This session brings together scientists, forecasters, practitioners and stakeholders interested in exploring the use of ensemble hydro-meteorological forecast and data assimilation techniques in hydrological applications: e.g., flood control and warning, reservoir operation for hydropower and water supply, transportation, and agricultural management. It will address the understanding of sources of predictability and quantification and reduction of predictive uncertainty of hydrological extremes in deterministic and ensemble hydrological forecasting. Uncertainty estimation in operational forecasting systems is becoming a more common practice. However, a significant research challenge and central interest of this session is to understand the sources of predictability and development of approaches, methods and techniques to enhance predictability (e.g. accuracy, reliability etc.) and quantify and reduce predictive uncertainty in general. Ensemble data assimilation, NWP preprocessing, multi-model approaches or hydrological postprocessing can provide important ways of improving the quality (e.g. accuracy, reliability) and increasing the value (e.g. impact, usability) of deterministic and ensemble hydrological forecasts. The models involved with the methods for predictive uncertainty, data assimilation, post-processing and decision-making may include machine learning models, ANNs, catchment models, runoff routing models, groundwater models, coupled meteorological-hydrological models as well as combinations (multimodel) of these. Demonstrations of the sources of predictability and subsequent quantification and reduction in predictive uncertainty at different scales through improved representation of model process (physics, parameterization, numerical solution, data support and calibration) and error, forcing and initial state are of special interest to the session.