GMPV4.4 | Early Earth Evolution – New Frontiers in Archean Studies
Orals |
Mon, 10:45
Tue, 10:45
Tue, 14:00
EDI
Early Earth Evolution – New Frontiers in Archean Studies
Including GMPV Division Outstanding ECS Award Lecture
Convener: Dominik SorgerECSECS | Co-conveners: Silvia Volante, Thomas Mueller
Orals
| Mon, 28 Apr, 10:45–12:30 (CEST)
 
Room K1
Posters on site
| Attendance Tue, 29 Apr, 10:45–12:30 (CEST) | Display Tue, 29 Apr, 08:30–12:30
 
Hall X2
Posters virtual
| Attendance Tue, 29 Apr, 14:00–15:45 (CEST) | Display Tue, 29 Apr, 08:30–18:00
 
vPoster spot 1
Orals |
Mon, 10:45
Tue, 10:45
Tue, 14:00

Orals: Mon, 28 Apr | Room K1

Chairpersons: Dominik Sorger, Silvia Volante, Thomas Mueller
10:45–10:50
10:50–11:10
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EGU25-4459
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solicited
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On-site presentation
Kristoffer Szilas

Archean cratons record complex geological histories with multiple episodes of magmatic and metamorphic events that overprint and obscure the oldest crustal remnants. Fieldwork still forms the cornerstone of geological research, enabling direct observation of rocks in their natural context to unravel Earth's complex history. However, the polymetamorphic nature of craton formation commonly results in strong deformation, metamorphism, and metasomatism, which complicates field relations and the tectonic interpretation of the cratonic nuclei.

In Greenland, the oldest component of the North Atlantic Craton consists of the Eoarchean Itsaq Gneiss Complex (IGC), including the >3.7 Ga Isua Supracrustal Belt (ISB). Until recently it was believed that highly deformed mafic and ultramafic enclaves within the IGC predate the main tonalitic continental crust of the region, and that some of these could potentially be Hadean.

However, recent research has shown these enclaves at Ujaragssuit to be roughly 900 million years younger than first proposed. Furthermore, purported anorthosite sheets associated with these enclaves are in fact metasomatized ultramafic rocks, which together with thermodynamic evidence for Eoarchean granulite facies metamorphism, has obvious tectonic implications.

Likewise, claims of preserved mantle fabrics at ISB have turned out to be found within deserpentinized rocks of cumulate origin. Finally, the supposed oldest evidence for life on Earth is found in the form of graphite inclusions within garnet, which have turned out to be one billion years younger than initially assumed.

Such corrections of our understanding of the early Earth are a natural part of the scientific process and are to be expected as our analytical capabilities increase. However, the above examples demonstrate that a more modest approach should be adopted within the early Earth research community.

Faster progress could be made by relying on careful and conservative interpretations in an incremental manner, rather than making outrageous claims as encouraged by many journals and the media. We should keep Brandolini's law in mind and avoid pushing our models beyond what the data supports.

How to cite: Szilas, K.: New perspectives on the tectonic evolution of the early Earth driven by advances in geochronology and thermodynamic modelling: examples from Greenland, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-4459, https://doi.org/10.5194/egusphere-egu25-4459, 2025.

11:10–11:20
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EGU25-5587
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On-site presentation
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Esa Heilimo, Jaana Halla, Kumar Batuk Joshi, and Matti Kurhila

The transformation of basaltic crust into thick, buoyant felsic crust with a tonalite-trondhjemite-granodiorite (TTG) composition was a pivotal process in Earth's evolution during the Archaean Eon (4.03–2.50 Ga). Geochemical modeling and experimental studies strongly support the hypothesis that TTGs formed via the partial melting of hydrated mafic rocks, though field evidence remains scarce. TTGs are categorized into two geochemical types: low-HREE and high-HREE (heavy rare earth elements) TTGs. While their genesis is widely attributed to the partial melting of hydrated basaltic crust, the mechanisms producing the two types remain debated.

This study presents U–Pb zircon ages to investigate the temporal relationships between the two TTG types in the Lake Inari terrain, Fennoscandia shield. Zircon populations from low- and high-HREE TTGs, along with adjacent porphyritic granitoids, indicate a prolonged migmatization phase from 2900 to 2600 Ma. This suggests sustained heat from a stationary mantle plume associated with stagnant or sluggish lid tectonics. The intermingling and parallel ages of high- and low-HREE TTGs imply a shared source rather than distinct tectonic settings.

Prolonged melting episodes of thickened felsic crust produced porphyritic granites between 2650 and 2500 Ma. The ∼1.9 Ga Lapland-Kola orogeny caused minor zircon recrystallization, but did not alter the Archaean migmatite morphology. TTG formation in the Lake Inari terrain peaked around 2.8 Ga, approximately 100 Ma before the proposed assembly of the Kenorland supercontinent.

The bimodal TTG-metabasalt association exhibits diverse migmatite structures, including metatexites, metatexite-diatexite transitions, and massive diatexites. These features formed due to crustal weakening, melt segregation, extraction, migration, and redistribution (SEMR) processes, as well as synanatectic strain. Metabasalts within the terrain likely represent remnants of a basaltic upper ‘lid’ layer. We interpret the Lake Inari terrain as evidence of extensive migmatization in deeper layers of an overthickened basaltic plateau, sustained by a mantle plume and consistent with a stagnant or sluggish lid tectonic setting. Our findings suggest that the partial melting of plateau basalts, producing buoyant TTGs, may have initiated continental evolution

How to cite: Heilimo, E., Halla, J., Joshi, K. B., and Kurhila, M.: Prolonged Archaean migmatization and TTG Genesis in the Lake Inari terrain: Insights into stagnant lid tectonics and early continental crust formation, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-5587, https://doi.org/10.5194/egusphere-egu25-5587, 2025.

11:20–11:30
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EGU25-4934
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ECS
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Virtual presentation
Samyayan Ghosal, Sukanta Dey, Jaganmoy Jodder, Manoj Kumar Sahoo, and Marlina Elburg

The end of Neoarchean (⁓2.5 Ga) is characterized by the emplacement of diverse granitoid groups, final cratonisation of different Archean blocks, and the onset of mobile lid tectonics/modern style plate tectonics associated with the cooling of the mantle. The southeastern margin of the Bastar Craton, Central India, contains well-developed exposures of granitoids of this period. We for the first time report field, petrographic, whole-rock geochemical, zircon U-Pb and Hf isotope studies on these poorly documented granitoids. These ⁓2.47–2.48 Ga granitoids are deformed, silicic, potassic, ferroan, LILE, and HFSE enriched, showing characteristics similar to A-type granites. They show a low Sr/Y ratio (<25), moderate to high Y and Yb contents, distinct negative Eu and Sr anomalies, and moderately fractionated to nearly flat HREE patterns. These granitoids yielded distinct sub-chondritic initial εHf signatures (εHft: –3.8 to –14.1). All these features indicate the formation of these granitoids due to the high-temperature reworking of older felsic crust at a shallow depth, leaving behind a plagioclase-bearing residue without significant garnet. By synthesizing craton-wide information on rock association, we suggest the operation of subduction and accretion of various arc-related terrains at ~2.5 Ga within the Bastar Craton. We further propose that the ~2.48 Ga high LILE-HFSE, ferroan potassic granitoids are formed in an extensional geodynamic setting associated with post-orogenic uplift. This marks the termination of the compressive forces of the subduction, leading to the final cratonisation.

How to cite: Ghosal, S., Dey, S., Jodder, J., Kumar Sahoo, M., and Elburg, M.: Late Neoarchean crust generation and final cratonisation of the Bastar Craton: Insights from granitoids petrology, zircon U-Pb and Lu-Hf systematics, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-4934, https://doi.org/10.5194/egusphere-egu25-4934, 2025.

11:30–11:40
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EGU25-106
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ECS
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On-site presentation
Kausik Satpathi and Pritam Nasipuri

The Singhbhum, Bastar, and Dharwar cratons in the South India Block (SIB) form a continuous mass of >2.5 Ga crystalline rocks in South India. In this contribution, we investigate whether these cratons grew together with the suggested ‘Ur’ framework or if they evolved separately. The Karimnagar granulite belt on the NE edge of the Eastern Dharwar Craton (EDC) contain enclaves of mafic granulites and high-Al metapelites within variably deformed charnockites and blastoporphyritic granitoids. The foliated charnockites exhibit magmatic flow texture, euhedral-subhedral pyroxene phenocrysts, and chess-board twinning in the quartz grains. Feldspar and pyroxene phenocryst laths share high-energy boundaries with quartz and each other. The Al-in-Opx thermometry indicates charnockites emplaced at a temperature > 900 °C. Also, the charnockites' whole rock chemistry supports an arc origin. The charnockites' oscillatory-zoned magmatic cores survive the recrystallization of zircon grains. The U-Pb Concordia plot shows a concordant age of 2680±15 Ma and 2504±12 Ma, from magmatic zircon cores. Recrystallized zircon grains exhibit an upper intercept age between 2510±4 Ma and 2509±3 Ma, overlapping with the U-Th-Pb ages in monazites (2502 -2508 Ma). The 207Pb/206Pb age versus εHf(t) plot of zircons indicates that ~2.5 Ga magmatic charnockites originated from <3.0 Ga crustal sources. In contrast, the charnockites from the Bastar craton, exhibit U-Pb ages at 2500 Ma and 1600 Ma. The orientation of structural data, thermometry, and geochronology of the charnockites, when combined together with the existing literature, i.e., lack of 1600 Ma ages from Karimnagar Charnockites, indicate late Neoarchean magmatic charnockites at the EDC margin were formed during a 2.7–2.5 Ga amalgamation between the separately evolved crustal blocks within the Dharwar Craton, probably as a part of Kenorland assembly. Our result is contrary to the concept that the Neoarchean Karimnagar Charnockites were part of a coherently evolved landmasses involving Dharwar and part of Bastar Craton, known as DHABSI, within the Ur supercontinent, that assembled during the Paleo/Mesoarchean evolutionary history of the Earth.

How to cite: Satpathi, K. and Nasipuri, P.: Archean Charnockites and their supercontinent connection: A case study from the Neoarchean Granulite Eastern Dharwar Craton in South India, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-106, https://doi.org/10.5194/egusphere-egu25-106, 2025.

11:40–11:50
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EGU25-5392
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On-site presentation
Timothy M. Kusky, Abdelmottaleb Aldoud, Lu Wang, and Jiannan Meng

The Paleo-Neoarchean Pilbara craton of western Australia is one of the best-exposed, most studied early Archean cratons on Earth, yet ideas about its origin are split between plate tectonic and non-plate tectonic models (Kusky et al., 2021). Some suggest that the domes-and-basins of the eastern Pilbara represent non-plate tectonic drips where thickened dense volcanic outpourings sagducted into a warm pre-existing sial. Other models propose an accretionary orogen model where oceanic affinity units were off-scraped in a subduction setting, and progressively intruded and re-deformed by arc-related plutons, forming the domes-and-basins. Based on our field, drone- and satellite-assisted structural mapping and analysis, along with processing of geophysical data, we suggest the latter model is more consistent with the geologic and geophysical data.  Here, we report results from our mapping and data synthesis of the craton-cutting Mulgandinnah shear zone.

Arc-slicing transform faults represent an integral component of convergent margin tectonics. They are developed above oblique subduction systems, cutting through and displacing the entire magmatic section of arcs, leading to tectonic repetition of segments of the overriding plate in the ensuing orogenic collage. Extant examples clearly show this process in Sumatra, New Zealand, and the Philippines, while ancient examples are reported from the Paleozoic Altaids, and Neoarchean Superior and Yilgarn cratons. Here, we report data that documents that the Paleo-Mesoarchean Eastern Pilbara craton, recently interpreted to be a preserved mid-upper crustal level of a magmatic arc, is cut and repeated by a major 3.0-2.93 Ga arc-slicing fault, the sinistral Mulgandinnah shear zone (Aldoud et al., 2024), which sliced a previously 600 x 100 km segment of a Mesoarchean arc system, laterally moving different segments to their presently juxtaposed 200 x 200 km preserved fragment. We document the offsets using offset strata and plutons (i.e. domes), both from surface mapping and high-resolution Reduced to Pole (RTP) magnetic datasets for buried plutons. We document the sense of shear using classical kinematic indicators, and also show that that shearing occurred during partial melting at ~3.0 Ga. Geophysical data (reflection profiles) reveal that the domes-and-basins are confined to the upper crust, with a flat reflector (detachment shear zone?), into which listric thrust fault merge, at 10 sec (~30 km) depth, and no trace of any drips sinking deeper. This evidence demonstrates lateral plate motions by 3.0 Ga, and shows oblique subduction, arc plutonism, arc-slicing and repetition, reflecting that crustal growth in some style of convergent margins was in operation by the Mesoarchean. To our knowledge, this is currently the oldest well-documented arc-slicing fault system on Earth, although this by no means that others may not have operated previously, and have been eroded, or remain to be documented.

 

Aldoud, A., Kusky, T.M.*, Wang, Lu, 2024, Is the Mulgandinnah shear zone, Pilbara craton, the world’s oldest arc-slicing transform fault? Geology 52, 801-806. https://doi.org/10.1130/G52360.1

Kusky, T.M.*, Windley, B.F., Polat, A., Wang, L., Ning, W.B., and Zhong, Y.T., 2021, Archean dome-and-basin style structures form during growth and death of intraoceanic and continental margin arcs in accretionary orogens, Earth-Science Reviews 220, 103725.  https://doi.org/10.1016/j.earscirev.2021.103725

How to cite: M. Kusky, T., Aldoud, A., Wang, L., and Meng, J.: The Mesoarchean Mulgandinnah shear zone, Pilbara Craton: the world’s oldest arc-slicing transform fault, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-5392, https://doi.org/10.5194/egusphere-egu25-5392, 2025.

11:50–12:00
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EGU25-4915
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On-site presentation
Lu Wang, Ruizhi Wang, Wenbin Ning, and Timothy M. Kusky

Archean dome-and-basin structures are widely interpreted to have formed in a stagnant-lid drip-tectonic or sagduction setting, unlike modern Earth. In the North China Craton, apparent dome-and-basin structures in eastern gneiss terrains are bordered by a contemporaneous 1800 km-long orogenic belt, exhibiting many classical hallmark indicators of plate boundary interactions found in Phanerozoic orogens, suggesting contrarily that plate tectonics was operating during formation of the domes. We solve this dilemma by showing that the domes-and-basins formed by a combination of fold interference, temporally constrained by felsic intrusion events, and folding of domal arc-related plutons. Strong deformation is related to overthrusting of nappes from the adjacent orogen, forming klippen, infolded with the gneisses, explaining the perplexing juxtaposition of plate tectonic and seemingly non-plate tectonic terrains so closely in space and time.

How to cite: Wang, L., Wang, R., Ning, W., and Kusky, T. M.: North China Archean dome-and-basin structures; arc plutons, superimposed folds, or sagduction?, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-4915, https://doi.org/10.5194/egusphere-egu25-4915, 2025.

12:00–12:30
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EGU25-13998
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ECS
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solicited
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Highlight
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GMPV Division Outstanding ECS Award Lecture
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On-site presentation
Renée Tamblyn and Jörg Hermann

The geological water cycle (or the deep water cycle) consists of water-rock interactions between the hydrosphere/atmosphere and lithosphere. This water plays a critical role in geological processes, for example, promoting melting and the formation of new continental crust, the mobilisation of economic metals, rock reactivity and rheology, and seismic activity. In the modern day, the most dominant form of the geological water cycle is the uptake of water in mantle-derived rocks in the oceans, and release of this water during subduction to melt overlying lithologies and form volcanic arcs. In the Archean, however, the geological water cycle is less well understood. This is particularly because (i) there are rare ophiolites from this timeframe, and lithologies responsible for water uptake and release may have been different and (ii) because the mode of tectonics is argued, meaning that the geodynamics and therefore conditions of water release are not well understood.

This presentation will focus on the processes of hydration and dehydration of ultramafic to mafic rocks from Archean greenstone belts (komatiites and komatiitic basalts). Geochemical evidence suggests that these rocks were initially hydrated on an Archean oceanic plateau after their eruption. During this process, they sequestered mobile elements such as boron from the seawater, and produced molecular H2 by the oxidation of Fe, a possible source of energy for early chemosynthetic life. Most greenstone belts have been metamorphosed to greenschist-amphibolite facies, indicating that they experienced some form of burial during Earths earlier history. Phase equilibria modelling shows that if komatiites are buried to higher temperature conditions (>750 °C), the breakdown of hydrous phases could release significant quantities of water into the surrounding rocks, promoting fluid-fluxed melting of surrounding lithologies. In the case of the Barberton Greenstone Belt, which contains ~8 % komatiite and ~20% basalt by volume, fluid release from the komatiite into the basaltic lithology would promote wet melting of basalts to form tonalite-trondhjemite-granodiorite (TTG) series rocks, important constituents of Archean continental crust.  While not abundant in the geological record, the role of ultramafic rocks in the Archean geological water cycle is evident, as is their importance in ocean floor processes and the formation of the Earth’s first TTG crust.

How to cite: Tamblyn, R. and Hermann, J.: The Archean geological water cycle , EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-13998, https://doi.org/10.5194/egusphere-egu25-13998, 2025.

Posters on site: Tue, 29 Apr, 10:45–12:30 | Hall X2

Display time: Tue, 29 Apr, 08:30–12:30
Chairpersons: Dominik Sorger, Silvia Volante, Thomas Mueller
X2.11
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EGU25-12964
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Rituparna Nayak, Biswabhushana Das, Pinak Nayak, Anamitra Dasgupta, Dilip Mukhopadhyay, Somnath Dasgupta, and Santanu Kumar Bhowmik

The Mesoarchaean Coorg granulite block-Mercara Shear Zone (MRSZ) - Meso- to Neoarchaean Western Dharwar Craton (WDC) crustal section is ideally suited to study the Early Earth tectonics, and in particular, to establish collisional tectonics that led to their amalgamation. However, despite numerous petrological and geochronological studies, the nature of tectonic relationships among the three litho-tectonic domains is not well understood. Importantly enough, there is a dearth of metamorphic studies from the western part of the WDC, and in its absence, the amalgamation tectonics between the WDC and the Coorg block is poorly constrained. The south-western part of the Western Dharwar Craton (WDC), in contact with the Mesoarchaean Coorg Granulite Massif, consists of NNW-SSE trending mafic to ultramafic dyke swarm that is variably metamorphosed. Based on field observations and petrographic study, we have classified the metamafic dykes into two broad types: (a) Undeformed to foliated metagabbro, locally with coarse coronal Grt around Cpx, Pl, Ilm, and Hbl1 (mineral abbreviations after Kretz, 1983) and differentially preserved igneous textures (Type-1) and (b) well-foliated and banded metamafites that lack magmatic textures and mineralogy, locally migmatitic with porphyroblastic Grt and Cpx and in others, garnetiferous amphibolite with porphyroblastic garnet (Type-2). Based on the degree of foliation development in these metamafites, we observe a south-westward increase in strain. Type-1 metamafites record a sequence of textural evolution, namely recrystallization of the magmatic Cpx±Opx+Pl assemblage→partial high-T hydration, producing Ti-Hbl (Ti=0.24-0.28)→growth of coarse coronal Grt [with a broad homogeneous magnesian core (XMg=0.25-0.23, XGrs=0.20-0.22) and slightly ferroan rim (XMg=0.21-0.22, XGrs=0.21-0.22), particularly in contact with Cpx] on the recrystallized matrix→a late Hbl-defined foliation (Ti=0.19-0.23). Type-2 metamafites show the development of a pervasive titaniferous Hbl-defined foliation (Ti=0.14-0.19), followed by the growth of compositionally homogeneous porphyroblastic Grt (XMg=0.21-0.22; Prp14-15Grs22-27) with or without Cpx (XMg=0.65-0.70, Altotal=0.03-0.08, and Natotal=0.01-0.03), and including localised crustal anataxis, producing tonalitic melt at the metamorphic peak. This was followed by the formation of late low Ti-Hbl (Ti=0.04-0.05). Using conventional thermobarometry, the peak P-T of type-1 metamafite has been estimated at ~ 8kb and 800°C.  In the type-2 metamafites, the peak and retrograde P-T is estimated at ~9kb and 800°C and ~7kb and 500°C respectively.  The effective bulk rock composition has been used to calculate the phase equilibria modelling of the type-2 metamafite, in which the intersections of compositional isopleths of XMg(Grt), XGrs(Grt), XAn(Pl), Al(Cpx), Ti(Hbl) defines a peak P-T of 9.4 kb and 800°C which is similar to that calculated by conventional thermobarometry. The peak and retrograde P-T conditions together record the retrograde segment of a clockwise P-T path of evolution. We relate the textural sequence, results of thermobarometric computations and phase equilibria modelling, and strain patterns in the metamafic dykes to suggest a pervasive thermo-tectonic event that led to the prograde burial of the extended cratonised WDC beneath the Coorg Granulite Block to high-pressure upper amphibolite to granulite facies metamorphic conditions. We link this event with continental collisions between the WDC and Coorg Block at the dawn of the Proterozoic.

How to cite: Nayak, R., Das, B., Nayak, P., Dasgupta, A., Mukhopadhyay, D., Dasgupta, S., and Bhowmik, S. K.: Metamorphic evolution and thermo-tectonic history of Metamafic Dykes: Insights into Continental Collision between Coorg Block and Western Dharwar Craton, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-12964, https://doi.org/10.5194/egusphere-egu25-12964, 2025.

X2.12
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EGU25-5404
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ECS
Zhenzhu Wu

The inner and outer layers of the Earth can be connected by plate tectonics with exchange of material and energy, thus shaping the habitable Earth today. However, the existence of Archean plate tectonics has been controversial. One of the reasons is the lack of rock records that can best represent the presence of the convergent plate boundaries during that time, such as continental lithosphere with ultrahigh-pressure metamorphism (> 2.7 GPa or 80–100 km). Here we investigated the peridotites from the North China Craton, and conducted a systematic investigation involving field survey, mineralogy, petrology, geochronology and geochemistry on these peridotites. Temperature and pressure conditions for protoliths of these peridotites, as well as oxygen fugacity (fO2), were also calculated, to constrain petrogenesis, tectonic setting, and characteristics of mantle fO2.

In situ U-Pb dating on zircons from the peridotites yields metamorphic/altered age of 2535–2517 Ma and were intruded by the unmetamorphosed granite dykes at ~2500 Ma. Garnet pseudomorphs and pyroxene with exsolved textures were identified in these peridotites, suggesting that the original garnet and pyroxene were brought from high pressures and the breakdown was induced by decompression. Reintegrating the compositions of the original garnet and pyroxene and compositions of the original garnet and pyroxene indicate that these peridotites were brought up or once seated at mantle depths of 110–130 km. The calculated dT/dP thermal gradients is around 375 oC/GPa, close to those of modern collisional orogens.   The occurrence of phlogopite and amphibole in the studied peridotites and the enrichment of light rare earth elements in their bulk-rock and mineral trace elements, as well as the higher contents of magnesium and aluminum in the rim, and chromium and iron in the core of spinels in some samples, which further demonstrates that the studied peridotites experienced mantle metasomatism during plate subduction. Using Olivine-orthopyroxene-spinel oxybarometry, this dissertation obtained the fO2 of these Archean metasomatized peridotites to range from ΔFMQ +1.0 to ΔFMQ +1.7, which are more oxidized than the Archean ambient mantle, but are similar to the modern sub-arc mantle.

The ultrahigh-pressure peridotites prove that some forms of plate tectonics have been operating at least since the Neoarchean, and also indicate that the continental deep subduction could have existed at least prior to 2.5 billion years ago. During this process, the Neoarchean mantle oxidation was increased, in which subducted crustal materials would have significantly metasomatized the mantle and increased its oxygen fugacity. This process may have contributed to the Archean atmospheric redox evolution and triggered the GOE in the early Proterozoic.

How to cite: Wu, Z.: Neoarchean Peridotites in the North China Craton and Implications for the oneset of Plate Tectonics, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-5404, https://doi.org/10.5194/egusphere-egu25-5404, 2025.

X2.13
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EGU25-6099
Massimo Tiepolo, Valentina Previti, Enrico Cannaò, Marco Filippi, Riccardo Tribuzio, Davide Mariani, and Gianluca Sessa

The Archean mantle is an invaluable source of information about the geodynamic processes active during the early Earth. However, our knowledge on Archean mantle compositions is still fragmentary due to its poor exposure on the present-day Earth. The Eoarchean Narssaq ultramafic complex within the Itsaq Gneiss Complex of southern West Greenland is one of the most extensively studied Eoarchean ultramafic sections. According to van de Locht et al. (2020), the ultramafic complex represents a remnant of the Archean mantle. Conversely, Zhang and Zilas (2024) proposed a cumulate origin for the same lithologies. Such contrasting interpretations have significant implications for the inferred geodynamic scenario active during the Eoarchean.

We carried out a new field survey on the Narssaq ultramafic complex collecting representative samples of dunites and hornblende peridotites. All samples include olivine, amphibole and phlogopite, as major rock-forming minerals. Accessory orthopyroxene, chromite and magnetite were in places also found. Mineral phases were characterized for major and trace elements concentration by electron microprobe and laser ablation ICP-MS, respectively. On selected amphiboles, images on trace element distribution were also carried out by LA-ICP-TOF-MS.

Preliminary data reveal that olivine is Fo90-91 and is characterised by exceptionally low contents of incompatible trace elements and high contents of Ni (>3500 ppm) and fluid mobile elements, such as B and Li (up to 4 and 6 ppm, respectively). Amphibole is mostly tremolitic in composition, although, amphibole grains in equilibrium with olivine and phlogopite locally preserve core ghost domains consisting of Mg-hornblende. These domains are characterized by extremely high Cr contents (>8500 ppm), nearly flat chondrite-normalized REE pattern at about 10 times CI chondrite with a marked negative Eu anomaly, and relatively high contents of both crustal (e.g., Pb, Th, U) and fluid mobile elements (e.g., Li, Be and B). Phlogopite is exceptionally Cr- and Ni-rich and displays low contents in incompatible trace elements, including those for which the affinity is higher, such as Cs, Rb and Ba; Li and B are up to 6 ppm.

The typically null concentrations of fluid immobile incompatible trace elements in olivine and the constantly high and similar contents of fluid mobile elements in all mineral phases indicates that the entire ultramafic system underwent re-equilibration and re-crystallisation during the metamorphic evolution of the Narssaq ultramafic complex. The mantle or cumulate origin of the complex is thus difficult to be assessed. Notwithstanding, we propose that amphibole crystallisation was related to a melt with a significant crustal component that interacted with the pre-existing ultramafic system. Further trace element and stable isotope micro-analyses are in progress, to verify if amphibole crystallisation was related to the emplacement or partial melting of the host Itsaq gneisses.

van De Locht J., Hoffmann J.E., Rosing M.T., Sprung P., Munker C. Preservation of Eoarchean mantle processes in 3.8 Ga peridotite enclaves in the Itsaq Gneiss Complex, southern West Greenland. Geochimica et Cosmochimica Acta 280 (2020) 1–25.

Zhang L. & Zilas K. Eoarchean ultramafic rocks represent crustal cumulates: A case study of the Narssaq ultramafic body, southern West Greenland. Earth Planet. Sci. Lett. 625 (2024) 118508

 

How to cite: Tiepolo, M., Previti, V., Cannaò, E., Filippi, M., Tribuzio, R., Mariani, D., and Sessa, G.: New insights into the origin of the Eoarchean Narssaq ultramafic complex (southern West Greenland) from trace element mineral chemistry, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-6099, https://doi.org/10.5194/egusphere-egu25-6099, 2025.

X2.15
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EGU25-11470
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ECS
Avishai Abbo, Horst Marschall, and Axel Gerdes

One of the major and most impactful changes the Earth has experienced is the formation, evolution and volumetric accumulation of continental crust through geologic time. The transition of continental crust from being mostly submerged to subaerial greatly affected the evolution of complex life by inducing the enrichment of oceans with nutrients via erosion. The transition from stagnant/squishy-lid dynamics to modern-style plate tectonics was probably facilitated by the growth and accumulation of thick continental crust. Many ideas of crustal growth curves were previously suggested, each employing different types of constraints. Many of these curves point to the Archean–Proterozoic transition as an important point of infliction in the evolution and accumulation of continental crust. We adopted a new approach aiming to indirectly trace the growth in subaerial exposure of continental crust by observing the change in elemental and isotopic composition of boron in the ocean, preserved in Archean–Proterozoic marine deposits. Boron is a continental element that is concentrated in the continental crust over time. The oceanic boron isotopic composition is controlled by the balance between the different sources and sinks of boron in and out of the ocean, amongst which the largest source is continental runoff. The onset of widespread continental emergence initiated the largest boron influx into the ocean, thus greatly affecting the oceanic B concentration and B isotopic budget. Box modelling of oceanic B concentration over time employing different crustal growth scenarios also shows that the mode of crustal growth greatly affects the time dependant change in oceanic B concentration. We analyzed samples of Archean and Proterozoic cherts, iron formations and marine shales for B isotopes using in-situ LA-MC-ICP-MS in order to construct the oceanic B isotopic record across this critical period. We observe a significant increase both in B concentration and in the range and variation of B isotopic values across the Archean–Paleoproterozoic transition that may suggest a transition of oceanic boron towards modern values (modern ocean δ11B = +39.6 ‰) at that time, suggesting a large increase in the area of exposed continental crust.

How to cite: Abbo, A., Marschall, H., and Gerdes, A.: Boron isotopes in Archean-Proterozoic marine deposits as a tracer of continental evolution and emergence, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-11470, https://doi.org/10.5194/egusphere-egu25-11470, 2025.

X2.16
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EGU25-709
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ECS
Valentina Previti, Massimo Tiepolo, Antonio Langone, Enrico Cannaò, Gianluca Sessa, and Massimo D'Antonio

The Finero Complex in the northern Ivrea-Verbano Zone represents one of the most enigmatic cross-sections through the mantle and lower continental crust. The mantle peridotite unit (Phlogopite Peridotite, PP) consists of pervasively metasomatized spinel-harzburgite enriched with abundant phlogopite and amphibole, locally exhibiting Cr-diopside veins (Zanetti et al., 1999). This unit is in contact with a mafic complex of lower crustal origin and Permian age (Lu et al., 1997), composed of three distinct units (Siena and Coltorti, 1989): i) the Layered Internal Zone (LIZ), which includes lherzolites, garnet-hornblendites, pyroxenites, anorthosites, and garnet-gabbros; ii) the Amphibole Peridotite (AP); iii) the External Gabbro (EG), which borders the Kinzigite Formation. The genetic relationships among these units remain a subject of debate.

We carried out in-situ Sr-isotope analyses of clinopyroxene, amphibole, and plagioclase across all lithologies of the Finero Complex to identify isotopic disequilibria that might indicate multiple, genetically distinct igneous events. In-situ Sr-isotope measurements were performed using LA-MC-ICP-MS at the Geochemistry Laboratory (GL@M) of the University of Milan.

In the PP samples, clinopyroxene and amphibole are in isotopic equilibrium but 87Sr/86Sr is highly variable, ranging from around 0.7040 to 0.7080. In the LIZ lithologies, amphibole shows a narrow variation in 87Sr/86Sr (0.7020 - 0.7030) and it is in isotopic equilibrium with clinopyroxene. An exception is observed in the anorthosite, where clinopyroxene exhibits a significantly more radiogenic signature (87Sr/86Sr > 0.7040). Plagioclase in all LIZ lithologies is more radiogenic than amphibole, with 87Sr/86Sr values ranging from around 0.7030 to 0.7040. In the AP, clinopyroxene and amphibole are isotopically equilibrated, with values close to 0.7035 ± 0.0001 (2SD). In the EG, plagioclase displays a significantly less radiogenic 87Sr/86Sr values (around 0.7030) compared to amphibole and clinopyroxene (>0.7070), showing isotopic disequilibrium.

Amphibole and clinopyroxene from the PP show variable crustal signatures supporting differences in the metasomatic agents (Zanetti et al. 1999). In both the AP and LIZ, plagioclase consistently shows more radiogenic values than amphibole, which is in isotopic equilibrium with clinopyroxene, except in the anorthosites. The highly unradiogenic 87Sr/86Sr signature of plagioclase in EG, close to that found in LIZ, reveals that plagioclases are remnants of a former reacted lithology. These observed isotopic disequilibria suggest that present-day Finero Complex is the result of infiltration and reaction of melts with different 87Sr/86Sr signatures into a pre-existing igneous complex. The less reacted lithologies, preserving similar 87Sr/86Sr signatures are lherzolites, pyroxenites and wehrlites. This peculiar rock association, the layered structure and the extremely depleted initial 87Sr/86Sr signature (down to 0.7020) closely resemble that of some Proterozoic, or even older, layered mafic-ultramafic complexes.

 

Lu, M. Hoffman H.W., Mazzucchelli M., Rivalenti G. 1997. The mafic-ultramafic complex near Finero (Ivrea-Verbano Zone). Chem. Geo. 140, 207-222. 

Siena, F., and M. Coltorti. 1989. The petrogenesis of a hydrated mafic-ultramafic complex and the role of amphibole fractionation at Finero (Italian Western Alps)." Neues Jahrbuch für Mineralogie Monatshefte 6, 255-274.

Zanetti, A., Mazzucchelli, M., Rivalenti, G., & Vannucci, R. 1999. The Finero phlogopite-peridotite massif: an example of subduction-related metasomatism. Contributions to Mineralogy and Petrology, 134(2), 107-122.

How to cite: Previti, V., Tiepolo, M., Langone, A., Cannaò, E., Sessa, G., and D'Antonio, M.: Is the Finero Complex (Ivrea Verbano Zone) originally Proterozoic or even older? Inferences from in-situ Sr isotope disequilibria, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-709, https://doi.org/10.5194/egusphere-egu25-709, 2025.

X2.17
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EGU25-14730
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ECS
Dayanna Vera-Cedeño and Berengere Mougel

Short-lived system chronometers provide evidence for the rapid and early differentiation of planet Earth. In particular, the hafnium182Hf – tungsten 182W system (t1/2 = 8.9 Ma) has been used to constrain the age of core formation and silicate differentiation taking advantage of the geochemical differences between these two elements during geological processes. For example, during core formation, W, which is a siderophile element, was attracted into the Earth’s core, while Hf, being a lithophile element, was concentrated into the silicate portion of the Earth. This contrasting difference in the behavior of these elements resulted in distinct 182Hf/182W isotopic ratios in both reservoirs, which are now reflected in the 182W/184W isotopic compositions of the samples derived from these reservoirs. The purpose of this work is to try to develop a new method for obtaining W isotope data for silicate rocks. The current bulk-rock analysis requires the use and preparation of large amounts of rock powder due to the very low W concentrations in most samples. Here, we propose a new methodology that may generate less costs and optimize the current method by replacing bulk-rock isotopic analysis with that of mineralogical fraction. In this study, we determined W concentrations (and other trace elements) of individual mineral phases from different types of rock by LA-ICP-MS. Our preliminary results reveal that titanium (Ti) - rich minerals, such as rutile and ilmenite, have systematically more elevated W concentrations than the other minerals. Rutile, in particular, captures most of the W in the rock. Replacing bulk rock isotopic analyses with analyses of Ti-rich minerals would require significantly less material to process. It is expected to obtain and compare results of W isotopic compositions of both the bulk rock and the Ti-rich mineral fraction.

How to cite: Vera-Cedeño, D. and Mougel, B.: Geochemical and isotope composition of tungsten (u182W): comparative analysis between bulk rock and mineral phases in silicated rocks, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-14730, https://doi.org/10.5194/egusphere-egu25-14730, 2025.

X2.18
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EGU25-19709
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ECS
Ariuntsetseg Ganbat, A. Alexander G. Webb, Thomas Müller, Jiawei Zuo, and Eunice Chit Yan Leung

Understanding lithospheric thickness during the Early Earth is crucial for unraveling tectonic modes (e.g., heat-pipe vs. stagnant-lid) and cooling mechanisms. The heat-pipe model likely produced a thick lithosphere early on, which thinned with declining volcanism before thickening again as stagnant-lid conduction became dominant. Conversely, the stagnant-lid mode involved a direct transition from a magma ocean to conduction, characterized by thin, weak lithospheres that gradually strengthened and thickened over time. Tracking the evolution of lithospheric thermal thickness provides a means to test these cooling mechanisms.

Basaltic rocks, the most abundant igneous rocks, offer critical insights into mantle conditions. Experimental evidence indicates that the oxides in primary basaltic melts are sensitive to melting pressure, making them effective proxies for lithospheric thickness. Using global geochemical datasets, such as GEOROC, we can infer lithospheric thickness from basaltic lithogeochemistry. This study evaluates lithospheric thickness during the Early Earth (4.0–3.0 Ga) using compiled basaltic lithogeochemical data. Despite their rarity, heat flow data, xenolith samples, and clinopyroxene thermobarometry were also used to validate findings. Basaltic lithogeochemistry indicates significant thinning from 120 km at ~3.65 Ga to 90 km by ~3.30 Ga, followed by subsequent thickening and eventual stabilization. Heat flow data, though craton-specific and with high age uncertainty, generally support a thinning trend from ~3.75 Ga to ~3.40 Ga, stabilizing and slightly thickening by ~3.20 Ga, with minimal fluctuations until ~3 Ga. Xenolith and clinopyroxene data, available only from ~3.60 Ga onward, indicate a stable lithospheric thickness between ~3.60 Ga and ~3.40 Ga, followed by thickening from ~3.40 Ga to ~3.20 Ga. These observations suggest an evolution from thick, cold lithospheres that initially thinned, likely transitioning to conductive cooling and thickening over time. This supports the probable viability of the heat-pipe model during the Early Earth and provides insights into the planet’s tectonic regimes and lithospheric evolution.

How to cite: Ganbat, A., Webb, A. A. G., Müller, T., Zuo, J., and Leung, E. C. Y.: Evolution of lithospheric thickness in Early Earth: Insights into tectonic regimes, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-19709, https://doi.org/10.5194/egusphere-egu25-19709, 2025.

X2.19
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EGU25-20570
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ECS
Chao Wang, Zhenzhu Wu, Mark B. Allen, Ming Tang, Yi Chen, Lihui Jia, and Shuguang Song

The Archean mantle redox state played an important role in degassing of the Earth's interior and thus influenced atmospheric oxygen levels of the early Earth. But it is unclear if any parts of the uppermost mantle were significantly oxidized by a certain point in the Archean. Here, we investigate oxygen fugacity (fO2) of Archean (> 2535–2517 Ma) peridotites in the North China Craton. Petrology and geochemistry reveal that they experienced strong Neoarchean subduction-related metasomatism. These Neoarchean subduction-metasomatized peridotites record fO2 of ΔFMQ +1.3 ± 0.4 (SD) [relative to the fayalite-magnetite-quartz (FMQ) buffer], which are more oxidized than the Archean ambient mantle, but similar to the modern sub-arc mantle. We propose that this Neoarchean rise of mantle oxidation in the North China Craton was induced by plate subduction, during which the Neoarchean sub-arc mantle in the North China Craton could have been metasomatized and oxidized, and its oxygen fugacity was increased. This process may have had connections with the Great Oxidation Event in the Early Proterozoic.

How to cite: Wang, C., Wu, Z., Allen, M. B., Tang, M., Chen, Y., Jia, L., and Song, S.: Rise of mantle oxidation by Neoarchean subduction in the North China Craton, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-20570, https://doi.org/10.5194/egusphere-egu25-20570, 2025.

X2.20
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EGU25-5303
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ECS
Wenbin Ning, Timothy Kusky, and Lu Wang

Ophiolitic mélange is a key geological component in ancient convergent plate margins. Understanding the block and matrix types, their igneous, sedimentary, and metamorphic P-T histories, and the structural and tectonic processes from formation to emplacement, is essential for deciphering paleo-subduction zone dynamics. Subduction channels, where some ophiolitic mélanges develop, are mechanically weak shear zones between the upper and lower plates, containing stacked oceanic sequences offscraped from the subducted plate, mixed with eroded crust and mantle materials from the forearc in arc-continent accretionary/collision zones. In this study, we present the results of detailed field mapping, structural analysis, geochemical, and geochronological investigations of the Neoarchean Zunhua and Shangying ophiolitic mélanges from the Eastern Hebei Complex in the Central Orogenic Belt, North China Craton. The Zunhua ophiolitic mélange consists of forearc-affinity ultramafic-mafic blocks (peridotite, podiform-chromite-bearing dunite, pyroxenite, metagabbro, metadiabase, metabasalt), with podiform chromitites containing inclusions of UHP TiO2(II) and remnants of UHP chenminigite, suggesting derivation from depths of 270–410 km prior to mélange formation. In contrast, the Shangying ophiolitic mélange to the east contains layered and isotropic N-MORB affinity metagabbro and garnet clinopyroxenite, metamorphosed under HP eclogite-facies conditions at 65–70 km. Both mélanges are characterized by a strongly sheared metasedimentary matrix. Zircon U-Pb dating of blocks and crosscutting dikes indicates that the ultramafic-mafic blocks in the Zunhua ophiolitic mélange formed at 2.55–2.52 Ga and were incorporated into the mélange between 2.52 and 2.50 Ga. The Shangying ophiolitic mélange formed between 2.53 and 2.52 Ga and was emplaced in the Eastern Block between 2.52 and 2.47 Ga. The Zunhua mélange preserves a nearly complete ophiolite sequence and records a Neoarchean subduction initiation and arc-continent collision event in a forearc supra-subduction zone (SSZ) setting. The Shangying mélange, composed of meta-basalts, gabbros, and garnet clinopyroxenites, formed at a mid-ocean ridge (MOR). The Zunhua SSZ ophiolitic mélange was emplaced over the forearc by accretionary thrusts, whereas the Shangying MOR ophiolitic mélange formed through subduction, mixing, and exhumation within a subduction channel. The juxtaposition of these two mélange belts with different tectonic affinities and emplacement styles during the Neoarchean arc-continent collision reveals a west-northwest-dipping subduction polarity, consistent with kinematic fabrics in the mélanges and their correlatives along the ~1,800 km paleo-subduction zone of the Central Orogenic Belt. The co-existence of SSZ and MOR ophiolitic mélanges in the Eastern Hebei Complex suggests that large-scale subduction/accretionary zones were active in the late Neoarchean. Geochronological data show that the processes of seafloor spreading, subduction initiation, forearc thrusting, and exhumation of subduction materials occurred over <80 million years, similar in duration to many Phanerozoic subduction-collision zones. These findings suggest that tectonic processes in the late Neoarchean were comparable to those of modern Earth.

How to cite: Ning, W., Kusky, T., and Wang, L.: The coexistence of Neoarchean SSZ and MOR ophiolitic mélanges in the North China Craton: dynamics of an Archean paleo-subduction zone, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-5303, https://doi.org/10.5194/egusphere-egu25-5303, 2025.

X2.21
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EGU25-7212
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ECS
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Juan David Solano Acosta, Alvar Soesoo, Rutt Hints, and Sophie Graul

This research explores the geochemistry of Paleoproterozoic metasedimentary and metavolcanic units in the Alutaguse region of North Estonia and the South Svecofennian (SS) zones, including Ladoga, Saimaa, Häme Belt, and Uusimaa Belt, to better understand the tectonic evolution of the Svecofennian Orogeny in Eastern Fennoscandia. Metasedimentary units consist of micaceous gneisses (± Grt ± Crd ± Sil), while metavolcanics include amphibolites and pyroxenic gneisses. Historical and new data show that High-SiO₂ (>63 wt%) metasediments have felsic origins similar to the Upper Continental Crust (UCC), whereas Low-SiO₂ (≤63 wt%) metasediments, resembling graywackes and shales, indicate mafic to intermediate origins similar to post-Archean Australian Shale (PAAS). Various weathering indices, including CIA, PIA, CIW, and ICV for metasediments, and AI, CCPI, WIP, and SI for metavolcanics, were applied to reveal these geochemical trends. The metavolcanics are classified as sub-alkaline, with geochemical signatures pointing to asthenospheric mantle origins for Alutaguse and subducted oceanic crust origins for SS. Tectonic affinity analyses indicate a predominant oceanic arc setting across both regions. High CaO and MnO concentrations in Alutaguse and Uusimaa metasediments suggest a genetic link, positioning Alutaguse as a 1.90–1.89 Ga back-arc to the Uusimaa belt, followed by the accretion of Uusimaa and Häme belts around 1.87 Ga, marking the closure of the Svecofennian ocean. The Alutaguse zone likely developed as a back-arc to the Tallinn-Uusimaa belt after the accretion of the Bergslagen microcontinent. This interpretation is supported by geophysical anomalies correlated with Zn-Pb-Fe mineralisation. The assemblages found in Alutaguse province comprises high proportions of highly deformed sulphides (pyrite, pyrrhotite, arsenopyrite) and sphalerite disseminated in graphitic amphibolitic-gneisses, which shows similarities with Bergslagen's VMS (SEDEX?) provinces and warrants further investigation.

 

Figure 1. Crustal structure in the central and southern parts of the Svecofennian orogen as integrated across the Baltic Sea, after Bogdanova et al. (2015) and Geochemical relations from the Alutaguse and SS metasedimentary units include major elemental tectonic discriminant functions.

 

How to cite: Solano Acosta, J. D., Soesoo, A., Hints, R., and Graul, S.: Is the Estonian Alutaguse Section of Eastern Fennoscandia a continuation of the Southern Svecofennian Finnish Terranes, or is it akin to the Swedish Bergslagen region?, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-7212, https://doi.org/10.5194/egusphere-egu25-7212, 2025.

Posters virtual: Tue, 29 Apr, 14:00–15:45 | vPoster spot 1

Display time: Tue, 29 Apr, 08:30–18:00
Chairpersons: Jeroen van Hunen, Silvio Ferrero, Dominik Sorger

EGU25-941 | ECS | Posters virtual | VPS22

Structure, metamorphism and geochronology of Archean Sargur Schist Belt, southern India 

Madhusmita Swain and Sukumari Rekha
Tue, 29 Apr, 14:00–15:45 (CEST)   vPoster spot 1 | vP1.23

The Sargur Schist Belt (SSB), the oldest supracrustal greenstone belt, present in the south-eastern part of the Western Dharwar Craton (WDC), is a ~ 320 km long N-S to NNE-SSW trending discontinuous belts that occurs as patches and pockets within the granitic‒gneissic complex. The SSB is mainly composed of metamafic, metaultramafic, metapelite, banded magnetite quartzite, micaceous quartzite, pyroxene granulite, amphibolite, hornblende-biotite schist/gneiss, etc. The schistose belt has undergone at least five deformations in which the last three are very prominent. The N-S trending high strain zones with S4 mylonitic foliation were produced during the EDC-WDC accretion (D4 deformation). The D5 deformation (developed due to the accretion of the WDC to Southern Granulite Terrane (SGT) along the Moyar/Bavali Shear Zone (BSZ)) developed broad open folds/warps in the N-S trend of the SSB (as well as WDC) with E-W trending axial planes. On a regional scale, the D3 fold axes curve into the WNW-striking BSZ (D5 deformation), a steeply dipping transpressional shear zone with dextral kinematics.

The estimated metamorphic P-T conditions of 440-585 °C and 6.0-9.5 kbar in metapelites from north to south and 640-770 °C and 7-10 kbar in granulites present in south only. The grade of metamorphism varies from greenschist facies in the north to upper amphibolite to granulite facies in the south. The metapelite and pyroxene granulite shows a loading and slow cooling path. The top to the north movement along the BSZ thrusted the high-grade metapelites, mafic-ultramafic rocks and granulite facies rocks over the WDC lithologies. The higher grade of metamorphism along the southern part as compared to the rest of the WDC is due to its location close to the WDC-SGT accretion zone. The zircons from the metapelitic schist provided older age population ranging between 3.3-3.2, 3.1-3.0 Ga followed by 2.9-2.7 Ga and 2.55-2.4 Ga, whereas the granulites (2.5 and 2.4 Ga) and foliated granites (2.6 Ga) yielded only the younger age populations. However, the monazites in schistose rocks located along the northern part recorded the oldest ages up to 2.7 Ga followed by 2.4 and 2.2-2.1 Ga ages. The monazites from foliated granites, irrespective of their location, provided ages of 2.53, 2.36 and 2.24 Ga. However, the monazites in schists and granulites from the southern part provided younger ages of 0.77, 0.67, 0.53 Ga. The prominent 0.84, 0.76 and 0.62 Ga monazite ages obtained from the metapelites close to the BSZ suggests that the accretion along the BSZ initiated in Mid-Neoproterozoic and continued till Early-Paleozoic. 

How to cite: Swain, M. and Rekha, S.: Structure, metamorphism and geochronology of Archean Sargur Schist Belt, southern India, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-941, https://doi.org/10.5194/egusphere-egu25-941, 2025.

Banded Iron Formations (BIFs), generally containing magnetite (Fe3O4), hematite (Fe2O3), and quartz (SiO2) in Archean oceans, have important implications for the primitive-life and sea-water condition of the primitive Earth. It is generally agreed that BIFs were deposited within marine sediments on stable continental margins (Superior-type) or associated with volcanic rocks (Algoma-type). The oxidation of Fe with free O2 is challenging due to the lack of knowledge on the extent and amount of the free oxygen available in oceanic water. Iron can precipitate in two oxidation states, i.e., +2 and +3, in magnetite and hematite, respectively. In addition, the magnetite crystallizes in the isometric crystal system, whereas hematite crystallizes in the trigonal crystal system. Since Electron Probe microanalysis cannot differentiate the oxidation states of Fe, we use X-ray diffraction and δ56 Fe values to identify the mineral phases in BIFs and utilize the EH–pH diagram to constrain the pH and redox state of Archean oceans.

The Banded Iron Formation occurs in two east-west trending linear belts in the Bundelkhand Craton. The northern belt, extending from Babina in the west to Mauranipur in the east, is an Algoma-type BIF. In contrast, the least explored southern belt, near Girar, is a Superior-type BIF. Powder X-ray diffraction patterns of the northern BIF belt indicate hematite and quartz without carbonates. On the contrary, the X-ray diffraction pattern of BIFs from Girar suggests the presence of quartz, hematite, and siderite. In addition, the result of Fe-isotope data indicates that the δ56 Fe values of Northern BIFs range from 0.2050/00 to 0.2550/00, while the δ56 Fe values from the Southern BIFs range from 1.3500/00 to 2.1260/00.

The high positive δ56 Fe from the Fe-rich bands indicates that Fe (III) delivery was the primary mechanism driving iron enrichment in the Southern BIFs. The Southern BIF's substantial Fe isotope fractionations indicate initial partial Fe (II) oxidation in low-Eh conditions as siderite, the primary mineral for hematite, was deposited between pH and Eh of 7.5 to 10 and -0.3 to -0.2 volts. With an increase in the Eh to -0.2 to -0.1, magnetite becomes the stable phase. Still, with an increase in the Eh (0.1 to 0.3 Volts), hematite becomes stable in phases with the same pH range as the aqueous medium. Since an increasing Eh with a similar pH range indicates oxidation, we suggest that southern Bundelkhand Craton BIFs materials were deposited in more oxidized conditions. This evidence suggests that microbial Fe (III) reduction in Southern BIFs occurred during the Earth's Late Neoarchean – Early Paleoproterozoic transition. The increased oxidation condition, i.e., excess oxygen in the Archean Sea in Bundelkhand Craton, could probably relate to photochemical or microbial oxidation.

How to cite: Bisht, B. P. S., Kk, A., and Nasipuri, P.: X-ray diffraction pattern and Fe-isotope of Banded Iron Formation to constrain the fluctuating redox State of Archean Ocean: A Case Study from Banded Iron Formation from Bundelkhand Craton, North Central India, EGU General Assembly 2025, Vienna, Austria, 27 Apr–2 May 2025, EGU25-123, https://doi.org/10.5194/egusphere-egu25-123, 2025.