velocity and density contrasts across the 410-km discontinuity between the upper mantle and the mantle transition zone. To do so, we performed simultaneous single-crystal X-ray diffraction and Brillouin scattering measurements at room temperature up to ~12 GPa on Fo90 olivine with ~0.20 wt.% H2O to constrain its full elastic tensor. Results were complemented with a careful re-analysis of all the available single-crystal elasticity data from the literature for Fo90 olivine to re-determine the elastic behaviour of the anhydrous phase. Our new data show that the sound wave velocities of hydrous and anhydrous olivines are indistinguishable within uncertainties at pressures corresponding to the base of the upper mantle. Therefore, if amounts of water were to be incorporated into the crystal structure of Fo90 olivine, its elastic and seismic behaviour at high pressure would likely remain unchanged. This suggests that water in olivine is not seismically detectable, at least for contents consistent with deep upper mantle conditions. Moreover, the incorporation of water in olivine is unlikely to be a key factor in reconciling seismological observations at the 410-km discontinuity with a pyrolitic mantle, but rather corroborates previous evidence of a deep upper mantle that is less enriched in olivine than the pyrolite model.

How to cite: Faccincani, L., Criniti, G., Kurnosov, A., Boffa Ballaran, T., Withers, A. C., Mazzucchelli, M., Nestola, F., and Coltorti, M.: Elasticity of hydrous olivine at high pressure and seismic detectability of water in Earth's mantle, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-14573, https://doi.org/10.5194/egusphere-egu23-14573, 2023.

10:00–10:10
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EGU23-15214
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ECS
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On-site presentation
Laura Czekay, Nobuyoshi Miyajima, and Daniel Frost

The diffusion of atoms in minerals at high temperatures and pressures influences Earth’s lower mantle dynamic processes. This study aims to better understand the physical behaviour of Earth’s most abundant mineral with implications for lower mantle viscosity. Previous studies that measured Si-self diffusion coefficients in bridgmanite (Brg) showed a value at 25 ± 1 GPa and 1800 °C of Log10(DSi) = -18 ± 0.5 (based on units of m2/s). Our study revealed a significantly slower diffusion coefficient that may challenge previous calculations of lower mantle viscosity. We investigated Al, Si interdiffusion in Brg experimentally at 24 GPa and 1750 to 2000 °C using a multianvil apparatus using diffusion couples composed of bridgmanites that were pre-synthesised from 0-5 mol.% Al2O3-bearing MgSiO3 enstatite. The Al diffusion profiles were analysed across the diffusion interface in the recovered samples using a scanning transmission electron microscope equipped with an energy-dispersive X-ray spectrometer. The obtained diffusion coefficient for interdiffusion (volume diffusion) at 24 GPa and 1800 °C was Log10(DAl,Si) = -20.1 ± 0.7. The resulting data can be used to estimate deformational strain rates of Brg in the lower mantle from viscosity based on different creep mechanisms.

How to cite: Czekay, L., Miyajima, N., and Frost, D.: Al, Si diffusion in bridgmanite to estimate the Earth's lower mantle rheology, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-15214, https://doi.org/10.5194/egusphere-egu23-15214, 2023.

Coffee break
Chairpersons: Catherine McCammon, Juraj Majzlan, Melanie J. Sieber
10:45–10:55
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EGU23-6782
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ECS
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On-site presentation
Lin Wang, Nobuyoshi Miyajima, Fei Wang, Xiaoyu Wang, and Tomoo Katsura

Bridgmanite and CaSiO3-perovskite, respectively, are the first and third most abundant minerals in the Earth's lower mantle. The intersolubility of Ca and Mg between these two minerals is still under debate. Some studies indicated limited intersolubility, while others suggested a complete dissolution of CaSiO3-perovskite into bridgmanite at lower mantle conditions. This controversy leads to different explanations of the physical properties of the lower mantle such as density, elasticity, and viscosity, accordingly modifying our understanding of the nature and dynamics of the Earth’s interior. Therefore, it is essential to determine the intersolubility of bridgmanite and CaSiO3-perovskite.

The intersolubility of Ca and Mg between bridgmanite and CaSiO3-perovskite can be affected by the temperature, pressure, and bulk compositions of the system. Previous studies showed an increase in intersolubility with temperature, but reported no robust pressure and composition dependence. Because FeAlO3 is the second dominant component in bridgmanite, investigating the effect of FeAlO3 content and pressure dependence is essential to clarify the phase relation of the Earth’s lower mantle.

This study determined the pressure and FeAlO3 dependence on the intersolubility of bridgmanite and CaSiO3-perovskite at pressures of 27 to 40 GPa at a constant temperature of 2300 K using a multi-anvil press. Two compositions of MgSiO3:CaSiO3 = 1:1 and MgSiO3:FeAlO3:CaSiO3 = 3:2:5 were examined. SEM images clearly show the existence of two phases in all products. TEM-EDS analyses indicate a decrease in the CaSiO3 content of bridgmanite in both systems with increasing pressure. The FeAlO3 component only slightly enhances the CaSiO3 content of bridgmanite: adding the FeAlO3 component increases the CaSiO3 content of bridgmanite from 0.04(2) to 0.3(2) mol.% at 40 GPa. The MgSiO3 content of CaSiO3-perovskite decreases with increasing pressure from 1.8(7) to 0.06(8) mol.% in the FeAlO3-free system, and from 1.2(5) mol.% mol to an unmeasurably small value in the FeAlO3-bearing system. We conclude that, even with the presence of a FeAlO3 component in bridgmanite, the intersolubility is limited and remains nearly constant at different pressures. Thus, bridgmanite and CaSiO3-perovskite should coexist in the lower mantle, and CaSiO3-perovskite is the host mineral of large lithophile elements such as Ca in the lower mantle.

How to cite: Wang, L., Miyajima, N., Wang, F., Wang, X., and Katsura, T.: Limited intersolubility of Ca and Mg between bridgmanite and CaSiO3-perovskite in the lower mantle, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-6782, https://doi.org/10.5194/egusphere-egu23-6782, 2023.

10:55–11:05
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EGU23-545
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ECS
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On-site presentation
Sanem Elidemir, Nilgün Güleç, Kıymet Deniz, and Yusuf Kağan Kadıoğlu

Investigation of the reservoir lithology of Edremit geothermal field from western Anatolia is performed using the drill cuttings that belong to the reservoir levels. The samples are analysed in an attempt to determine the mineralogical and petrographical features, mineral compositions and whole rock geochemistry. The examinations include macroscopic and microscopic analyses, followed by the techniques of X-Ray Diffraction (XRD), Confocal Raman Spectroscopy (CRS), Electron Probe Micro Analysis (EPMA) and X-Ray Fluorescence (XRF). Dominant rock fragments and mineral phases are identified as granitic rocks and quartz, feldspars, micas, carbonates and amphiboles, respectively. Textural characteristics of the samples display the effects of cataclasm and alteration, indicating faulting and hydrothermal fluid activity. The changes in major and trace element concentrations along the well bore reveal three different concentration levels at depth intervals of 900-928 m, 930-974 m and 976-1038 m as well as an inverse relationship between SiO2 and CaO. These three distinctive zones correlate well with the variations in grains sizes (coarse to fine) and textural features (cataclastic to mylonitic) with depth. Taking into account the reported water leakage zone around 930 m depth and the evidences for hydrothermal fluid effect (such as pyrite abundance, alterations, sulphur presence) observed along the well bore, possible fault zone and as a result, the likely pathway for the hydrothermal fluid is inferred to be in the middle section (930-974 m) of the identified three zones. It is also deduced from the lithogeochemical results that the fluid is potentially Si-rich in this zone and Ca-rich in deeper levels which are in line with the previously investigated hydrogeochemistry of the system. This study points out that mineralogical-petrographical studies integrated with geochemical analyses can potentially serve as significant indicators in determination of lithological variations that can be correlated with fault zones of deep systems for prospective exploration sites.

 

This study has been published in Applied Geochemistry in 2022 and complete work can be accessed from https://doi.org/10.1016/j.apgeochem.2022.105388

How to cite: Elidemir, S., Güleç, N., Deniz, K., and Kadıoğlu, Y. K.: Implications for Possible Fault Zones Deduced from Lithogeochemical Characterization of Reservoir Levels of a Geothermal Field: Edremit Example, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-545, https://doi.org/10.5194/egusphere-egu23-545, 2023.

11:05–11:15
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EGU23-1127
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ECS
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On-site presentation
Louise Darricau, Julia Cucinotta, Josselin Gorny, Arnaud Mangeret, Mathilde Zebracki, and Alexandra Courtin

Between 1948 and 2001, the extraction of Uranium (U) ores in France have produced a large quantity of waste (tailings, waste rock, etc.), still containing U-rich minerals and other trace elements (TE), that were associated to the initial mineralization. Some of those TE can be relatively mobile and redistributed with U in the various reservoirs of the critical zone, contaminating environmental compartments such as soils and sediments.

Wetlands correspond to areas where the physical and chemical conditions may greatly vary according to the variations of the water table. When these areas are contaminated by mining inputs, the presence of particulate organic matter (POM) in large quantity may influence the mobility of U and many various TE. Moreover, in recent years, the multiplicity of drought events can lead to the modification of the ability of such wetlands to sequestrate U and its co-occurring metals. The consequences of these events in terms of speciation and mobility of contaminants under oxidizing conditions need thus to be better understood.

For this purpose, wetland soils impacted by former U mining and milling activities in a site of the Massif Central (Rophin, France) were studied. Various analytical approaches (SEM, EPMA analyses and BCR chemical extractions) were deployed to determine the speciation of TE and understand their stability (leaching tests) under oxidizing conditions.

The pollution index Igeo, calculated along a soil core of 48 cm, highlights significant anthropogenic contributions in U, Pb and Cu the highest contamination levels in those elements being linked to a white layer, probably inherited from the former mining activities. For Cu and U, the solid speciation in this mining deposits is mainly governed by adsorption on surface particles and to a lesser extent, by precipitation of authigenic/inherited phases such as oxides for U (e.g. uranium dioxide - UO2) and sulfides for Cu (e.g. chalcopyrite - CuFeS2). Sorption processes onto the POM seems to mainly govern their speciation in ancient and recent POM-rich layers. Along the soil core Pb solid speciation seems mostly associated to stable phosphates e.g. plumbogummite (PbAl3(PO4)(PO3OH)(OH)6) inherited from the regional granite and U-Pb-rich mineralization. Again, mining deposits show differences with Pb adsorbed on surface particles and linked to other mineral phases such as sulphates e.g. anglesite (PbSO4) and hokutolite ((Ba,Pb)SO4). Additionally, refractory granite minerals contain U and Pb in variable quantities all along the soil core, (e.g. titanium oxides, REE phosphates, zircons). Eventually, minute amounts of Pb and U phosphates containing traces of Cu and As, with a stoichiometry close to parsonsite (Pb2(UO2)(PO4)2 2H2O), the prevailing U mineralization of the Rophin deposit, are also identified. The various U and TE-phases identified in this wetland outline different behavior and mobility according to environmental parameters modifications. Finally, leaching tests and chemical extractions highlighted a certain mobility for some elements, such as Cu and U, that may be hazardous for the environment.

How to cite: Darricau, L., Cucinotta, J., Gorny, J., Mangeret, A., Zebracki, M., and Courtin, A.: Reactivity of U and co-occurring metals from mine deposits in a wetland under oxidizing conditions, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-1127, https://doi.org/10.5194/egusphere-egu23-1127, 2023.

11:15–11:25
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EGU23-967
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On-site presentation
Christopher Brough, Bradley Staniforth, Corinne Garner, James Strongman, John Fletcher, and Rory Colville

The Donegal mica crisis began in 2011 and was initially linked to the presence of excessive free mica in the binder of aggregate concrete masonry units (ACMU) used for construction of dwellings and commercial premises in the decade prior. Free mica was identified to be abraded from the muscovite rich aggregate source, a low-grade phyllite. This free mica increased the microporosity of the cement binder leaving it highly susceptible to secondary degradation processes, including moisture ingress, potential freeze-thaw degradation and internal or external sulphate attack. As well as weakening the binder overall strength the ability to adhere to the flakey mica-rich aggregate was also reduced. Further work since then has highlighted the presence of elevated levels of pyrrhotite within the predominant problematic aggregate, a highly reactive sulphide responsible for internal sulphate attack. Taken together, ACMU’s produced using phyllite aggregate has produced abundant defective concrete block within County Donegal. These ACMU’s have rapidly deteriorated producing the present crisis within County Donegal.

Whilst the most defective phyllite-bearing ACMU has typically already suffered critical deterioration, work undertaken as part of I.S. 465 has also highlighted other metasedimentary aggregates in use within County Donegal which are of lower or higher metamorphic grade. Sulphide abundance within these aggregates is lower and sometimes absent, depending on the grade and phases of deformation they have been subjected to. In addition, when sulphides are present pyrite tends to predominate, with pyrrhotite largely absent except for at the higher metamorphic grades transitioning from the problematic phyllite (i.e. schist, hornfels and amphibolite). These aggregates also produce slightly lower levels of free mica in the binder, either due to stronger annealing at higher metamorphic grades or less abradable mica and splaying along crenulations at lower grades. These aggregate types, and the houses built from the ACMU’s are nevertheless showing signs of degradation and point to the need to consider the longer-term impacts and risks of ACMU’s made from the different aggregate types that may be prevalent within County Donegal.

This abstract proposes a three-fold metric for identifying the most defective ACMU’s at risk of premature deterioration dependent on the metamorphic grade and deformation characteristics of the aggregate used, the amount of free mica produced in the binder and the abundance of sulphides, particularly pyrrhotite.

How to cite: Brough, C., Staniforth, B., Garner, C., Strongman, J., Fletcher, J., and Colville, R.: The Donegal mica scandal, the tip of an iceberg?, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-967, https://doi.org/10.5194/egusphere-egu23-967, 2023.

11:25–11:35
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EGU23-14853
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ECS
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On-site presentation
Stylianos Aspiotis, Jochen Schlüter, and Boriana Mihailova

Talc and serpentine-group minerals are Mg-dominant trioctahedral layered silicates that are common in igneous and metamorphic rocks and can be found in a wide range of geological conditions. Hence, a precise physicochemical characterization of these phyllosilicates in intact mineral assemblies, e.g. in thin sections as prepared for polarization microscopy, can provide a better insight into the processes of mineral formation, magma differentiation, and alteration. Moreover, talc and serpentines are common mineral components in a variety of cultural-heritage objects such as engraved gems and old Babylonian cylinder seals. Hence, material profiling of artefacts can help understand their origin through crystallographic and crystallochemical markers that may advance provenance studies. Since sampling of such objects is mostly prohibitive, the development of non-destructive, non-invasive, and preparation-free analytical methods is desired.

To address this quest, a series of 18 serpentine-group minerals (nominally Mg3Si2O5OH4) and 10 talc samples (nominally (Mg3)Si4O10OH2) with different contents of Fe as a minor element was selected and studied by Raman spectroscopy and wavelength-dispersive electron microprobe analysis (WD-EMPA) to explore the potential of Raman spectroscopy as a truly non-destructive method for quantitative compositional characterization of these groups of phyllosilicates. The methodological approach is based on the already established quantitative relationships between the crystallochemical composition and the Raman signals of biotites (Aspiotis et al., 2022). The goal was first to verify whether the Raman scattering arising from the framework vibrations (15-1215 cm-1) and OH-bond stretching (3500-3900 cm-1) can assist in the identification of serpentine-group minerals and talc samples with various cationic compositions at the octahedral site. Secondly to establish quantitative relationships between the Raman signals (peak positions, integrated intensities, and full widths at half maximum) and the crystal chemistry of these phyllosilicates. We demonstrate that the quantification of MMg and M(Fe2++Mn) contents in talc from the Raman spectroscopic analysis is as accurate as from EMPA. Regarding serpentines, MMg and MFe2+ amounts can be determined as well with a relative precision of ~ 2 and 5%, respectively.

How to cite: Aspiotis, S., Schlüter, J., and Mihailova, B.: Exploring Raman spectroscopy for crystallochemical analysis of talc and serpentine: application beyond geosciences, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-14853, https://doi.org/10.5194/egusphere-egu23-14853, 2023.

11:35–11:45
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EGU23-10283
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ECS
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Virtual presentation
Anirudh Prabhu, Shaunna M. Morrison, Ahmed Eleish, Peter Fox, Joshua J. Golden, Robert T. Downs, Samuel Perry, Peter C. Burns, Jolyon Ralph, and Robert M. Hazen

Minerals are the oldest surviving materials from the formation of our solar system. They are time capsules that store and provide information about the evolution of Earth and other planetary bodies. In addition to being a cornerstone of geoscience research, minerals also have economic, industrial and commercial importance in many sectors of society. One of the fundamental questions in mineralogy and geosciences in general is “Where to find minerals?”. Due to the complex and intertwined nature of natural systems, it has been hard to predict the occurrences of minerals. However, with increase in the volume and accuracy of mineral data and rise of mineral informatics, data science and analytics methods can be developed to answer this fundamental question in mineralogy. 

 

In this contribution, we present “mineral association analysis”, a method to: 1) Predict the mineral inventory for any existing locality. 2) Predict previous unknown localities for any given mineral. Mineral association analysis is a machine learning method that uses association rule learning to find interesting patterns based on mineral occurrence data. Using mineral association analysis, we have been able to predict locations of critical minerals, such as minerals with Li- and Th-bearing phases, predict the mineral inventory of mars analogue sites, and even understand how mineralization and mineral associations changed through deep time.

How to cite: Prabhu, A., Morrison, S. M., Eleish, A., Fox, P., Golden, J. J., Downs, R. T., Perry, S., Burns, P. C., Ralph, J., and Hazen, R. M.: Mineral Association Analysis: Predicting unknown mineral occurrences and improving our understanding of mineralogy, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-10283, https://doi.org/10.5194/egusphere-egu23-10283, 2023.

11:45–11:55
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EGU23-16233
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On-site presentation
Dominik C. Hezel, Heidi E. Höfer, and Andreas Fichtner

The electron microprobe (EPMA) flank method can be used to determine in-situ the Fe2+/Fe3+ ratios in garnet [1], and potentially also in other minerals. It is a tool to reveal the redox history of rocks, especially when the garnet grain size or garnet homogeneity requires a microanalytical technique for Fe3+/Fe(tot) determination (e.g., [2,3,4]). The flank method is based on the accurate intensity measurement at two positions on the flanks of the FeLa and FeLemission lines, and makes thus use of the systematic change of the intensities and wavelengths of the FeL lines with: (i) the iron oxidation state and (ii) the total iron content.  Data reduction of the obtained data so far required a complex combination of numerous Excel spreadsheets, and, for multiple linear regressions, the conversion to text files in combination with the Matlab clone Octave. This work-flow required a trained expert, and could quickly take up to even several days. 

We converted this process into a web-application with a simple and intuitive graphical user interface (GUI), with which the entire work-flow can be completed within minutes to hours. The web-application uses the 2-dimensional linear regression fit to determine Fe2+ from its dependency both on the intensity ratio FeLb/FeLa and the total Fe content, based on eq. 2 in [1].  The web-application allows the visual examination of all data using a large variety of plots for in-depth data inspection. Video tutorials embedded on the website explain not only how to use the website, or how the data reduction itself works, but also the flank as well as the EPMA method itself. Own data can be uploaded and reduced, and an available demo dataset allows training and exploring the web-application.

The entire web-application is realised using Python, Streamlit and a public GitHub repository. We will present what the flank method is, how it works using the EPMA, how the data reduction process works, and demonstrate how to use the web-application from the raw dataset to the final results.

[1] Höfer H. E. and Brey G. P. (2007) The iron oxidation state of garnet by electron microprobe: Its determination with the flank method combined with major-element analysis. Am Mineral 92, 873–885.

[2] Wang C, Tao R, Walters JB, Höfer HE, Zhang L (2022): Favorable P–T–ƒO2 conditions for abiotic CH4 production in subducted oceanic crusts: A comparison between CH4-bearing ultrahigh- and CO2-bearing high-pressure eclogite. Geochim. Cosmochim. Acta 336, 269-290

[3] Tang M, Lee C-TA, Costin G, Höfer HE (2019): Recycling reduced iron at the base of magmatic orogens. Earth and Planetary Science Letters 528, 115827. doi.org/10.1016/j.epsl.2019.115827

[4] Aulbach S, Höfer HE, Gerdes A (2019): High-Mg mantle eclogites from Koidu (West African craton): Neoproterozoic ultramafic melt metasomatism of subducted Archaean plateau-like oceanic crust. Journal of Petrology 60, 723-754

How to cite: Hezel, D. C., Höfer, H. E., and Fichtner, A.: A new web-based and open data reduction application to determine Fe2+/Fe3+ ratios using the electron microprobe flank method., EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-16233, https://doi.org/10.5194/egusphere-egu23-16233, 2023.

11:55–12:05
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EGU23-9209
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ECS
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On-site presentation
Edyta Waluś and Maciej Manecki

The wide range of colored wastewater from industries in the aquatic environment poses a great threat to human and animal health and poses a great obstacle to the ecological ecosystem. Therefore, an effective, efficient, and environment-friendly treatment methods are being sought. Hydroxyl- phosphate and arsenate compounds have recently attracted attention for magnetic and photocatalytic applications in photoreactions with visible light.  They can be a promising alternative to TiO2, in which the photoabsorption spectrum is in the range of ultraviolet (UV) light owing to its large bandgap, which accounts for only 5% of the sunlight.

Here, we present a detailed analysis of the properties of libethenite Cu2PO4OH - olivenite Cu2AsO4OH solid solution series, and their photocatalytic activities under visible light. Seven compounds of the solid solution series were successively synthesized by the wet chemical method at 70°C according to the results of Fourier-transform infrared (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS) tests. The photocatalytic performance of the samples was thoroughly investigated for the degradation of methylene blue MB solutions under visible light and measurements by UV-vis spectroscopy.

We demonstrated the useful photocatalytic activity of these complex structures for the degradation of methylene blue (MB) dye under visible-light irradiation. The substitution effect of [PO4]3− anions by [AsO4]3− results in changes in the bonds of the OH group, which are the origin of the photocatalytic properties of this material, altering the bond length and geometry.  In addition, these substitutions affected the morphology of the precipitating solids, which changed the surface area of the material. This way the substitution of As with P in the solid solution series affected the photocatalytic properties The MB degradation efficiency after 6h declines from ~ 84 % for the Cu2AsO4OH and Cu2PO4OH down to ~81% for intermediate member.  The present work provides insights leading to a better understanding of the photocatalytic performance of Cu2PO4OH and Cu2AsO4OH. Thanks to these results it may be beneficial to prepare more efficient photocatalysts based on this material for sunlight photocatalysis, which will also be helpful in designing and preparing novel technologies.

This research was funded by NCN research grant no. 2021/41/N/ST10/03566

How to cite: Waluś, E. and Manecki, M.: Photocatalytic properties of libethenite Cu2PO4OH - olivenite Cu2PO4OH  solid solution series, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-9209, https://doi.org/10.5194/egusphere-egu23-9209, 2023.

12:05–12:15
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EGU23-8801
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ECS
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On-site presentation
Kacper Staszel, Anna Jędras, Mateusz Skalny, Klaudia Dziewiątka, Kamil Urbański, Julia Sordyl, Karolina Rybka, Jarosław Majka, and Maciej Manecki

Research on rare earth elements (REE) is currently of high importance due to these elements being considered as critical raw materials. Particularly REE phosphates are the subject of laboratory experiments since they have various applications resulting from their structural diversity. In crystalline rocks REE phosphates occur as monazites and xenotimes (REEPO4, monoclinic and tetragonal, respectively). Secondary phosphates precipitate out of aqueous solution usually in the form of rhabdophane or churchite (REEPO4·nH2O, trigonal and monoclinic). Their formation results in immobilization of REE which plays a significant role in controlling the solubility of REE in nature, in beneficiation processes, and in technological applications.

The precipitation of rhabdophanes is usually studied experimentally in pure systems. However, it is recognized that the presence of other solution components can significantly affect the processes and the final product. Since both Pb and REE readily form phosphates that precipitate out of aqueous solutions, it has been hypothesized that the precipitation of REE-phosphates in the presence of Pb would result in the formation of mixed phosphate phases (containing both Pb and REE) or a mixture of two phases: phosphoschultenite PbHPO and rhabdophane REEPO4·nH2O. Despite the difference in ionic charge between Pb2+ and REE3+, formation of either phosphoschultenite PbHPO partially substituted with REE, or rhabdophanes partially substituted with Pb was also considered.

Synthesis of La-, Ce-, and Sm-rhabdophanes was attempted in the absence (control) and in the presence of Pb2+ ions in the solution (at ambient conditions, pH between 2 and 4). The final solutions were analyzed with inductively coupled plasma optical emission spectroscopy (ICP-OES) for Pb and REE concentrations, while solids were filtered, dried, and analyzed with powder X-ray diffraction (PXRD), scanning electron microscopy (SEM/EDS), Raman spectroscopy, and differential thermal analysis (DTA/TG).

As expected, monoclinic analogs of rhabdophanes precipitated in the absence of Pb: LaPO4·0.67H2O, CePO4·0.67H2O, and SmPO4·0.67H2O. However, at the presence of Pb2+, distinct new phases were formed. This precipitation removes REE elements from the solution very efficiently. The product forms extremely fine (<1 mm) crystalline precipitate in the form of globular aggregates. XRPD patterns of each of them are nearly identical, shifted towards higher angles as the ionic radius decreases in the order La – Ce – Sm. At this stage of research, the structure of these phases could not be identified conclusively. Chemical composition was approximated using SEM/EDS microanalysis (the precipitate is too fine for a microprobe). Raman spectrum indicates that the phases are hydrated and DTA analysis allowed to estimate the water content. At this stage of research, the chemical formula has been determined as La2Pb3(PO4)4 · nH2O, Ce2Pb3(PO4)4 · nH2O, and Sm2Pb3(PO4)4 · nH2O, where n is between 3.3 and 3.5. Such unexpected results provide better insight into the new recovery pathways currently being explored for these critical raw materials. The results of these preliminary experiments open up new avenues for exploring as yet unknown crystalline phases composed of Pb-REE phosphates with potentially interesting practical applications.

This research was partly funded by NCN research grants no. 2021/43/O/ST10/01282 and 2019/35/B/ST10/03379.

How to cite: Staszel, K., Jędras, A., Skalny, M., Dziewiątka, K., Urbański, K., Sordyl, J., Rybka, K., Majka, J., and Manecki, M.: Impact of Pb2+ presence on precipitation of REE phosphates (analogs of rhabdophane) from aqueous solutions., EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-8801, https://doi.org/10.5194/egusphere-egu23-8801, 2023.

12:15–12:25
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EGU23-10435
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ECS
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On-site presentation
Ziyi Zhu and Ian Campbell

Zircon is an invaluable accessory mineral found in a wide range of crustal rocks. It can faithfully record its host rock’s composition, over long periods of geological time, leading to its wide use in studies of continental evolution. Detrital zircons collected from Earth’s modern rivers provide a representative sample that can be used to study the evolution of the continental crust on a large scale, aided by long-time sediment-sediment recycling, which results in the efficient mixing of zircons from source rocks of diverse origins.  

We use the Lu contents in zircons to identify those that come from the high-pressure zones of the deep mountain roots. By applying this technique to our global data base of zircon from major rivers, we show that Nuna and Gondwana were periods when Earth’s topography was dominated by high, Himalayan-type mountains, whereas Rodinia was not. The dramatic difference between Rodinia on one hand, and the amalgamation of Nuna and Gondwana on the other, is also manifested in other geological proxies, such as peaks in the average metamorphic pressure, seawater Sr isotope and S-type granite abundance. The two periods of extensive high mountain (supermountain) formation coincide with two major changes in Earth’s evolution: (i) postulated increases in atmospheric oxygen, and (ii) major biological advances. We argue that the big evolutionary changes that occurred during these two periods were potentially driven by dramatic increases in the supply of bio-limiting nutrients into the oceans, which resulted from the rapid erosion of Earth’s two supermountains.

How to cite: Zhu, Z. and Campbell, I.: Earth’s supermountains as revealed by detrital zircon from modern rivers linked to biological evolution, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-10435, https://doi.org/10.5194/egusphere-egu23-10435, 2023.

Posters on site: Mon, 24 Apr, 14:00–15:45 | Hall X2

Chairpersons: Jannick Ingrin, Juraj Majzlan, Catherine McCammon
X2.98
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EGU23-15126
Christiane Wagner, Beate Orberger, Johan Villeneuve, Omar Boudouma, Nicolas Rividi, Ghassem Nabatian, Maryam Hornamand, and Iman Moussef

Iron ore deposits from Iran are spatially related to the main suture zones of the Iranian continental fragmented block. In western Iran, the Sanandaj-Sirjan structural zone (SSZ) hosts several iron ore deposits interpreted being of volcano sedimentary, hydrothermal or mixed volcano sedimentary-skarn origin. In the northern part of the SSZ the early Cambrian (~530 Ma) Takab iron ore deposit consists of disseminated, layered and nodular magnetite mainly hosted in folded micaschists, and also in calcschists or metavolcanics. Quartz may show grain boundary migration and feldspar is partly altered. Accessory minerals are Mn-Ba-oxides, barite, monazite ± uraninite and Mn-carbonate (in calschists) in the matrix or in cross-cutting veins.

The low concentrations of Cr (<30 ppm) and Ni (10 ppm), low Ti (15-200 ppm) and V< 100 ppm) and high Mn (1800-2600 ppm) are consistent with a hydrothermal origin. Nodular magnetite shows distinct higher Mn (9400 ppm) and disseminated magnetite higher Ti (1400 ppm).

All magnetite types show positive Eu anomalies, stronger in nodular and disseminated magnetite, and strong positive Y anomalies, with Y/Ho ratios (25-40) similar to that of MOR- hydrothermal fluids.  The (La/Yb)PAAS ratios are >1in disseminated (1.2) and nodular magnetite (2.2), but <1 in layered magnetite (0.5-0.7). Nodular magnetite shows a negative Ce anomaly, similar to that of the calcschists. These results indicate mixing of hot hydrothermal fluid and seawater during the precipitation of the Takab BIF.

In nodular magnetite the average ∂56Fe of -0.3 ‰ is typical of low T-hydrothermal environment, while the heavier ∂56Fe (1.4 ‰) in disseminated magnetite points to magmatic or magmatic-hydrothermal fluid. ∂56Fe data in the layered magnetite are variable (-0.2 to +1.12 ‰) but mostly in the magmatic-hydrothermal box of discrimination diagrams. ∂18O values are positive in disseminated and nodular magnetite (+2.15‰ and +5.30 ‰ respectively on average), and vary from -2.52 ‰ to +1.22 ‰ in layered magnetite.

Based on the trace elements and REE data it can be concluded that primary layered magnetite ore crystallized statically from a Fe-Si rich mixed seawater and hot hydrothermal fluid. Regional deformation induced dynamic recrystallization of quartz, and disruption of magnetite bands.The chemical and isotopic signature of the disseminated magnetite points to a predominant imprint of an ortho-magmatic fluid. However, post primary mineralization hydrothermal alterations complicate the signal recorded by magnetite and evidence a complex story: for example, the lighter ∂18O of layered magnetite suggests re-equilibration with low temperature fluid. Similarly, the low ∂56Fe of nodular ore results likely from the precipitation of magnetite from a light hydrothermal fluid that may have dissolved a primary magnetite with heavy iron isotope signature. Moreover, re-equilibration with carbonated rocks likely results in the observed negative Ce anomaly and higher ∂18O (up to 6.30 ‰ on average).

How to cite: Wagner, C., Orberger, B., Villeneuve, J., Boudouma, O., Rividi, N., Nabatian, G., Hornamand, M., and Moussef, I.: Resolving the source and ore-forming processes of the Takab Iranian BIF using Fe and O isotope pairs in magnetite., EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-15126, https://doi.org/10.5194/egusphere-egu23-15126, 2023.

X2.99
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EGU23-1538
Chanmin Yoo, Mun Gi Kim, and Kiseong Hyeong
Polymetallic nodules in abyssal plains have long attracted attention as potential resources for some critical metals. Thier exploitation may cause a serious disturbance to the marine environment, and proper environmental impact assessments must be made beforehand. Discharge of the fluid-particle mixture tailings after hydraulic lifting is one of the poorly understood disturbances in the mining of polymetallic nodules, with fines generated by collisions between nodules and pipe walls making up an important part of the discharge. In order to better understand the formation process and properties of these nodule fines, degradation experiments were conducted on two types of polymetallic nodules from the Clarion-Clipperton Fracture Zone, eastern Pacific. During the experimental degradation in a planetary ball mill, the portion of fine particulates in the size of several to few tens of micrometers gradually increased. This confirms that hydraulic lifting will generate significant amount of nodule fines that are too small to be recovered and are likely to be discharged into the ocean. Processes such as abrasion and attrition are likely responsible for their production. The fines generated have higher contents of Al, K, and Fe and lower contents of Mn, Co, Ni, As, Mo, and Cd compared to the average composition of the original nodules. Release of sediment paticles encapsulated in the nodules is largely responsible for the difference, but uneven contribution of ferromanganese minerals and irregular behaviors of some elements such as Pb were also observed. The collected results show that the fines generated during lifting of polymetallic nodules are not the same as simple nodule powder and have significant compositional differences depending on the particle size, and a more detailed approach is needed for the environmental impact assessment.
 

How to cite: Yoo, C., Kim, M. G., and Hyeong, K.: Fines produced from degradation of polymetallic nodules: implications for deep-sea mining, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-1538, https://doi.org/10.5194/egusphere-egu23-1538, 2023.

X2.100
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EGU23-3189
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ECS
Julia Sordyl, Carmen Chamberlain, Teagan Sweet, Peter C. Burns, and Maciej Manecki

Apatite supergroup minerals are tolerant to various chemical substitutions. Data on the presence of uranium in natural lead apatite - pyromorphite (Pb5(PO4)3Cl) indicate that the content of U(VI) reaches up to 0.5 wt%. This indicates that significant amounts of U(VI) may be accommodated in the pyromorphite structure, which may affect the ultimate development of Pb-apatite nuclear waste forms. However, the U content of natural pyromorphite represents the concentration of U in source solutions rather than in the mineral structure. The structural constraints on the upper limit of U incorporated into pyromorphite at low temperature are unknown. This is relevant to U and Pb-apatite applications in radioactive waste remediation.

In the present study, eight compounds were synthesized from aqueous solutions in a still water column under ambient conditions. A solution containing UO2(NO3)2∙6H2O and Pb(NO3)2 in varied molar proportions was added slowly by dripping through a glass funnel into the solution containing dissolved NaH2PO4·6H2O and NaCl. In each synthesis, the molar ratio of UO2:Pb was varied as follows: 1:1; 1:10; 1:20; 1:30; 1:40; 1:50; 1:100; 1:200, aiming at the final composition of Pb5-x(UO2)x(PO4)3Cl. The overall goal was to reach the upper limit of U incorporation into pyromorphite upon precipitation at room temperature. The final solutions were analyzed with inductively coupled plasma optical emission spectroscopy (ICP-OES) for Pb and U concentrations, while solids were filtered, dried, and analyzed with powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) and Raman spectroscopy.

In all experiments precipitation was observed. U was removed from the solution at levels ranging from 87.2% (σ = 1.9) to 94.1% (σ = 2.5), and Pb was removed at levels ranging from 95.7% (σ = 2.6) to 98.4% (σ = 1.9). PXRD patterns revealed that five of the eight synthesis products were the synthetic analogs of pyromorphite containing (UO2)2+ partially substituting Pb2+. The observed Raman bands at the regions: 1050 – 918 cm-1, 586 – 541 cm-1, and 439 – 392 cm-1 were attributed to the vibrations of the (PO4)3+ units, while those at 830 – 800 cm-1 were assigned to the (UO2)2+ units. As the U content of the initial solution increased, the intensity of the (UO2)2+ band increased relative to the highest band of (PO4)3+. When the initial concentration of U was the highest, coprecipitation of a second phase, the not-yet-described Pb-analog of meta-autunite (Ca(UO2)2(PO4)2∙6H2O), was observed.

This experimental study showed that precipitation of pyromorphite can effectively remove uranium from aqueous solutions although substitution in pyromorphite cannot exceed 1 wt% U(VI) when precipitated under ambient conditions. The coprecipitation of the potentially new lead uranium phosphate is further investigated.

This research was funded by the Polish NCN grant no. 2019/35/B/ST10/03379.  

How to cite: Sordyl, J., Chamberlain, C., Sweet, T., Burns, P. C., and Manecki, M.: Immobilization of uranium from aqueous solutions by precipitation of lead apatite – pyromorphite (Pb5(PO4)3Cl), EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-3189, https://doi.org/10.5194/egusphere-egu23-3189, 2023.

X2.101
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EGU23-3692
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ECS
Mineralogical and isotopic studies in the Gol-Cheshmeh copper deposit, NE Iran
(withdrawn)
Behrooz Bakhshandeh, Azam Entezari Harsini, Rahim Masoumi, Farahnaz Bakhshandeh GharehTapeh, and Asgar Babaei
X2.102
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EGU23-6406
Jean-François Boily, N. Tan Luong, and Michael Holmboe

Hydrophilic nanominerals exposed to air moisture host thin water films that are key drivers of reactions of interest in terrestrial and atmospheric settings. Water films can trigger irreversible mineralogical transformations, and control chemical fluxes across networks of aggregated nanomaterials. Using X-ray diffraction, vibrational spectroscopy, electron microscopy, and (micro)gravimetry we tracked water film-driven transformations of periclase (MgO) nanocubes to brucite (Mg(OH)2), as well as to amorphous magnesium carbonate (AMC) in the presence of moist CO2. We show that 3-4 monolayer-thick water films first triggered the nucleation-limited growth of brucite and AMC, and that water film populations continuously grew on newly-formed nanoparticles. Small (8 nm-wide) nanocubes were completely converted to brucite under this growth regime, while growth on larger (32 nm-wide) nanocubes transitioned to a diffusion-limited regime when (~1.3 nm-thick) brucite nanocoatings began hampering the flux of reactive species to growth fronts. In contrast, AMC growth was limited to the nucleation-limited regime as nanocoatings hindered the transport of reactive species from the MgO core to growth fronts. By resolving nanocoating growth on a model reactive hydrophilic mineral, this work provides new insight into the study of water film-driven nanomineral transformations that are important to geosciences.

How to cite: Boily, J.-F., Luong, N. T., and Holmboe, M.: MgO nanocube hydroxylation and carbonation by nanometric water films, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-6406, https://doi.org/10.5194/egusphere-egu23-6406, 2023.

X2.103
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EGU23-3809
Yongmei Zhang, Xuexiang Gu, Shiyue Yao, and Wei Zhao

The Gaogangshan deposit in the northern Lesser Xing'an Range, NE China, consists of typical collision-type porphyry Mo mineralization related to Permo-Triassic granitic intrusions. Ore-forming process is recorded by multiple generations of quartz, including pre-ore stage quartz with unidirectional solidification texture (UST), early ore-stage quartz-molybdenite veins with K-feldspar alteration halos (Q1), late ore-stage quartz-sulfides veins with sericite alteration (Q2), and post-ore stage quartz veins (Q3) associated with calcite and fluorite. Cathodoluminescent textures, trace elements and fluid inclusions in quartz reveal physicochemical conditions, evolution of ore fluids and the Mo mineralization process. The UST quartz and Q1 veins are dominated by CL-bright homogenous and/or granular mosaic textures, containing more Ti concentrations (average = 35-42 ppm) than Q2 and Q3 veins. The molybdenite-bearing Q2 veins are dominated by CL-gray granular and zonal textures, displaying less CL intensity and lower Ti concentrations (average = 16 ppm) than early-stage quartz. The Q3 veins have the lowest CL-intensity and the lowest Ti concentrations (average = 2.5 ppm) among all quartz types. Three types of inclusions are identified in above quartz samples, including liquid-vapor aqueous inclusions, CO2-bearing liquid-vapor aqueous inclusions and halite-bearing multiphase aqueous inclusions. The ore-forming fluids in ore-stage Q1 and Q2 veins are dominated by large salinity variation (2.3-38.9 wt% NaCl equiv.), CO2-bearing (4.2-8.9 mol%) two-phase aqueous inclusions with vapor volumetric proportions of 30-65%. Intersections of fluid inclusion isochores with Ti-in-quartz isopleths yield quartz formation conditions of ~2.2 kbar at ~640°C for UST quartz, ~1.25 kbar at ~510°C for Q1, ~1.0 kbar at ~440°C for Q2, and ~0.37 kbar at ~220°C for Q3. The Gaogangshan porphyry Mo deposit formed at depths of 3.8 to 4.7 km. Fluid decompression and temperature decreasing resulted in molybdenite precipitation.

How to cite: Zhang, Y., Gu, X., Yao, S., and Zhao, W.: Texture and trace element geochemistry of quartz in porphyry system: Perspective from the Gaogangshan Mo Deposit, NE China, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-3809, https://doi.org/10.5194/egusphere-egu23-3809, 2023.

X2.104
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EGU23-11456
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ECS
Adrián López-Quirós, Christof Pearce, Javier Dorador, Fernando Nieto, Francisco J. Rodríguez-Tovar, Henrieka Detlef, Katrine Elnegaard Hansen, Joanna Davies, and Marit-Solveig Seidenkrantz

Process-based, mechanistic research of mineral authigenesis has been progressively utilized to understand the biogeochemical processes taking place at the sediment–water interface (SWI), and to capture long-term sedimentary (biogeochemical) records of paleoenvironments. A better understanding of mineral authigenic sedimentary processes directly beneath the SWI in Arctic continental shelves is thus fundamental as Earth’s polar regions are at greatest risk of future climate change. This is in part due to disturbances in the benthic–pelagic coupling related to changes in ocean circulation and sea ice dynamics.

In this study, we aim at focusing on the Holocene period by investigating sedimentary archives recovered from the NE Greenland shelf during the NorthGreen17 Expedition. Here we combined a suite of sedimentological (e.g., detailed ichnological analysis and taphonomic features of the benthic foraminifera Cassidulina neoteretis), mineralogical (bulk and clay mineralogy) and geochemical (major, trace and rare earth elements, and δ13C and δ18O stable isotope signatures recorded in Cassidulina neoteretis) proxies with bulk organic matter parameters (δ13C, TOC, TN). The first results of this study, presented during the EGU General Assembly 2023 in Vienna, Austria, focus on several important points such as: (1) changes in sedimentation (geochemical characteristics) over the NE Greenland sediment profiles; (2) evolutionary characteristics of terrigenous influx, redox conditions and productivity; and (3) controlling factors and modes of organic matter accumulation.

How to cite: López-Quirós, A., Pearce, C., Dorador, J., Nieto, F., Rodríguez-Tovar, F. J., Detlef, H., Elnegaard Hansen, K., Davies, J., and Seidenkrantz, M.-S.: Early diagenetic transformations, fluxes, and reaction rates in Holocene sediments of the NE Greenland shelf, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-11456, https://doi.org/10.5194/egusphere-egu23-11456, 2023.

X2.105
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EGU23-12038
Maciej Manecki, Julia Sordyl, Mikołaj Leś, and Kacper Staszel

   Supply of technologically important rare earth elements (REEs) is of concern in Europe. Important European sources are associated with apatites and phosphate rocks. Due to high production, this is a potential resource, but technical and cost challenges hinder the commercial recovery of REEs. A new extraction approach exploring selective co-precipitation of REEs and Pb in the form of phosphates offers cheap and effective technology which can be included in the existing flow of ore processing.

   Most hydrometallurgical REE enrichment processes vary in efficiency for heavy and light REE. The aim of the present study was to verify whether this novel method of removing REEs from solution by co-precipitation with Pb-phosphates also has this drawback. Solution containing ca. 100 mg/L of Sc, Y, Th, and lanthanides (except Pm) was mixed with a solution containing Pb2+, PO43-, and Cl- to induce precipitation (pH between 2 and 4, ambient conditions). The initial and final solutions were analyzed with inductively coupled plasma optical emission spectroscopy (ICP-OES) for Pb and REE concentrations, while solids were filtered, dried, and analyzed with powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM).

   In all experiments, the formation of a precipitate composed mainly of crystalline pyromorphite (Pb,REE)5(PO4)3Cl was found, accompanied in smaller amounts by a second, less crystalline phase. In the SEM images, pyromorphite is apparent as hexagonal rods and needles (micrometers in size) while the second phase forms Cl-free, loose aggregates of globular grains, tens of nanometers in size. The extent of REE substitution for Pb in the pyromorphite structure, determined in a separate study for La, is at the order of ca. 1 wt. % La2O. At the experiment conditions, the charge difference between Pb2+ and REE3+ is compensated by Na+. Significant amounts of REEs are also precipitated in the form of Cl-free Pb-REE-phosphate, which constitutes an accompanying phase or a mixture of phases. At this stage of research, the structure and chemical composition of these phases could not be identified conclusively: the XRD pattern is obscured by pyromorphite, and the precipitate is too fine for regular microprobe analysis.

   The concentrations of metals in question were reduced in the solution very significantly. For initial concentrations in the 1-10 ppm range, they were completely removed from solution to concentrations below detection limits of 0.002 ppm (concentrations of Y and La dropped down to below 0.01 ppm). For initial concentrations of 80 ppm, only Sc and Th were removed completely while concentrations of Ce, Pr, Nd, Sm, Eu, Gd, and Tb were reduced by over 60%, these of Dy, Ho, Er, Tm, Yb, and Lu by ca. 50 % and concentrations of Y and La dropped down only by ca. 40%. This may indicate that although the fractionation of REEs is not systematic and not very significant, heavy REEs are removed from the solution slightly less effectively. However, the crystalline and heavy precipitate allows easy separation of the solution.

This research was partially funded by NCN research grants no. 2019/35/B/ST10/03379 and 2021/43/O/ST10/01282. 

How to cite: Manecki, M., Sordyl, J., Leś, M., and Staszel, K.: Fractionation of REEs upon removal from solution by precipitation of lead apatite – pyromorphite (Pb,REE)5(PO4)3Cl, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-12038, https://doi.org/10.5194/egusphere-egu23-12038, 2023.

X2.106
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EGU23-13147
Bruno Reynard and Xin Zhong

An experimental calibration of the Raman shifts of quartz with pressure up to ~2 GPa and differential stress up to ~0.6 GPa parallel and perpendicular to the c-axis is presented. The position of the 206 cm−1 peak depends only on hydrostatic pressure P, and its pressure dependence is recalibrated with a peak fitting procedure that is more adequate for Raman barometry than previous calibrations. The position of the 128 and 464 cm−1 peaks depends on P and also on differential stress , which can be determined from the position of these two peaks knowing hydrostatic pressure from the position of the 206 cm−1 peak. This calibration provides direct relationships between Raman shifts and stress, with a simple formulation of residual pressure and differential stress assuming uniaxial stress along the c-axis of quartz inclusions. It is tested on data from experimental and natural inclusions. Pressures from the present calibration are similar within uncertainties to those obtained with previous experimental calibration within uncertainties, and experimental inclusions yield residual pressures consistent with synthesis pressure. Inconsistent residual differential stresses are obtained from the 128 and 464 cm−1 peaks on some experimental inclusions, providing a criterion for identifying inclusions under complex stress conditions that are not appropriate for geobarometry. Recent data on natural inclusions show self-consistent differential stress, consistent with the assumption of major stress along symmetry axis of the inclusion crystals and with values expected from elastic models. The average pressure values from the 128 and 464 cm−1 peaks is similar to the residual pressure from the 206 cm−1 peak that depends only on hydrostatic pressure. It can be used to obtain pressure when the 206 cm−1 peak position cannot be used due to interference with host mineral peaks. Using the 128 and 464 cm−1 peaks alone, or averaging either 128 and 206 or 206 and 464 cm−1 peaks can induce systematic bias in the residual pressure determination. Applications of the present results to natural inclusions suggest that combined determination of residual pressure and differential stress may be used both for barometry and thermometry pending further calibration.

How to cite: Reynard, B. and Zhong, X.: Quartz under stress: Raman calibration and applications to geobarometry of metamorphic inclusions, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-13147, https://doi.org/10.5194/egusphere-egu23-13147, 2023.

Posters virtual: Mon, 24 Apr, 14:00–15:45 | vHall GMPV/G/GD/SM

Chairpersons: Julien Reynes, Jannick Ingrin, Melanie J. Sieber
vGGGS.15
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EGU23-5720
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ECS
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Amritpaul Singh

The Newania carbonatite complex (~1473 Ma) in northwestern India is one of the oldest carbonatitic occurrence in India. It is a plutonic complex, comprising of two types of carbonatites and fenitized aureole within host Untala granite of Banded Gneissic Complex. The two types of carbonatites present include: (1) magnesiocarbonatite, and (2) ferrocarbonatite. This study illustrates textural and compositional variation of carbonate phases present in magnesiocarbonatite. Magnesiocarbonatite is principally composed of dolomite-ankerite series carbonates and accessory magnesite-siderite series carbonates. Dolomite-ankerite series carbonates occur as coarse-to-medium-grained (>200 µm) subhedral-to-anhedral crystals, displaying three types of deformation textures: (1) equigranular mosaic fabric with frequent triple junctions, thick-to-thin twin lamellae and absence of strain-derived deformational changes; (2) elongated medium-grained crystals, oriented in one direction, having high aspect ratio and twin lamellae density; and (3) coarse-grained crystals, mostly subhedral, with straight-to-lobate-to-serrated grain boundaries; surrounded by numerous fine-grained crystals which at places, impregnates the coarse carbonate crystals and form finger-like and island structures. Texture (1) is typical of plutonic carbonatites in extensional intraplate setting and texture (2) and (3) represents deformational changes as a result of high-strain and low-T conditions to high-T dynamic recrystallization, respectively. However, deformation has minor to none influence on the liquidus composition of dolomite-ankerite series carbonates. These carbonates, irrespective of texture, correspond compositionally with dolomite and ferroan dolomite, having Fe2+/Fe2++Mg=0.12–0.43. Concomitant increase in Fe and Mn and decreasing Mg at relatively restricted Ca content indicate magmatic origin and compositional evolutionary trend. Magnesite-siderite series carbonates are medium-grained (<300µm) subhedral to anhedral discrete crystals. These are magmatic in origin and are crystallized simultaneously with surrounding dolomite-ankerite series carbonates. Compositionally, these are ferroan magnesite and magnesian siderite with restricted Mg:Fe ratio of 0.96–1.12. The presence of magmatic magnesite-siderite series carbonates and the evolutionary trend displayed by dolomite-ankerite series carbonates attest for magmatic origin of the Newania carbonatites. Experimental work has demonstrated that dolomite and magnesite are stable up to the mantle depths of 80–110 kms and >110 kms, respectively. As the pressure approaches 32 kBar, the melts produced via. partial melting of phlogopite-bearing peridotite becomes more enriched in its magnesian content as the carbonate mineralogy changes from dolomite to magnesite. Such mantle-derived carbonatitic melts are inferred to be parent of the Newania carbonatites.

How to cite: Singh, A.: Textural and compositional variation of carbonate minerals in the Newania carbonatites, Rajasthan, India, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-5720, https://doi.org/10.5194/egusphere-egu23-5720, 2023.

vGGGS.16
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EGU23-8396
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ECS
Bo Wang, Shiyue Chen, Jihua Yan, and Qingmin Dong

Abstract:Base on the identification of rock flakes, XRD, physical property analysis and field EM, the characteristics of the reservoir, the types of the reservoir are systematically analyzed. The results show that the main rock types of the upper sandstone reservoir of Cangdong depression are chip quartz sandstone (52%), followed by feldspar quartz sandstone (32%) and quartz sandstone (16%). Because the average burial depth of the upper sandstone reservoir is greater than 2900m, the existence of native pores is rarely found under strong compaction, and the reservoir space type of this reservoir is mainly secondary dissolved pores and intercrystalline micropores, but there are few cracks in local areas. This reservoir has a mean porosity of 7.71% and mean permeability of 0.59 mD. The types of diagenesis in the upper sandstone reservoir mainly include compaction, cementation, dissolution and metasomatism. Combined with the law of the combination and evolution of Ro and clay minerals and the structural characteristics of the microscopic particles, we can know that the upper sandstone of the second section in the hole of Cangdong depression is in the early stage.

 

Keywords: Cangdong depression; 2nd member of Kongdian formation; upper sandstone; reservoir; diagenesis

How to cite: Wang, B., Chen, S., Yan, J., and Dong, Q.: nd, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-8396, https://doi.org/10.5194/egusphere-egu23-8396, 2023.

vGGGS.17
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EGU23-7833
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ECS
Yang Yang

The Jiama deposit is located in the eastern part of Gangdise metallogenic belt, and is one of the largest copper polymetallic deposits in Tibet. Pyrrhotite is one of the most common metallic minerals of the Jiama deposit.Its typomorphic characteristics not only reflect its formation environment but also indicate its formation mechanism and deposit genesis. In this paper, pyrrhotite samples from different lithologies were collected, and the morphology, composition and structure of pyrrhotite were analyzed by means of mineralogy, X-ray diffraction and electron microprobe analysis. The study shows that pyrrhotite of the Jiama deposit is mainly distributed in the skarn and hornfels, which are far away from the center of the porphyry intrusion. The powder X-ray diffraction curves and cell parameters of pyrrhotite show that the pyrrhotite in the skarn is mainly high-temperature hexagonal pyrrhotite. The pyrrhotite in the hornfels is a mixture like associated body of high-temperature hexagonal pyrrhotite and low-temperature monoclinic pyrrhotite, with the monoclinic pyrrhotite being dominant. The results of electron microprobe analysis of pyrrhotite in skarn and hornfels show that the content of Fe in pyrrhotite of skarn is 60.09%~60.71%, averaging 60.38%, and the content of S is 38.18%~38.69%, averaging 38.35%, with the corresponding chemical formula being Fe8S9~Fe10S11. At the same time, the content of Fe in pyrrhotite of hornfels is 59.05%~59.57%, averaging 59.10%, and the content of S is 39.28%~39.95%, averaging 39.59%, with the corresponding chemical formula being Fe5S6~Fe7S8. Based on the above mineralogical characteristics, the author hold that the precipitation mechanism of pyrrhotite in the deposit is as follows: the hot magma surged and interacted with the carbonate and clasolite formation, and the addition of atmospheric water caused the ore-forming fluid to quickly cool down in the hornfels, forming associated body of high-temperature hexagonal pyrrhotite and low temperature monoclinic pyrrhotite. At the same time, a large number of ore-bearing hydrothermal fluids formed and filled in favorable ore-forming space (mainly interlayer fracture zone) for precipitation and mineralization, forming skarn orebodies; the fluid then experienced a slow cooling in the skarn ore segment to form a high temperature hexagonal pyrrhotite. Based on geological characteristics of the deposit and geochemical characteristics of related elements, it is concluded that the Jiama deposit type is of the porphyry-skarn type.

How to cite: Yang, Y.: Typomorphic mineralogical characteristics of pyrrhotite in Jiama Cu polymetallic deposit, Tibet, and its geological significance, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-7833, https://doi.org/10.5194/egusphere-egu23-7833, 2023.

vGGGS.18
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EGU23-11367
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ECS
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Parminder Kaur, Gurmeet Kaur, and Sebastian Tappe

The Gondwana sedimentary sequences of Damodar Valley in eastern India are intruded by the potassic intrusives of Cretaceous age. This study focuses on the mineralogy of one such potassic-rich dyke occurring in an underground Jamadoba colliery seam XI in Jharia basin, Jharkhand, India. It consists of olivine, phenocrystal phlogopite, microphenocrysts of phlogopite, apatite and diopside embedded in the groundmass comprising phlogopite, apatite, amphibole, ilmenite, rutile and K-feldspar. The presence of forsteritic olivine, low Al and Fe rich phlogopite, low Al-Na diopside, Al-poor and Ti-rich amphiboles and Fe-rich K-feldspar indicate the lamproitic character of the potassic dyke. Using a mineralogical-genetic classification scheme, the Jamadoba-XI dyke is classified as an olivine-phlogopite-apatite-diopside-amphibole-feldspar lamproite.

How to cite: Kaur, P., Kaur, G., and Tappe, S.: Mineralogy of a Jamdoba-XI lamproite dyke from Jharia basin, Jharkhand, India, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-11367, https://doi.org/10.5194/egusphere-egu23-11367, 2023.

vGGGS.19
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EGU23-4240
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ECS
Aaron Herve Mbwe Mbissik and the Abdellatif Elghali, Muhammad Ouabid, Otmane Raji, Jean-Louis Bodinier, Hicham El Messbahi

Potash is one of three important fertilizers (i.e., N, P and K) needed for plants and provides K as essential nutrient worldwide. The largest sources of raw materials for potash production are evaporites sedimentary rocks, mainly sylvite (potassium chloride -KCl) in the fertilizer industry. However, the potash resource’s is principally located in the northern hemisphere and their needs are highly important in southern countries, particularly in Africa due to crop demands . Furthermore, the low use of potash is exacerbated by the high market prices beyond the reach of farmers, demand inflations, and causing rampant K deficiency in several Africa soils. It is therefore imperative to search for alternative K sources, potentially using the locally available silicate minerals such as K-feldspars and feldspathoids, and other important K-concentrated minerals such as kalsilite or orthoclase present in many African countries. These minerals represent promising sources for the development of new and ecological fertilizers, particularly adapted to tropical soils. However, silicate minerals such as K-feldspar (KAlSi3O8) are characterized by a low dissolution rate that is not only extremely low compared to evaporitic potash but also does not allow having enough bioavailable potassium. Indeed, the silicon-oxygen tetrahedron (SiO4)4− and aluminum-oxygen tetrahedron (AlO4)5− configuration leads to a solid network structure that inhibits potassium availability. Consequently, to enhance potassium release, the crystal matrix of feldspar must be destroyed or at least altered. The present study was undertaken to investigate potential deposit of K-mineral sources present in Morocco. Six potassic igneous rocks (syenites and trachytes) from the Tamazeght, Jbel Boho, Ait Saoun, and El Glo’a regions (Morocco) were sampled and characterized. Then they were hydrothermally treated to enhance their K release for potential use as potassic fertilizers. The raw materials are mainly formed by microcline (up to 74%), orthoclase (20–68%), albite (36–57%), biotite muscovite (15–23%), and titanite, calcite, hematite, and apatite as accessory minerals. These samples were crushed and milled to reach a particle size <150 μm and mixed with 4 N NaOH solution in an autoclave. The powders were allowed to react with the solution at 170°C for 7h. X-ray diffraction (XRD), thermal gravimetric analysis (TGA), infrared spectroscopy (IRTF), and scanning electron microscopy (SEM-EDS) were carried out on treated samples to characterize the mineralogical and structural changes due to the alkali-hydrothermal treatment.The treated material was leached and the elements released were measured using inductively coupled plasma–atomic emission spectroscopy (ICP-AES). The hydrothermal process showed a strong effect on structure breakdown as well as on the release of K and other nutrients such as P, Fe, Si, Mg, and Ca. Therefore, the alkali-hydrothermal treatment allowed the release of 50.5 wt% K. Moreover, the release of Mg, Ca, Fe, P, K, and Si were also significantly increased. The ultimate project goal is to develop novel approach for locally production of K-based fertilizer from K-alkaline rocks and these encouraging results need to be examined further.

How to cite: Mbwe Mbissik, A. H. and the Abdellatif Elghali, Muhammad Ouabid, Otmane Raji, Jean-Louis Bodinier, Hicham El Messbahi: Alkali-Hydrothermal Treatment of K-Rich Igneous Rocks for Potassic Fertilizers production in Morocco, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-4240, https://doi.org/10.5194/egusphere-egu23-4240, 2023.

vGGGS.20
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EGU23-3219
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ECS
Arkodeep Sengupta and Mruganka Kumar Panigrahi

Raman microspectrometry and EPMA have been used to compositionally characterize different types of sphalerite based on its FeS mole fraction. This is in reference to some previous studies where the mole fraction of FeS in sphalerite was quantified by measuring the relative intensities of peaks in Raman spectra. Based on petrographic study of samples, sphalerite was distinguished on the basis of its colour (transparent, honey yellow translucent and dark brown translucent). This was followed up by Raman microspectrometric analysis. The acquisitions were made using the Horiba LabRAM HR Evolution with a multichannel Peltier cooled (-70℃) CCD detector, using a 532 nm frequency-doubled Nd:YAG laser, 30s exposure and a laser power of 25% in the spectral range of 200-700 cm-1. Three distinct peaks were obtained, of which the ones at ~299 and ~329 cm-1 are assigned to Fe-S vibration modes, while the one at ~350 cm-1 is assigned to the Zn-S vibrations. From Fig. 1, it can be observed that there is a strong correlation between the peak intensities and the Fe content, with some peaks dominating the other within individual spectrum depending on their respective FeS and ZnS contents. After applying a baseline correction, the spectra were truncated within the range of 250-360 cm-1. The Pseudo-Voigt function (a linear combination of Gaussian and Lorentzian functions) was employed for deconvolution and peak-fitting. By measuring the heights of the peaks at 300 cm-1 (h1) and 350 cm-1 (h3), the h1/h3 ratio was computed. The FeS mole fraction was then calculated by substituting the values of the ratio in a linear equation. To validate the extracted sphalerite chemistry based on the iron content from Raman studies, elemental analysis was carried out using a Cameca SX-Five EPMA. The Fe concentrations, thus obtained, are in good agreement with the EPMA data (Fig. 2).

Keywords: Raman Microspectrometry, EPMA, Sphalerite, FeS mole fraction

             

How to cite: Sengupta, A. and Panigrahi, M. K.: Raman microspectrometric and EPMA characterization of Sphalerite from Zawar Group of Mines, Rajasthan, India, EGU General Assembly 2023, Vienna, Austria, 23–28 Apr 2023, EGU23-3219, https://doi.org/10.5194/egusphere-egu23-3219, 2023.

vGGGS.21
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EGU23-14477
Conditions of magma genesis and syn-tectonic emplacement of the granitic rocks of Tinos Island (Cyclades, Greece)
(withdrawn)
Christina Stouraiti, Konstantinos Soukis, Angeliki Papoutsa, Constantinos Mavrogonatos, Parthenios Alvanos, Sofia Laskari, and Panagiotis Voudouris