Black soils play a vital role in the global carbon cycle due to their high carbon stocks derived from their formation under specific environmental conditions. Black paleosols in landscapes, where under the present climate other soils dominate, provide valuable information about former environments and pedogenesis.
Here, we investigated black layers preserved in the floodplain of the Aue Creek, a tributary of the Leine River in Southern Lower Saxony, Central Germany. Its catchment is mainly made up of Triassic sandstone, and Triassic and Jurassic limestone, covered by Pleistocene periglacial slope deposits and loess, in which typically Luvisols have developed. In parts of the catchment, Luvic Phaeozems on the slopes testify former climatic conditions suitable for Phaeozem formation, which then shifted to conditions suitable for Luvisol formation. We took nine drill cores from the floodplain, in which black layers occurred, and analyzed them for pedomorphological features, radiocarbon ages of bulk soil organic matter (SOM), carbonate contents, dithionite-extractable Al, Fe, Mn, and Si, grain size distribution, total elemental and mineralogical composition. The majority of the calibrated radiocarbon ages of the bulk SOM of the black horizons fell into the Atlantic period (8545-5661 cal BP), while a few ages fell into the Subboreal-Subatlantic transitional (4519-3725 cal BP) and Subatlantic period, coinciding with the Iron Age (2314-2175 cal BP). These ages exceeded those of the underlying layers, which mostly dated to around 1600-1900 cal BP. One possible explanation for this phenomenon could be the hardwater effect which should, however also have affected the overlying and underlying layers. Another explanation is that the formation of the black horizons originally took place on the adjacent slopes, where it started already during the early Holocene. This hypothesis is supported by the relict Luvic Phaeozems that occur in the catchment. Thereby, the radiocarbon ages of the black material reflect the formation time of the biomass that was subsequently turned into SOM in a dynamic equilibrium of SOM accumulation and decomposition. The later a black soil was eroded, the later this dynamic SOM equilibrium stopped. On its way towards the floodplain, the eroded black soil material was most likely halted for some time as a colluvial deposit on the foot slopes. Only around 1600-1900 cal BP, when human influence led to enhanced erosion, some of the black sediments were remobilized, transported to the floodplain and redeposited there. Such cascade-wise erosion-deposition process may explain, how black material characterized by older SOM may have got embedded in between considerably younger sediments.
For a more comprehensive understanding of the formation of such black layers embedded in alluvial sediments, which have been reported from various regions of Germany, we recommend that future studies also include novel proxies such as vegetation biomarkers, in order to get a clearer picture of the vegetation, under which the black soils developed and test the above hypothesis.